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    Publication Date: 2020-01-01
    Print ISSN: 0031-0182
    Electronic ISSN: 1872-616X
    Topics: Geosciences , Physics
    Published by Elsevier
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    Publication Date: 2021-02-08
    Description: Iron isotopes in ocean floor basalts (OFB) away from convergent margins comprising mid-ocean-ridge and ocean island lavas show significant variation of 〉0.4‰ (expressed in the delta notation δ57Fe relative to IRMM-014), but processes responsible for this variation remain elusive. Bond-valence theory predicts that valence states (Fe3+ vs. Fe2+) control Fe isotopes during partial melting and crystal fractionation along the liquid line of descent and thus contribute substantially to this variation. Memory of past melt extraction or metasomatic re-enrichment in the source of OFB may further add to the observed variability, but systematic investigations to elucidate the respective contributions of these effects have been lacking. Submarine ridges and rifts in the Lau back-arc basin offer a unique opportunity to compare Fe isotopes in OFB from different melting regimes and variably depleted mantle sources. New Fe isotope data is presented for submarine lavas from the Rochambeau Ridges (RR) and the Northwest Lau Spreading Centre (NWLSC), and is compared with published data from the Central Lau Spreading Centre (CLSC). In line with first principle calculations and observations from a range of natural systems, crystal fractionation is identified as the dominant, controlling process for elevating δ57Fe in the lavas with olivine tentatively identified as the key driver. To compensate for the effect of crystal fractionation, olivine is mathematically added towards calculated primitive melt compositions (δ57Feprim). For this, we used a constant Ol-melt isotope fractionation factor based on published equilibrium partition functions adapted to decreasing temperature in a cooling melt. The degree of calculated Fe isotope fractionation through olivine crystal fractionation (monitored as Δ57Fe = δ57Femeasured − δ57Feprim) is positively correlated with increasing S and decreasing Ni content in the cooling lavas, fortifying the validity of the approach. Primitive lavas from individual Lau spreading centres and ridges vary to 0.1‰ in δ57Feprim, similar to primitive open-ocean MORB. However, the entire spread in Fe isotope variability in the primitive melts remains at 0.3‰, which we propose to be the extent of isotope heterogeneity in Earth’s upper mantle, with few extreme exceptions. The largest variability in δ57Feprim is observed for RR intra-plate lavas, which have been associated with the Samoan mantle plume and melting in an edge-driven convection scenario. Low, mid-ocean ridge-like 87Sr/86Sr in RR lavas excludes significant influence of isotopically heavy Samoan EM2-type components. However, co-variations with rare earth element pattern in some RR intra-plate lavas indicate garnet plays a role in elevating δ57Feprim during deeper melting. Excluding these deep-seated melts uncovers systematically decreasing δ57Feprim coupled to the degree of mantle source depletion, as recorded in Lu/Hf and Sm/Nd, in the back-arc basin basalts. This, however, holds only true for a comparison between sources of individual ridges, whereas no co-variation is observed within ridge segment data. This suggests that a process other than source depletion and crystal fractionation further adds to Fe isotope variability in the order of 0.1‰ on scales of individual ridge segments. This either marks the degree of Fe isotope variability below ridge segments, or is caused by secondary processes, such as melt-wallrock interaction or RTX (recharge and crystal fractionation) magma chambers.
    Type: Article , PeerReviewed
    Format: text
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  • 6
    Publication Date: 2023-06-12
    Description: Abstract
    Description: The crystalline aquifer in Ghana’s Pra Basin provides water for over 4 million people as many rivers are polluted by artisanal mining. The aim of the data collection was to understand the origin, quality and chemical evolution of surface water and ground water in order to improve the sustainable management of the resource. Here, we present data on major ions, trace metals, stable oxygen (δ18O) and hydrogen (δ2H) isotope ratios of surface water and ground water and mineralogical composition of rock outcrops from the Pra Basin in Ghana. The field campaign took place in March 2020 (water sampling) and August 2021 (outcrop sampling). A total of 34 surface water and 56 ground water samples were collected from rivers, public boreholes (depth 〉30 m) and hand-dug wells (depth 〈 10 m), respectively. The water samples were analysed for cations and trace metals using the Inductively Coupled Plasma Optical Emission Spectrometry (ICP-OES). The anions were analysed using the Ion Chromatography (IC). For the stable oxygen (δ18O) and hydrogen (δ2H) isotope ratios, a Picarro L-2140i Ringdown Spectrometer was used. The bulk elemental composition of the rock samples was analysed by X-ray fluorescence (XRF). The mineralogic composition was determined by X-ray diffraction (XRD) while the Zeiss Axiophot petrographic microscope was used for the petrographic thin section analysis. The data generated from all measurements are provided in a .zip folder consisting of four subfolders. Each folder contains Excel files discussed in the file inventory section.
