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  • Chemical Engineering  (12)
  • Granulometrical analysis  (1)
  • Nickel coated graphite  (1)
  • 1990-1994  (8)
  • 1975-1979  (6)
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Keywords
Publisher
Years
Year
  • 1
    Electronic Resource
    Electronic Resource
    Stability of nickel coatings on carbon fiber preforms: A SEM investigation (1994)
    Springer
    Applied composite materials 1 (1994), S. 231-245 
    Details
    ISSN: 1573-4897
    Keywords: MMC ; Nickel coated graphite ; Squeeze casting ; Instable interface ; Electroplating
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Metal Matrix Composites (MMC's) reinforced with continuous fibers were generally fabricated by a foil-sandwich technique or by liquid metal infiltration. Liquid metal infiltration may be used to cast final shapes in molds containing fiber preforms. It is also used to make composite wire from which may be fabricated panels and shapes by hot-press diffusion bonding or pultrusion. The major drawback of this method is that the molten matrix must wet the fiber for successful infiltration to occur, requiring special fiber surface treatments or matrix additives, and that, molten metals generally dissolve or degrade the fibers, necessitating a barrier coating on the fibers. All these problems can be solved using carbon fibers coated with metallic layers, e.g. nickel. This work analyses an easy method to produce modified carbon fibers by electroplating and the process of its recristallization. The topography of the growth front of the deposit has been studied. At temperatures higher than about 300° C an annealing under vacuum is required, because of the high reactivity of metal coating, nevertheless the heat treatment of metal deposit produces always an embrittled material.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00567529
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  • 2
    Electronic Resource
    Electronic Resource
    Erosion of reinforcement particles in SiC/aluminum composites (1994)
    Springer
    Applied composite materials 1 (1994), S. 449-463 
    Details
    ISSN: 1573-4897
    Keywords: SiC-pure Al composites ; Erosion ; Interfacial reaction ; SEM analysis ; Granulometrical analysis
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The granulometrical and morphological variations of eroded reinforcement particles during annealing for different times at several temperatures have been studied for SiC-pure Al system. The changes produced have been analysed by scanning electron microscope (SEM) after particle extraction.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00706504
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  • 3
    Electronic Resource
    Electronic Resource
    Effect of water absorption on the behavior of E-glass fiber/nylon-6 composites (1991)
    Brookfield, Conn. : Wiley-Blackwell
    Polymer Composites 12 (1991), S. 333-337 
    Details
    ISSN: 0272-8397
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The effect of water absorption on the stress transferability across E-glass fiber/nylon 6 interface has been studied using the embedded single fiber composite technique. The behavior of silane coated fiber and untreated fiber composites after periods of water immersion were compared. The silane coating provided both higher interfacial shear stress transferability and protection from permanent water damage in the interphase region. It was found that water absorption in the nylon matrix reduced the shear stress transferability through plasticization of the matrix, weakening of the interface, and the development of tensile swelling stresses at the phase boundaries. In untreated materials the shear stress transferability was limited by decoupling of the matrix from the broken fiber ends by either interface slippage or local plane strain fracture in the interphase region near the fiber end. In the silane treated materials the shear stress transferability was limited by constrained yielding of the polysiloxane/nylon interphase at the fiber end, thus indicating plasticization of the matrix was the primary factor. After 20 days of water immersion, there was permanent deterioration of stress transferability in the untreated samples, but very little permanent damage in the treated samples.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pc.750120507
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  • 4
    Electronic Resource
    Electronic Resource
    In-situ composites: Evaluation of the adhesion between the thermoplastic matrix and the fibers of liquid crystalline polymer (1992)
    Brookfield, Conn. : Wiley-Blackwell
    Polymer Composites 13 (1992), S. 169-173 
    Details
    ISSN: 0272-8397
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Mechanical properties of fiber reinforced composites depend on the formation of stable adhesive bonds between the constituents. In order to evaluate quantitatively the adhesion between liquid crystal polymer (LCP) fibers and a thermoplastic matrix of polycarbonate, the single fiber composite test (SFC), utilized for testing glass or carbon fiber composites, has been used. Neither chemical nor physical interaction has been found: the PC and LCP phases are completely incompatible. However, a mechanical friction between PC and LCP was observed during the drawing of the sample when the neck of the matrix started.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pc.750130304
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  • 5
    Electronic Resource
    Electronic Resource
    Cure kinetics of dicyanate matrix polymers (1992)
    Brookfield, Conn. : Wiley-Blackwell
    Polymer Composites 13 (1992), S. 191-196 
    Details
    ISSN: 0272-8397
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The cure kinetics of two dicyanate resins were investigated by differential scanning calorimetry under isothermal and nonisothermal conditions. An autocatalytic kinetic model was proposed and a set of general kinetic parameters was calculated from the isothermal experiments. Good agreement between experimental data and the kinetic model has been obtained under different processing conditions, which demonstrated the validity and the usefulness of the analytical procedure and of the kinetic expression employed. Consequently, in its current form, the modeling methodology is capable of describing the degree of cure during a typical processing cycle and has the potential for comparing different resin formulations as well as the manifestations of cure in property development. Specifically, in this work the modeling methodology was tested using two distinct dicyanate resin systems while the development of the cure was also observed through dielectric analysis (DEA).
