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  • 1
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    40Ar/39Ar age constraints to MIS 5.5 and MIS 5.3 paleo-sea levels: implications for global sea levels and ice-volume estimation (2023)
    PANGAEA
    Details
    Publication Date: 2023-08-31
    Description: We present ten 40Ar/39Ar age determinations, both on primary volcanic deposits and on detrital sanidine, which provide geochronologic control on the MIS 5.5 and MIS 5.3 sea-level indicators that occur at three coastal caves in the central Tyrrhenian Sea of Italy. Samples dated for the present work are as follows: - Two pumice clasts (MOSC-22, MOSC-37) extracted from the sand layers constituting the sedimentary fill of Moscerini Cave, recovered during the original archaeological excavations performed in the year 1949, stored at the IIPU (Istituto Italiano di Paleontolgia Umana) repository in Anagni (Frosinone, italy). These two samples were processed at the rare Gas Laboratory of the University of Wisconsin Madison in March, 2019. - One tephra layer (sample GDC-10) intercalated in the sedimentary fill of Capre Cave collected in June, 2021. - Seven sedimentary sand samples collected at Guattari Cave (GU-1, GU-5, GU-105, GU-116) in June, 2020, and at Capre Cave (GDC-6, GDC-8, GDC-0) in June, 2021 . These dates constrain the age of a Strombus-bearing biodetritic conglomerate associated with a tidal notch occurring at 9.5 m a.s.l. at Cape Circeo between 121.5±5.8 and 116.2±1.2 ka. Moreover, deposition of backbeach deposits intercalated in the sedimentary filling of Guattari and Capre coastal caves is bracketed in the interval 110.4±1.4 ka to 104.9±0.9 ka. Such deposits are directly correlated with a tidal notch at ~2.5 m associated with another biodetritic conglomerate at Cape Circeo. The latter is correlated with the adjacent marine terrace, occurring at 3-5 m in the coast between Capes Circeo and Anzio, for which a maximum age of 100.7±6.6 ka was previously reported. These data provide evidence for a maximum sea level around 9.5 m above the present sea level and a duration of MIS 5.5 highstand until 116 ka, in line with estimation from other regions in the world. In contrast, they suggest a maximum sea level during MIS 5.3 highstand that is similar to the present level, and only ~7 m lower than the MIS 5.5 highstand, challenging the reconstructions of the MIS 5 ice-sheet volumes and derived global sea levels that are based on the benthic oxygen isotope records.
    Keywords: 40Ar/39Ar geochronology; Age, mineral; Age, mineral, standard deviation; Analytical method; Capre_GDC-0; Capre_GDC-10; Capre_GDC-6; Capre_GDC-8; Capre Cave; Comment; DATE/TIME; Elevation of event; Event label; Geological sample; GEOS; Guattari_GU-1; Guattari_GU-105; Guattari_GU-116; Guattari_GU-5; Guattari Cave; Latitude of event; Longitude of event; MIS 5; Moscerini_MOSC-22; Moscerini_MOSC-37; Moscerini Cave; sea level change; Tyrrhenian Sea
    Type: Dataset
    Format: text/tab-separated-values, 40 data points
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    DATA PANGAEA
  • 2
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    Tephrochronology of the central Mediterranean MIS 11c interglacial (∼425–395 ka): New constraints from the Vico volcano and Tiber delta, central Italy (2021)
    Elsevier
    Details
    Publication Date: 2023-11-14
    Description: Through a systematic integrated approach, which combined lithostratigraphic, geochronological and geochemical analyses of tephra from near-source sections of the peri-Tyrrhenian volcanoes and mid to distal settings, here we provide an improved tephrochronological framework for the Marine Isotope Stage 11c interglacial (MIS 11c, ~425e395 ka) in the Central Mediterranean area. Specifically, we present the complete geochemical dataset and new high-precision 40Ar/39Ar ages of the previously poorly characterized earliest pyroclastic products of the Vico volcano (420e400 ka), including the Plinian eruptions of Vico a and Vico b and the immediately post-dating lower magnitude explosive events. Furthermore, we also provide new geochronological and geochemical data for the distal tephra layers preserved in the aggradational succession of the Tiber delta (San Paolo Formation), Roman area, which records sea level rise relating to the MIS 12 (glacial) to MIS 11 (interglacial) transition. Five pyroclastic units were recognized in Vico volcanic area, four out of which, Vico a, Vico b, Vico btop (a minor eruption immediately following Vico b and temporally very close to it) and Vico d were directly dated at 414.8 ± 2.2 ka, 406.5 ± 2.4 ka, 406.4 ± 2.0 ka and 399.7 ± 3.2 ka respectively (2s analytical uncertainties). These new data allow a critical reappraisal of the previously claimed identifications of Vico tephra from mid-distal to ultra-distal successions (i.e., Vico-Sabatini volcanic districts, Roman San Paolo Formation and Castel di Guido archaeological site, Sulmona Basin, Valdarno and Lake Ohrid), which were unavoidably biased by the poor and incomplete geochemical and geochronological reference datasets previously available. Such an improvement of the tephrochronological framework brings great benefits to any future investigations (e.g., paleoclimatology, archaeology, active tectonic, volcanology) in the dispersal areas of the studied eruptions at the key point in time that is MIS 11.