    Keywords: Birimian Supergroup ; Cape Coast granitoid ; Major ions ; Trace metals ; Stable isotopes ; X-ray fluorescence ; X-ray diffraction ; Petrographic thin section ; EARTH SCIENCE 〉 SOLID EARTH 〉 GEOCHEMISTRY 〉 GEOCHEMICAL PROCESSES 〉 MINERAL DISSOLUTION
    Type: Dataset , Dataset
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    Publication Date: 2023-08-09
    Description: Abstract
    Description: The USGS has suspended the distribution of the widely used whole rock reference materials BHVO, BCR and BIR. The goal of this work is to identify a material as similar as possible to the original BIR Islandic basalt. This material can then undergo an ISO-compliant certification of the whole rock powder major and trace element contents. The sampling quarry east of Reykjavik has multiple basalt flows and it is not known which one was originally sampled in 1980 for production of above mentioned reference materials. In this study, three samples were tested to see which is most similar to what was published by Flanigan (1984). Here, the results of this exploratory sample collection are presented, but note that these data are not part of the certification process or represent certified results.
    Description: Methods
    Description: Three basalt samples each of around 500 grams were collected at an abandoned quarry circa 12 km east of Reykjavik, Iceland. The samples were ground to 〈63 µm using an agate mortar. Major and minor element concentrations were determined on glass beads by xrf. Some minor and trace elements were determined on whole rock digests using the standard 4 acid digestion.
    Keywords: Iceland ; compound material 〉 igneous material 〉 igneous rock ; compound material 〉 igneous material 〉 igneous rock 〉 fine grained igneous rock 〉 basalt ; In Situ/Laboratory Instruments 〉 Spectrometers/Radiometers 〉 ICP-MS ; In Situ/Laboratory Instruments 〉 Spectrometers/Radiometers 〉 XRF
    Type: Dataset , Dataset
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  • 8
    Publication Date: 2024-01-30
    Description: Abstract
    Description: The EU funded project CRM-geothermal aims to establish an overview of the potential for critical raw materials (CRM) in geothermal fluids across the EU and third countries (Ref). Within this framework, the geothermal sites of Tuzla, Seferihisar and Dikili in eastern Turkey have been visited in March 2023. To estimate the potential of CRM at these sites, a comprehensive sampling program was performed. Rock samples (drill gravel) of the production borehole and scaling from gas-water separators were obtained. Furthermore, sampling of geothermal fluids (gas and brine) and precipitates (salt) along the production line was performed. Here, the results of the geochemical analyses of solid sample materials (drill gravel, scales and salt) are presented. All analyses were performed in the ElMiE-Lab (Elements and Minerals of the Earth Laboratory) at German Research Centre for Geosciences Potsdam, Germany (https://labinfrastructure.geo-x.net/laboratories/8). For their major and minor element compositions, bulk samples of drill gravel and scales were analyzed with XRF and ICP-MS, respectively. Salt precipitates were analyzed for dry loss and mineral composition using XRD.
    Description: Methods
    Description: Sampling of drill gravel: Drill core gravel from Tuzla geothermal site was obtained from existing samples taken during drilling in 2010. For the analyses, three samples of the geothermal reservoir horizon at different depth and from two different drill holes were chosen. Sampling of scales: Scales were sampled during geothermal power plant maintenance in 2023 in Tuzla and in 2022 in Seferihisar. It was analyzed from all water-gas separators from the three drill holes in Tuzla. For Seferihisar, fresh scales were obtained from inside a tube, a pump and a fitter. Sampling of salt precipitates: During the visits, fresh salt precipitates were taken from outside the pipeline that transports geothermal brine to the power plant. The sampling points were located near the production well. Here, few connectors were slightly leaking which is negligible for the geothermal power production. Over time, the small amounts of brine release causes salt precipitation, due to brine cooling and evaporation. The residual salts occurs in form of fine crystalline precipitations around the pipe connectors or, stalactite-like salt tubings. Sampling of fresh, slightly moist material was performed by either scratching material off the precipitate deposit or breaking off juvenile stalactite outgrowth. The sample were stored and transported in air-tight zipper plastic bags to avoid sample alteration by atmospheric air.
