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  • 1
    Publication Date: 2022-10-21
    Description: © The Author(s), 2020. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Haumann, F. A., Moorman, R., Riser, S. C., Smedsrud, L. H., Maksym, T., Wong, A. P. S., Wilson, E. A., Drucker, R., Talley, L. D., Johnson, K. S., Key, R. M., & Sarmiento, J. L. Supercooled Southern Ocean waters. Geophysical Research Letters, 47(20), (2020): e2020GL090242, doi:10.1029/2020GL090242.
    Description: In cold polar waters, temperatures sometimes drop below the freezing point, a process referred to as supercooling. However, observational challenges in polar regions limit our understanding of the spatial and temporal extent of this phenomenon. We here provide observational evidence that supercooled waters are much more widespread in the seasonally ice‐covered Southern Ocean than previously reported. In 5.8% of all analyzed hydrographic profiles south of 55°S, we find temperatures below the surface freezing point (“potential” supercooling), and half of these have temperatures below the local freezing point (“in situ” supercooling). Their occurrence doubles when neglecting measurement uncertainties. We attribute deep coastal‐ocean supercooling to melting of Antarctic ice shelves and surface‐induced supercooling in the seasonal sea‐ice region to wintertime sea‐ice formation. The latter supercooling type can extend down to the permanent pycnocline due to convective sinking plumes—an important mechanism for vertical tracer transport and water‐mass structure in the polar ocean.
    Description: F. A. H. was supported by the Swiss National Science Foundation (SNSF; Schweizerischer Nationalfonds zur Förderung der wissenschaftlichen Forschung) grant numbers P2EZP2_175162 and P400P2_186681. This work was supported by the National Science Foundation (NSF) Southern Ocean Carbon and Climate Observations and Modeling (SOCCOM) Project under the NSF Award PLR‐1425989. R. M. would like to thank the National Oceanic and Atmospheric Administration (NOAA) GFDL for mentorship and computational support. S. R. was also supported by the U.S. Argo grant and NOAA grant NA15OAR4320063 to the University of Washington. L. H. S. thanks the Fulbright Foundation for the U.S.‐Norway Arctic Chair grant. We are deeply thankful to the large number of scientists, technicians, and funding agencies contributing to these databases, being responsible for the collection and quality control of the high‐quality data that form the basis of this work. We thank Josh Plant for his initial notification on very low temperatures observed in some of the float profiles. We would also like to thank the students, teachers, and schools who are participating in the SOCCOM Adopt‐a‐Float program. Four of the floats used in this study were adopted and have a clear signal of supercooling. These participants are listed in Table S1.
    Keywords: Southern Ocean ; Supercooling ; Sea ice ; Ice shelf ; Observations ; Convection
    Repository Name: Woods Hole Open Access Server
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  • 2
    Publication Date: 2022-10-26
    Description: Author Posting. © American Geophysical Union, 2020. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Reviews of Geophysics 58(3), (2020): e2019RG000672, doi:10.1029/2019RG000672.
    Description: Global sea level provides an important indicator of the state of the warming climate, but changes in regional sea level are most relevant for coastal communities around the world. With improvements to the sea‐level observing system, the knowledge of regional sea‐level change has advanced dramatically in recent years. Satellite measurements coupled with in situ observations have allowed for comprehensive study and improved understanding of the diverse set of drivers that lead to variations in sea level in space and time. Despite the advances, gaps in the understanding of contemporary sea‐level change remain and inhibit the ability to predict how the relevant processes may lead to future change. These gaps arise in part due to the complexity of the linkages between the drivers of sea‐level change. Here we review the individual processes which lead to sea‐level change and then describe how they combine and vary regionally. The intent of the paper is to provide an overview of the current state of understanding of the processes that cause regional sea‐level change and to identify and discuss limitations and uncertainty in our understanding of these processes. Areas where the lack of understanding or gaps in knowledge inhibit the ability to provide the needed information for comprehensive planning efforts are of particular focus. Finally, a goal of this paper is to highlight the role of the expanded sea‐level observation network—particularly as related to satellite observations—in the improved scientific understanding of the contributors to regional sea‐level change.
    Description: The research was carried out in part at the Jet Propulsion Laboratory, California Institute of Technology, under a contract with the National Aeronautics and Space Administration. The authors acknowledge support from the National Aeronautics and Space Administration under Grants 80NSSC17K0565, 80NSSC170567, 80NSSC17K0566, 80NSSC17K0564, and NNX17AB27G. A. A. acknowledges support under GRACE/GRACEFO Science Team Grant (NNH15ZDA001N‐GRACE). T. W. acknowledges support by the National Aeronautics and Space Administration (NASA) under the New (Early Career) Investigator Program in Earth Science (Grant: 80NSSC18K0743). C. G. P was supported by the J. Lamar Worzel Assistant Scientist Fund and the Penzance Endowed Fund in Support of Assistant Scientists at the Woods Hole Oceanographic Institution.