    Description: Published
    Description: 106470
    Description: 1V. Storia eruttiva
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 3
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    Mediterranean tephrostratigraphy and peri-Tyrrhenian explosive activity revaluated in light of the 430-365 ka record from Fucino Basin (central Italy) (2021)
    Elsevier
    Details
    Publication Date: 2023-11-21
    Description: Accurately reconstructing the scale and timing of dynamic processes, such as Middle-Late Pleistocene explosive volcanism and rapid climatic changes, requires rigorous and independent chronological constraints. In this framework, the study of distal volcanic ash layers, or tephra, transported and deposited over wide regions during explosive volcanic eruptions, is increasingly being recognised as a fundamental chronostratigraphic tool for addressing these challenging issues. Here we present a high-resolution distal tephra record preserved in the lacustrine sedimentary succession of the Fucino Basin, central Italy. The investigated record spans the 430-365 ka time interval, covering the entirety of Marine Isotope Stage 11 (MIS 11), and provides important insights into peri-Tyrrhenian potassic explosive volcanism from sources located in central Italy against a backdrop of Mediterranean palaeooclimate records. The succession of ash fall events of this time interval is reconstructed through a detailed lithostratigraphic, geochemical and 40Ar/39Ar geochronological characterization of the deposits preserved as discrete layers in the Fucino F4-F5 sediment core. This work is complemented by similarly detailed characterization of selected proximal pyroclastic units from the peri-Tyrrhenian potassic volcanoes. Geochemical fingerprinting of the tephra deposits by means of their major, minor and trace elements and Sr isotope composition indicates that all the thirty-two investigated ash layers derived from the peri-Tyrrhenian potassic volcanoes. The stratigraphically continuous succession of the Fucino tephra layers allowed the development of a fully independent, 40Ar/39Ar age-constrained, Bayesian age-depth model for the investigated time interval. The age-model allows us to establish modelled ages for the tephra layers within the succession that are not directly dated. The resulting dated tephra record clearly reveals a highly time resolved and previously unparalelled chronicle of explosive activity from the Vulsini, Vico, Sabatini, Colli Albani and Roccamonfina volcanic complexes. Our study provides a benchmark and valuable geochemical and geochronological dataset to be used as a reference for any future development and application of the tephrostratigraphic methods across the central Mediterranean area both during the investigated 430-365 ka time interval, and deeper in time. This contribution underlines the importance of integrating proximal and distal sedimentary records to more accurately establish long-term and comprehensive volcanic eruption records.
