ISSN:
1076-5174
Keywords:
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Physics
Notes:
The electron impact mass spectra of nine solanidane N-oxides show, in addition to the known typical fragmentation pattern of the solanidane moiety, the fragment ions [M - C5H9]+ and [C6H12NO]+, due to thermal Cope syn-eliminations caused by the N-oxide function and subsequent cleavage of the bonds between C(22) and C(23) and between C(20) and C(22), respectively, in the so-obtained cyclic N,N-dialkylhydroxylamines.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/jms.1190300130
Permalink