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pc.750130307
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  • 6
    Electronic Resource
    Electronic Resource
    Wilhelmy plate studies of carbon fiber/viscous fluid systems (1993)
    Brookfield, Conn. : Wiley-Blackwell
    Polymer Composites 14 (1993), S. 224-228 
    Details
    ISSN: 0272-8397
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The use of Wilhelmy plate techniques for studying the interactions of fibers with fluids of variable viscosity is discussed. The influence of hydrodynamic effects of force (F) VS. DEPTH (z) plots is interpreted on the basis of surface tension-independent added terms of the constitutive equation of the Wilhelmy experiment. Wetting experiments using pseudoplastic fluids (polyethyleneglycol/water solution) show that viscoelasticity is indeed important in the interpretation of Wilhelmy plate experiments. The comparison of wetting experiments performed on untreated and plasma-treated carbon fibers showed that at low stage speed and fluid viscosity, surface chemistry and morphology determines contact angles. At higher stage speeds and viscosities and advancing and receding angles are affected by surface chemistry-independent and hydrodynamics-dependent added contributions.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pc.750140307
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  • 7
    Electronic Resource
    Electronic Resource
    Ultimate behavior of dry and water-swollen polymer network/glass bead composites (1975)
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 15 (1975), S. 35-39 
    Details
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Tensile properties of a poly(2-hydroxyethyl methacrylate) (PHEMA) network filled with various amounts of glass beads, in the dry and the equilibrium water-swollen states, have been studied below and above Tg. The temperature ranged from 5° C to 170° C and the volume fraction of the filler was up to 50 percent. In the glassy region it has been found that the temperature at which the transition from brittle to ductiel behavior occurs is increased by the presence of the filler. In the brittle zone the strength of the composites is decreased by the presence of the filler and can be predicted by using a finite element method; in the ductile zone, however, the strength of the composites reaches that of the unfilled polymer.In the rubbery region failure envelopes have been obtained for both dry and swollen PHEMA/glass bead composites. Using a double shift procedure all the data have been superimposed to obtain universal failure envelopes for the two different states. The dependence of the shift factors on filler content is discussed.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pen.760150106
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  • 8
    Electronic Resource
    Electronic Resource
    The effect of hot drawing on the properties of short fiber reinforced extruded sheets (1979)
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 19 (1979), S. 1046-1053 
    Details
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The hot drawing of extruded composite sheets can be used to control the orientation of both matrix and reinforcing fibers. A study was made of the effect of draw ratio on the properties of an extruded polystyrene sheet containing 0 to 1 percent of short glass fibers. An increase in draw ratio resulted in an increase in fiber orientation. A model of a rigid fiber rotating in an elongational flow field was used to describe the effect of draw ratio on the final orientation distribution. An increase in draw ratio also caused an increase in the amount of fiber breakage. A shear-lag analysis was used to estimate the extent of damage as a function of draw ratio. It was also found that the mechanical properties were dependent upon both the draw ratio and fiber concentration.
    Additional Material: 14 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pen.760191413
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  • 9
    Electronic Resource
    Electronic Resource
    The effects of thermal treatment, residual solvent, and preswelling on the thermal properties and sorption behavior of poly(2,6-dimethyl, 1,4-phenylene oxide)-polystyrene blends (1978)
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 18 (1978), S. 1006-1011 
    Details
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The effects of thermal treatment, residual solvent, and preswelling on the thermal properties and swelling behavior of solution cast polyblend films of poly(2,6-dimethyl,1,4-phenylene oxide) (PPO) and polystyrene (PS) were determined. Repeated cycling in the DSC analysis of the “as cast” films suggested that the original films contained residual casting solvent and that solvent-induced crystallization occurred in the PPO-rich compositions. Crystallinity was, apparently, eliminated by the first heating cycle in the differential scanning calorimeter. Sorption kinetics and apparent equilibria, characterizing the penetration of these films by n-hexane from the vapor phase, indicated that both the sorption rate and apparent equilibria are significantly affected by the prior history of the film samples. The sorption results presented here are quantitatively consistent with earlier studies of the PPO-PS system. The increased rate and amount of sorption observed in preswollen samples, and the reduced rate and amount of sorption observed in annealed samples are consistent with recent descriptions of sorption behavior in diverse glassy homopolymer systems.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pen.760181307
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  • 10
    Electronic Resource
    Electronic Resource
    Dynamic-mechanical and dielectric characterization of PEEK crystallization (1990)
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 30 (1990), S. 314-320 
    Details
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Dynamic-mechanical and dielectric characterization of the cold crystallization of PEEK has been performed in order to develop a non-destructive evaluation method of crystallinity in thermoplastic matrices. The Avrami approach is applied here to describe the Poly(ether ether ketone) (PEEK) crystallization kinetics after an appropriate reduction of dynamic-mechanical and dielectric parameters. Avrami exponents obtained from dielectric characterization are comparable with those obtained with DSC measurements reported in literature, while the exponents obtained from the dynamic-mechanical characterization are higher, reflecting also changes in the aspect ratio of the growing crystals. Variations in the glass transition temperature detected during cold crystallization are analyzed and analogies between PEEK and PET are discussed.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pen.760300509
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