    Description: Published
    Description: 103706
    Description: 6A. Geochimica per l'ambiente e geologia medica
    Description: JCR Journal
    Keywords: Peri-Tyrrhenian explosive volcanism Mediterranean ; tephrochronology Marine ; tephrochronology Marine Isotope Stage 11
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 4
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    Parameterization of clinopyroxene growth kinetics via crystal size distribution (CSD) analysis: Insights into the temporal scales of magma dynamics at Mt. Etna volcano (2021)
    Elsevier
    Details
    Publication Date: 2023-11-16
    Description: There is increasing recognition that both textural and compositional changes of clinopyroxenes crystallizing from mafic alkaline magmas are the direct expression of complex dynamic processes extending over a broad range of spatial and temporal scales. Among others, supersaturation and relaxation phenomena play a key role in controlling the final crystal cargo of variably undercooled magmas erupted from active alkaline volcanoes. Following this line of reasoning, we have carried out isothermal- isobaric, decompression, and cooling rate experiments on a basalt interpreted as the parental magma of mafic alkaline eruptions at Mt. Etna volcano (Sicily, Italy). The main purpose is to reconstruct and quantify the textural changes (i.e., length of major and minor axes, surface area per unit volume, area fraction, and maximum growth rate) of clinopyroxene upon variable pressures (30-300 MPa), temperatures (1,050-1,100 °C), volatile contents (0-5 wt.% H 2 O and 0-0.2 wt.% CO 2 ), and equilibration times (0.25-72 h). By integrating experimental data and thermodynamic modeling, the transition between interface-controlled (euhedral morphologies) and diffusion- controlled (anhedral morphologies) growth regimes has been determined at an undercooling threshold value of ~33 °C. Early melt supersaturation causes the fast growth of tiny clinopyroxenes with strong disequilibrium shapes, whereas an increasing relaxation time leads to the slow growth of large clinopyroxenes showing textural equilibration. According to these kinetic principles, both growth rate and relaxation time have been parameterized in relation to the crystal size distribution (CSD) analysis of naturally undercooled clinopyroxenes erupted during 2011-2012 lava fountain episodes at Mt. Etna volcano. Results indicate that the crystallization of microlites and microphenocrysts takes place under (dis)equilibrium growth conditions, in the order of ~10 0 -10 1 min (large undercooling, short equilibration time) and ~10 1 -10 2 h (small undercooling, long equilibration time), respectively. This temporal information allows to disentangle the cooling and decompression paths of Etnean magmas rising and accelerating along a vertically extended, highly dynamic plumbing system. While clinopyroxene microlites develop during the fast ascent of magmas (~10 0 -10 1 m s -1 ) within the uppermost part of the conduit or immediately before ejection from the vent, the onset of microphenocryst crystallization occurs at depth and continues within the plumbing system during the slow ascent of magmas (~10 -2 m s -1 ) that migrate through interconnected storage regions.
    Description: Published
    Description: 106225
    Description: 3V. Proprietà chimico-fisiche dei magmi e dei prodotti vulcanici
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 5
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    Soils developed on the Si-poor, alkali-rich pyroclastic rocks of the Colli Albani volcanic district (Central Italy): The effect of leucite, clinopyroxene and phlogopite on the base cations mobility (2023)
    Elsevier
    Details
    Publication Date: 2023-03-31
    Description: The Colli Albani volcanic district emplaced huge pyroclastic-flow deposits up to 20 m thick in the southeastern suburbs of the City of Rome. The soil quality onto the gentle slopes of the Colli Albani has certainly contribute to the growth of Ancient Rome, a city with one million inhabitants as early as 2000 years ago. Interestingly, the Colli Albani soils developed on K-foiditic pyroclastic rocks with peculiar low silica, high alkali and high CaO composition. In the past, the productivity of the Colli Albani soils was maximized without the understanding of the unique physical, chemical, and mineralogical properties of these soils; now an in-depth knowledge of the Colli Albani soils is necessary to respond to the current and increasingly demand of sustainable soil use.
    Description: Published
    Description: 105430
    Description: 6A. Geochimica per l'ambiente e geologia medica
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 6
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    Experimental measurements of the viscosity and melt structure of alkali basalts at high pressure and temperature (2023)
    Nature PG
    Details
    Publication Date: 2023-03-31
    Description: Volcanic eruptions are shallow phenomena that represent the final stage of density- and viscositydriven processes of melt migration from source rocks at upper mantle depths. In this experimental study, we investigated the effect of pressure (0.7–7.0 GPa) and temperature (1335–2000 °C) on the viscosity and the atomic melt structure of a synthetic anhydrous primitive alkaline basalt, an analogue of the pre-eruptive magma that likely feeds the Campi Flegrei Volcanic District at present day. Obtained viscosities (0.5–3.0 Pa s), mobility (0.1–0.4 g cm3 Pa− 1 s− 1) and ascent velocity (1.5–6.0 m yr− 1) are presented to support geochemical and geophysical observations of Campi Flegrei as a critical volcanic district currently undergoing gradual magma recharge at depth.
