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  • 1
    Publication Date: 2023-06-22
    Description: Carbonate minerals are ubiquitous in most sediment-hosted mineral deposits. These deposits can contain a variety of carbonate types with complex paragenetic relationships. When normalized to chondritic values (CN), rare-earth elements and yttrium (REE+YCN) can be used to constrain fluid chemistry and fluid-rock interaction processes in both low- and high-temperature settings. Unlike other phases (e.g., pyrite), the application of in situ laser ablation-inductively coupled plasma-mass spectroscopy (LA-ICP-MS) data to the differentiation of pre-ore and hydrothermal carbonates remains relatively untested. To assess the potential applicability of carbonate in situ REE+Y data, we combined transmitted light and cathodoluminescence (CL) petrography with LA-ICP-MS analysis of carbonate mineral phases from (1) the Proterozoic George Fisher clastic dominated (CD-type) massive sulfide deposit and from (2) correlative, barren host rock lithologies (Urquhart Shale Formation). The REE+YCN composition of pre-ore calcite suggests it formed during diagenesis from diagenetic pore fluids derived from ferruginous, anoxic seawater. Hydrothermal and hydrothermally altered calcite and dolomite from George Fisher is generally more LREE depleted than the pre-ore calcite, whole-rock REE concentrations, and shale reference values. We suggest this is the result of hydrothermal alteration by saline Cl--rich mineralizing fluids. Furthermore, the presence of both positive and negative Eu/Eu* values in calcite and dolomite indicates that the mineralizing fluids were relatively hot (〉250°C) and cooled below 200–250°C during ore formation. This study confirms the hypothesis that in situ REE+Y data can be used to differentiate between pre-ore and hydrothermal carbonate and provide important constraints on the conditions of ore formation.
    Description: Helmholtz-Gemeinschaft http://dx.doi.org/10.13039/501100001656
    Description: https://doi.org/10.5880/GFZ.3.1.2020.005
    Keywords: ddc:553.4 ; CD-type massive sulfide deposit ; Rare earth elements ; Carbonate chemistry ; Proterozoic ; Mount Isa ; LA-ICP-MS
    Language: English
    Type: doc-type:article
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  • 2
    Publication Date: 2024-01-30
    Description: Abstract
    Description: The EU funded project CRM-geothermal aims to establish an overview of the potential for critical raw materials (CRM) in geothermal fluids across the EU and third countries (Ref). Within this framework, the geothermal sites of Tuzla, Seferihisar and Dikili in eastern Turkey have been visited in March 2023. To estimate the potential of CRM at these sites, a comprehensive sampling program was performed. Rock samples (drill gravel) of the production borehole and scaling from gas-water separators were obtained. Furthermore, sampling of geothermal fluids (gas and brine) and precipitates (salt) along the production line was performed. Here, the results of the geochemical analyses of solid sample materials (drill gravel, scales and salt) are presented. All analyses were performed in the ElMiE-Lab (Elements and Minerals of the Earth Laboratory) at German Research Centre for Geosciences Potsdam, Germany (https://labinfrastructure.geo-x.net/laboratories/8). For their major and minor element compositions, bulk samples of drill gravel and scales were analyzed with XRF and ICP-MS, respectively. Salt precipitates were analyzed for dry loss and mineral composition using XRD.
    Description: Methods
    Description: Sampling of drill gravel: Drill core gravel from Tuzla geothermal site was obtained from existing samples taken during drilling in 2010. For the analyses, three samples of the geothermal reservoir horizon at different depth and from two different drill holes were chosen. Sampling of scales: Scales were sampled during geothermal power plant maintenance in 2023 in Tuzla and in 2022 in Seferihisar. It was analyzed from all water-gas separators from the three drill holes in Tuzla. For Seferihisar, fresh scales were obtained from inside a tube, a pump and a fitter. Sampling of salt precipitates: During the visits, fresh salt precipitates were taken from outside the pipeline that transports geothermal brine to the power plant. The sampling points were located near the production well. Here, few connectors were slightly leaking which is negligible for the geothermal power production. Over time, the small amounts of brine release causes salt precipitation, due to brine cooling and evaporation. The residual salts occurs in form of fine crystalline precipitations around the pipe connectors or, stalactite-like salt tubings. Sampling of fresh, slightly moist material was performed by either scratching material off the precipitate deposit or breaking off juvenile stalactite outgrowth. The sample were stored and transported in air-tight zipper plastic bags to avoid sample alteration by atmospheric air.