    Keywords: Sea level ; Satellite observations ; Remote sensing
    Repository Name: Woods Hole Open Access Server
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  • 3
    Publication Date: 2022-10-26
    Description: Author Posting. © American Geophysical Union, 2021. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Global Biogeochemical Cycles 35(4), (2021): e2020GB006895, https://doi.org/10.1029/2020GB006895.
    Description: The Amazon River drains a diverse tropical landscape greater than 6 million km2, culminating in the world's largest export of freshwater and dissolved constituents to the ocean. Here, we present dissolved organic carbon (DOC), organic and inorganic nitrogen (DON, DIN), orthophosphate (PO43−), and major and trace ion concentrations and fluxes from the Amazon River using 26 samples collected over three annual hydrographs. Concentrations and fluxes were predominantly controlled by the annual wet season flood pulse. Average DOC, DON, DIN, and PO43− fluxes (±1 s.d.) were 25.5 (±1.0), 1.14 (±0.05), 0.82 (±0.03), and 0.063 (±0.003) Tg yr−1, respectively. Chromophoric dissolved organic matter absorption (at 350 nm) was strongly correlated with DOC concentrations, resulting in a flux of 74.8 × 106 m−2 yr−1. DOC and DON concentrations positively correlated with discharge while nitrate + nitrite concentrations negatively correlated, suggesting mobilization and dilution responses, respectively. Ammonium, PO43−, and silica concentrations displayed chemostatic responses to discharge. Major and trace ion concentrations displayed clockwise hysteresis (except for chloride, sodium, and rubidium) and exhibited either dilution or chemostatic responses. The sources of weathered cations also displayed seasonality, with the highest proportion of carbonate- and silicate-derived cations occurring during peak and baseflow, respectively. Finally, our seasonally resolved weathering model resulted in an average CO2 consumption yield of (3.55 ± 0.11) × 105 mol CO2 km−2 yr−1. These results represent an updated and temporally refined quantification of dissolved fluxes that highlight the strong seasonality of export from the world's largest river and set a robust baseline against which to gauge future change.
    Description: This work was supported by a grant from the Harbourton Foundation to R. G. M. Spencer and R. M. Holmes. T. W. Drake was supported by ETH Zurich core funding to J. Six. R. G. M. Spencer was additionally supported by NSF OCE-1333157.
    Description: 2021-09-15
    Keywords: Amazon river ; Dissolved organic carbon ; Fluxes ; Weathering ; Geochemistry
    Repository Name: Woods Hole Open Access Server
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  • 4
    Publication Date: 2022-10-26
    Description: Author Posting. © American Geophysical Union, 2021. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters 48(10), (2021): e2021GL092904, https://doi.org/10.1029/2021GL092904.
    Description: We report marine dissolved organic carbon (DOC) concentrations, and DOC Δ14C and δ13C values in seawater collected from the Southern Ocean and eastern Pacific GOSHIP cruise P18 in 2016/2017. The aging of 14C in DOC in circumpolar deep water northward from 69°S to 20°N was similar to that measured in dissolved inorganic carbon in the same samples, indicating that the transport of deep waters northward is the primary control of 14C in DIC and DOC. Low DOC ∆14C and δ13C measurements between 1,200 and 3,400 m depth may be evidence of a source of DOC produced in nearby hydrothermal ridge systems (East Pacific Rise).
    Description: This work was supported by NSF (OCE-1458941 and OCE-1951073 to Ellen R. M. Druffel), Fred Kavli Foundation, Keck Carbon Cycle AMS Laboratory, NSF/NOAA funded GO-SHIP Program, Canada Research Chairs program (to Brett D. Walker) and American Chemical Society Petroleum Research Fund New Directions (55,430-ND2 to Ellen R. M. Druffel and Brett D. Walker).
    Description: 2021-11-24
    Keywords: 13C ; Carbon cycle ; Circumpolar deep water ; Dissolved inorganic carbon ; Dissolved organic carbon ; Radiocarbon
    Repository Name: Woods Hole Open Access Server
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  • 5
    Publication Date: 2022-05-27
    Description: Author Posting. © American Geophysical Union, 2021. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Global Biogeochemical Cycles 35(6), (2021): e2021GB006938, https://doi.org/10.1029/2021GB006938.