    Description: Published
    Description: 2599
    Description: 3V. Proprietà chimico-fisiche dei magmi e dei prodotti vulcanici
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 7
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    A review of plagioclase growth rate and compositional evolution in mafic alkaline magmas: Guidelines for thermometry, hygrometry, and timescales of magma dynamics at Stromboli and Mt. Etna (2024)
    Elsevier
    Details
    Publication Date: 2024-03-26
    Description: Mafic alkaline magmas, such as those feeding the persistent eruptive activity of Stromboli and Mt. Etna volcanoes in Italy, are dominated by the crystallization of plagioclase via cooling and degassing phenomena related to the dynamics of shallow crustal reservoirs and eruptive conduits. Because plagioclase textures and compositions are extremely sensitive to the changes of intensive variables in subvolcanic plumbing systems, the phenomenological variability of erupted crystals preserves detailed evidence of complex growth histories. From this point of view, we reappraise the textural maturation and compositional complexity of plagioclase by allying thermodynamic and kinetic principles to natural and experimental observations, with the purpose of drawing up guidelines for reconstructing magma dynamics in mafic alkaline volcanic settings. A multifaceted statistical method is adopted to parameterize the decay of crystal growth rate with increasing crystallization time, as relaxation kinetics prevails over melt supersaturation effects. This model parameterization is combined with the textural analysis of natural plagioclase crystals to quantify the residence time of phenocrysts in equilibrium with magmas at Stromboli and Mt. Etna and/or the timescale of rapid microlite growth during disequilibrium ascent of magmas within the conduit. The role played by temperature and melt-water content on plagioclase components and major cation substitution mechanisms is also evaluated under both isobaric-isothermal and decompression conditions. The emerging paradigm is that the influence of dissolved water on anorthite-albite exchange between plagioclase and melt is overwhelmingly mitigated by changes in temperature at conditions of P = 30–300 MPa, T = 1050–1150 °C, fO2 = NNO + 1.9-NNO + 2.3, and melt-H2O = 0.6–4.4 wt%. As a corollary, anorthite and albite melt activities are almost fully encapsulated in the variation of anhydrous melt components as the crystallization of plagioclase proceeds during magma cooling. Following this line of reasoning, we propose an integrated modeling approach to decipher complex zoning patterns in natural plagioclase phenocrysts from mafic alkaline eruptions. Key findings from our re-assessment of equilibrium, thermometric, and hygrometric models indicate that temperature and dissolved water can be iteratively estimated for different plagioclase textural patterns if crystals are sufficiently strongly zoned and probability-based criteria are applied to determine the maximum probability distribution from kernel density analysis.
    Description: Natural Environment research Council UK grant NE/T009292/1; INGV Progetti Ricerca Libera 2019 Grant #52/2020; INGV Departmental Strategic Project UNO; PRIN MIUR Grant #2017J277S9_004.
    Description: Published
    Description: 104399
    Description: OSV2: Complessità dei processi vulcanici: approcci multidisciplinari e multiparametrici
    Description: JCR Journal
    Keywords: Mafic alkaline magmas ; Plagioclase growth rate parameterization ; Plagioclase-based thermometry and hygrometry ; 04.08. Volcanology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 8
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    The Italian Quaternary volcanism (2024)
    AIQUA
    Details
    Publication Date: 2024-03-13
    Description: The peninsular and insular Italy are punctuated by Quaternary volcanoes and their rocks constitute an important aliquot of the Italian Quaternary sedimentary successions. Also away from volcanoes itself, volcanic ash layers are a common and frequent feature of the Quaternary records, which provide us with potential relevant stratigraphic and chronological markers at service of a wide array of the Quaternary science issues. In this paper, a broad representation of the Italian volcanological community has joined to provide an updated comprehensive state of art of the Italian Quaternary volcanism. The eruptive history, style and dynamics and, in some cases, the hazard assessment of about thirty Quaternary volcanoes, from the northernmost Mt. Amiata, in Tuscany, to the southernmost Pantelleria, in Sicily Channel, are here reviewed in the light of the substantial improving of the conceptual models, methodological approaches and the overall knowledge made in the last decades in the volcanological field study. We hope that the prest review can represent an useful and agile document summarising the knowledege on the Italian volcanism at the service of the Quaternary community operating in central Mediterranean area.
    Description: Published
    Description: 221-284
    Description: OSV2: Complessità dei processi vulcanici: approcci multidisciplinari e multiparametrici
    Description: N/A or not JCR
    Keywords: Stratigraphy, Geochronology, geochemistry, Quaternary volcanism, eruptive history, Italy ; 04.08. Volcanology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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