    Keywords: critical raw materials ; geothermal power plant eastern turkey ; drill gravel ; scales ; salt precipitates ; geochemistry ; XRF ; ICP-MS ; XRD ; EARTH SCIENCE 〉 HUMAN DIMENSIONS 〉 ECONOMIC RESOURCES 〉 ENERGY PRODUCTION/USE 〉 GEOTHERMAL ENERGY PRODUCTION/USE ; energy 〉 energy type 〉 non-conventional energy 〉 geothermal energy ; Models/Analyses 〉 CRM
    Type: Dataset , Dataset
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  • 3
    Publication Date: 2024-02-07
    Description: Metamorphic and deformed rocks in thrust zones show particularly high seismic anisotropy causing challenges for seismic imaging and interpretation. A good example is the Seve Nappe Complex in central Sweden, an old exhumed orogenic thrust zone that is characterized by a strong but incoherent seismic reflectivity and considerable seismic anisotropy. However, only little is known about their origin in relation to composition and structural influences on measurements at different seismic scales. Here, we present a new integrative study of cross‐scale seismic anisotropy analyses combining mineralogical composition, microstructural analyses and seismic laboratory experiments from the COSC‐1 borehole, which sampled a 2.5 km‐deep section of metamorphic rocks deformed in an orogenic root now preserved in the Lower Seve Nappe. While there is strong crystallographic preferred orientation in most samples in general, variations in anisotropy depend mostly on bulk mineral composition and dominant core lithology as shown by a strong correlation between these. This relationship enables to identify three distinct seismic anisotropy facies providing a continuous anisotropy profile along the borehole. Moreover, comparison of laboratory seismic measurements and electron‐backscatter diffraction data reveals a strong scale‐dependence, which is more pronounced in the highly deformed, heterogeneous samples. This highlights the need for comprehensive cross‐validation of microscale anisotropy analyses with additional lithological data when integrating seismic anisotropy over seismic scales.
    Type: Article , PeerReviewed
    Format: other
    Format: text
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  • 4
    Publication Date: 2024-03-08
    Description: Abstract
    Description: In autumn 2022, an expedition to Tanzania was undertaken within the framework of the research project “CRM-geothermal” and Scintific Priority Program (SPP) 2238 “Dynamics of Ore Metal Enrichment”. Within „CRM-geothermal“ we are looking for an environmentally friendly co-production of critical raw materials together with the provision of geothermal energy. In the EARS, high levels of rare earth elements (REE), Sr, Ba and Mg are expected in waters and solids in areas with alkaline volcanic rocks, while other critical elements, including helium, have been sought in other localities. In particular, the eastern branch is the most juvenile sector and has increased geothermal potential related to hot fluids migrating along permeable faults. Tanzania was crossed from north to south, along the eastern arm of the EARS, to collect gas, water, rock and sediment samples associated with natural hot springs, lakes and vents. On site, physical and chemical parameters were measured in-situ and documented together with the geology, infrastructure and the domestic use of the hot site. In the south, existing drill sites and geothermal development areas were visited and gas and water samples were taken from boreholes and rocks sampled from drill cores. The survey covered 13 sites, from Lake Natron in the north to Lake Malawi in the south (see map).
    Type: Dataset , Dataset
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  • 5
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    Publication Date: 2024-03-27
    Description: Was ist digitales Lesen? Wie gehen Lesende mit der digitalen Angebotsfülle um? Individuelle Bewältigungsmechanismen reichen oft nicht mehr aus, um diese Herausforderung zu meistern, und der Hype um digitale Medien verstellt den Blick auf ihre Tradition. Die Entwicklung stabiler Lesestrategien und Medienkompetenz erfordert daher eine systematische historische und wissenschaftliche Beschreibung des Phänomens. Aus der Synthese von Leseakttheorie, Materialitäts- und Medienforschung sowie Praxistheorie entwickelt Franziska Wilke eine Lesetypologie, die das Lesen digitaler Literatur veranschaulicht. Ihre gewonnenen Erkenntnisse nützen nicht nur Lesenden, sondern auch jenen, die es werden möchten.
    Keywords: Lesen ; Medien ; Medienkompetenz ; Digitalisierung ; Praxistheorie ; Literatur ; Wolfgang Iser ; Technik ; Allgemeine Literaturwissenschaft ; Digitale Medien ; Literaturtheorie ; Medientheorie ; Literaturwissenschaft ; Reading ; Media ; Media Competence ; Digitalization ; Practice Theory ; Literature ; Technology ; Literary Studies ; Digital Media ; Theory of Literature ; Media Theory ; thema EDItEUR::D Biography, Literature and Literary studies::DS Literature: history and criticism::DSB Literary studies: general ; thema EDItEUR::J Society and Social Sciences::JB Society and culture: general::JBC Cultural and media studies::JBCT Media studies ; thema EDItEUR::D Biography, Literature and Literary studies::DS Literature: history and criticism::DSA Literary theory
    Language: German
    Format: image/jpeg
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