    Description: As climate-driven El Niño Southern Oscillation (ENSO) events are projected to increase in frequency and severity, much attention has focused on impacts regarding ecosystem productivity and carbon balance in Amazonian rainforests, with comparatively little attention given to carbon dynamics in fluvial ecosystems. In this study, we compared the wet 2012 La Niña period to the following normal hydrologic period in the Amazon River. Elevated water flux during the La Niña period was accompanied by dilution of inorganic ion concentrations. Furthermore, the La Niña period exported 2.77 Tg C yr−1 more dissolved organic carbon (DOC) than the normal period, an increase greater than the annual amount of DOC exported by the Mississippi River. Using ultra-high-resolution mass spectrometry, we detected both intra- and interannual differences in dissolved organic matter (DOM) composition, revealing that DOM exported during the dry season and the normal period was more aliphatic, whereas compounds in the wet season and following the La Niña event were more aromatic, with ramifications for its environmental role. Furthermore, as this study has the highest temporal resolution DOM compositional data for the Amazon River to-date we showed that compounds were highly correlated to a 6-month lag in Pacific temperature and pressure anomalies, suggesting that ENSO events could impact DOM composition exported to the Atlantic Ocean. Therefore, as ENSO events increase in frequency and severity into the future it seems likely that there will be downstream consequences for the fate of Amazon Basin-derived DOM concurrent with lag periods as described here.
    Description: This work was partially supported by National Science Foundation grant OCE-1464396 to Robert G. M. Spencer and funding from the Harbourton Foundation to Robert G. M. Spencer, R. Max Holmes, and Bernhard Peucker-Ehrenbrink.
    Description: 2021-12-11
    Keywords: Amazon river ; carbon cycling ; dissolved organic carbon ; dissolved organic matter ; ENSO ; FT-ICR MS
    Repository Name: Woods Hole Open Access Server
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  • 6
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2020. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Oceans 125(5), (2020): e2019JC015920, doi:10.1029/2019JC015920.
    Description: A major surface circulation feature of the Arctic Ocean is the Transpolar Drift (TPD), a current that transports river‐influenced shelf water from the Laptev and East Siberian Seas toward the center of the basin and Fram Strait. In 2015, the international GEOTRACES program included a high‐resolution pan‐Arctic survey of carbon, nutrients, and a suite of trace elements and isotopes (TEIs). The cruises bisected the TPD at two locations in the central basin, which were defined by maxima in meteoric water and dissolved organic carbon concentrations that spanned 600 km horizontally and ~25–50 m vertically. Dissolved TEIs such as Fe, Co, Ni, Cu, Hg, Nd, and Th, which are generally particle‐reactive but can be complexed by organic matter, were observed at concentrations much higher than expected for the open ocean setting. Other trace element concentrations such as Al, V, Ga, and Pb were lower than expected due to scavenging over the productive East Siberian and Laptev shelf seas. Using a combination of radionuclide tracers and ice drift modeling, the transport rate for the core of the TPD was estimated at 0.9 ± 0.4 Sv (106 m3 s−1). This rate was used to derive the mass flux for TEIs that were enriched in the TPD, revealing the importance of lateral transport in supplying materials beneath the ice to the central Arctic Ocean and potentially to the North Atlantic Ocean via Fram Strait. Continued intensification of the Arctic hydrologic cycle and permafrost degradation will likely lead to an increase in the flux of TEIs into the Arctic Ocean.
    Description: Funding for Arctic GEOTRACES was provided by the U.S. National Science Foundation, Swedish Research Council Formas, French Agence Nationale de la Recherche and LabexMER, Netherlands Organization for Scientific Research, and Independent Research Fund Denmark. Data from GEOTRACES cruises GN01 (HLY1502) and GN04 (PS94) have been archived at the Biological and Chemical Oceanography Data Management Office (Biological and Chemical Oceanography Data Management Office (BCO‐DMO); https://www.bco-dmo.org/deployment/638807) and PANGAEA (https://www.pangaea.de/?q=PS94&f.campaign%5B%5D=PS94) websites, respectively. The inorganic carbon data are available at the NOAA Ocean Carbon Data System (OCADS; doi:10.3334/CDIAC/OTG.CLIVAR_ARC01_33HQ20150809).
    Description: 2020-10-08
    Keywords: Arctic Ocean ; Transpolar Drift ; trace elements ; carbon ; nutrients ; GEOTRACES]
    Repository Name: Woods Hole Open Access Server
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