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  • 1
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    American Association for the Advancement of Science (AAAS)
    Publication Date: 1998-12-04
    Description: A calcium-aluminum-rich inclusion (CAI) from the Allende meteorite was analyzed and found to contain melilite crystals with extreme oxygen-isotope compositions ( approximately 5 percent oxygen-16 enrichment relative to terrestrial oxygen-16). Some of the melilite is also anomalously enriched in oxygen-16 compared with oxygen isotopes measured in other CAIs. The oxygen isotopic variation measured among the minerals (melilite, spinel, and fassaite) indicates that crystallization of the CAI started from oxygen-16-rich materials that were probably liquid droplets in the solar nebula, and oxygen isotope exchange with the surrounding oxygen-16-poor nebular gas progressed through the crystallization of the CAI. Additional oxygen isotope exchange also occurred during subsequent reheating events in the solar nebula.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Yurimoto -- Ito -- Nagasawa -- New York, N.Y. -- Science. 1998 Dec 4;282(5395):1874-7.〈br /〉〈span class="detail_caption"〉Author address: 〈/span〉H. Yurimoto, Department of Earth and Planetary Sciences, Tokyo Institute of Technology, Ookayama, Meguro, Tokyo 152-8551, Japan. M. Ito and H. Nagasawa, Department of Chemistry, Gakushuin University, Mejiro, Toshima, Tokyo 171-8588, Japan.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/9836634" target="_blank"〉PubMed〈/a〉
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 2
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    Unknown
    American Association for the Advancement of Science (AAAS)
    Publication Date: 1998-12-04
    Description: A calcium-aluminum-rich inclusion (CAI) from the Allende meteorite was analyzed and found to contain melilite crystals with extreme oxygen-isotope composition (approximately 5 percent oxygen-16 enrichment relative to terrestrial oxygen-16). Some of the melilite is also anomalously enriched in oxygen-16 compared with oxygen isotopes measured in other CAIs. The oxygen isotopic variation measured among the minerals (melilite, spinel, and fassaite) indicates that crystallization of the CAI started from oxygen-16-rich materials that were probably liquid droplets in the solar nebula, and oxygen isotope exchange with the surrounding oxygen-16-poor nebular gas progressed through the crystallization of the CAI. Additional oxygen isotope exchange also occurred during subsequent reheating events in the solar nebula.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Yurimoto, H -- Ito, M -- Nagasawa, H -- New York, N.Y. -- Science. 1998 Dec 4;282(5395):1874-7.〈br /〉〈span class="detail_caption"〉Author address: 〈/span〉Department of Earth and Planetary Sciences, Tokyo Institute of Technology, Japan. yuri@geo.titech.ac.jp〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/9874638" target="_blank"〉PubMed〈/a〉
    Keywords: Crystallization ; *Meteoroids ; Oxygen/*analysis ; Oxygen Isotopes/*analysis ; *Solar System
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Physics and chemistry of minerals 26 (1999), S. 425-431 
    ISSN: 1432-2021
    Keywords: Key words SIMS ; Depth profiling ; Forsterite Diffusion ; Arrhenius plot ; Activation energy
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Geosciences , Physics
    Notes: Abstract  Diffusion coefficients of Co2+ and Ni2+ in synthetic single crystal forsterite along the c-axis were determined in the temperature ranges, 700–1200 °C and 800–1300 °C, respectively. The synthesized forsterite specimens were coated with thin evaporated films of CoO and NiO on the c-surface and annealed for diffusion experiments. The short penetration distance of diffusing ions in forsterite was measured by secondary ion mass spectrometry using the depth profile method. The diffusion coefficients of Co (700–1200 °C) and Ni (800–1300 °C) are given by: and The observed diffusion coefficient values show good linear relationships in Arrhenius plots and the activation energy values obtained agree well with the previous values, although the diffusion coefficient values observed at the high temperature end of the experimental range deviate from the previous values. These results indicate that Co and Ni diffuse in olivine with a single mechanism within the temperature range observed, possibly with an extrinsic in nature as in the case of Mg tracer diffusion observed by Chakraborty et al. 1994 and of Fe-Mg interdiffusion by Chakraborty.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    Physics and chemistry of minerals 24 (1997), S. 385-395 
    ISSN: 1432-2021
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Geosciences , Physics
    Notes: Abstract  The concentrations of hydrogen and the other trace elements in olivines from mantle xenoliths have been determined by secondary ion mass spectrometry (SIMS) for clarifying the incorporation mechanism and the behavior of the hydrogen. The hydrogen contents in olivines from mantle xenoliths range from 10 to 60 ppm wt. H2O and the concentration range is consistent with the previous infrared (IR) spectroscopic data. IR spectra of the olivine crystals show no effects of the weathering or secondary alteration. The hydrogen is distributed homogeneously among olivine grains in each mantle xenolith. However, the hydrogen contents of the olivine crystals are less than those for the olivine phenocrysts crystallized from the host magma. Olivine inclusions in diamonds also show similar hydrogen contents to the xenolithic olivines. Thus the hydrogen content of xenolithic olivines does not attain equilibrium with water in the host magma during the transportation from the Earth's mantle to the surface, and is taken as a reflection of the hydrogen condition in the mantle. Correlations of hydrogen with trivalent cation contents in garnet peridotitic olivines indicate the incorporation of hydrogen into mantle olivines by a coupled substitution mechanism, with the hydrogen present in the form of hydroxyl in oxygen positions adjacent to the M site vacancies. The hydrogen content of xenolithic olivines increases with pressure but decreases with increasing temperature, suggesting importance of olivine as a water reservoir at low temperature regions such as in subducting slabs.
    Type of Medium: Electronic Resource
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  • 5
    Publication Date: 1999-07-19
    Print ISSN: 0342-1791
    Electronic ISSN: 1432-2021
    Topics: Chemistry and Pharmacology , Geosciences , Physics
    Published by Springer
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  • 6
    Publication Date: 1997-08-20
    Print ISSN: 0342-1791
    Electronic ISSN: 1432-2021
    Topics: Chemistry and Pharmacology , Geosciences , Physics
    Published by Springer
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