    Keywords: critical raw materials ; geothermal power plant eastern turkey ; drill gravel ; scales ; salt precipitates ; geochemistry ; XRF ; ICP-MS ; XRD ; EARTH SCIENCE 〉 HUMAN DIMENSIONS 〉 ECONOMIC RESOURCES 〉 ENERGY PRODUCTION/USE 〉 GEOTHERMAL ENERGY PRODUCTION/USE ; energy 〉 energy type 〉 non-conventional energy 〉 geothermal energy ; Models/Analyses 〉 CRM
    Type: Dataset , Dataset
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    Publication Date: 2024-02-14
    Description: Abstract
    Description: The Southern Permian Basin in Central Europe (in Germany and Poland) hosts several sediment-hosted Cu deposits (see Borg et al., 2012). The Cu- and Zn-Pb sulfide mineralization is preserved in the coarse-grained continental siliciclastics of the uppermost Rotliegend (S1), organic matter- and carbonate-rich marine mudstones of the Kupferschiefer (T1) and dolomitic Zechstein Limestone (Ca1). In these datasets, we provide quantitative mineralogical and geochemical data of drill core samples from the Saale Basin in East Germany. The samples include the uppermost Rotliegend sandstone (S1), Kupferschiefer (T1) and lowermost Zechstein Limestone (Ca1), referred as the Kupferschiefer system, from three drill cores (Sangerhausen, Allstedt and Wallendorf). This data publication includes quantitative mineralogy (X-ray diffraction), bulk rock major, minor and trace element geochemistry (X-ray fluorescence and inductively coupled mass spectrometry) and total organic carbon (elemental analyzer).
    Keywords: Kupferschiefer ; Saale Basin ; Eastern Germany ; Quantitative mineralogy ; Bulk rock geochemistry ; Base metals ; Total organic carbon ; Major elements ; Trace elements ; X-ray diffraction ; X-ray flourescence ; Inductively coupled plasma-mass spectrometry ; Diagenetic history ; Timing of Cu- and Zn-Pb sulfide mineralization ; compound material 〉 sedimentary material 〉 sedimentary rock 〉 generic sandstone 〉 sandstone ; EARTH SCIENCE 〉 OCEANS 〉 MARINE SEDIMENTS 〉 DIAGENESIS ; EARTH SCIENCE 〉 OCEANS 〉 OCEAN CHEMISTRY 〉 MARINE GEOCHEMISTRY ; EARTH SCIENCE 〉 SOLID EARTH 〉 GEOCHEMISTRY 〉 MARINE GEOCHEMICAL PROCESSES 〉 MINERAL DISSOLUTION
    Type: Dataset , Dataset
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    Publication Date: 2024-03-08
    Description: Abstract
    Description: In autumn 2022, an expedition to Tanzania was undertaken within the framework of the research project “CRM-geothermal” and Scintific Priority Program (SPP) 2238 “Dynamics of Ore Metal Enrichment”. Within „CRM-geothermal“ we are looking for an environmentally friendly co-production of critical raw materials together with the provision of geothermal energy. In the EARS, high levels of rare earth elements (REE), Sr, Ba and Mg are expected in waters and solids in areas with alkaline volcanic rocks, while other critical elements, including helium, have been sought in other localities. In particular, the eastern branch is the most juvenile sector and has increased geothermal potential related to hot fluids migrating along permeable faults. Tanzania was crossed from north to south, along the eastern arm of the EARS, to collect gas, water, rock and sediment samples associated with natural hot springs, lakes and vents. On site, physical and chemical parameters were measured in-situ and documented together with the geology, infrastructure and the domestic use of the hot site. In the south, existing drill sites and geothermal development areas were visited and gas and water samples were taken from boreholes and rocks sampled from drill cores. The survey covered 13 sites, from Lake Natron in the north to Lake Malawi in the south (see map).
    Type: Dataset , Dataset
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