ALBERT

Description: The uptake of anthropogenic CO2 by the oceans has led to a rise in the oceanic partial pressure of CO2, and to a decrease in pH and carbonate ion concentration. This modification of the marine carbonate system is referred to as ocean acidification. Numerous papers report the effects of ocean acidification on marine organisms and communities but few have provided details concerning full carbonate chemistry and complementary observations. Additionally, carbonate system variables are often reported in different units, calculated using different sets of dissociation constants and on different pH scales. Hence the direct comparison of experimental results has been problematic and often misleading. The need was identified to (1) gather data on carbonate chemistry, biological and biogeochemical properties, and other ancillary data from published experimental data, (2) transform the information into common framework, and (3) make data freely available. The present paper is the outcome of an effort to integrate ocean carbonate chemistry data from the literature which has been supported by the European Network of Excellence for Ocean Ecosystems Analysis (EUR-OCEANS) and the European Project on Ocean Acidification (EPOCA). A total of 185 papers were identified, 100 contained enough information to readily compute carbonate chemistry variables, and 81 data sets were archived at PANGAEA - The Publishing Network for Geoscientific & Environmental Data. This data compilation is regularly updated as an ongoing mission of EPOCA.

Description: The upper Tortonian Metochia marls on the island of Gavdos provide an ideal geological archive to trace variations in Aegean sediment supply as well as changes in the North African monsoon system. A fuzzy-cluster analysis on the multiproxy geochemical and rock magnetic dataset of the astronomically tuned sedimentary succession shows a dramatic shift in the dominance of 'Aegean tectonic' clusters to 'North African climate' clusters. The tectonic signature, traced by the starvation of the Cretan sediment, now enables to date the late Tortonian basin foundering on Crete, related to the tectonic break-up of the Aegean landmass, at c. 8.2 Ma. The synchronous decrease in the North African climate proxies is interpreted to indicate a change in the depositional conditions of the sink rather than a climatic change in the African source. This illustrates that interpretations of climate proxies require a multiproxy approach which also assesses possible contributions of regional tectonism.

Description: Fine-grained sediment depocenters on continental shelves are of increased scientific interest since they record environmental changes sensitively. A north-south elongated mud depocenter extends along the Senegalese coast in mid-shelf position. Shallow-acoustic profiling was carried out to determine extent, geometry and internal structures of this sedimentary body. In addition, four sediment cores were retrieved with the main aim to identify how paleoclimatic signals and coastal changes have controlled the formation of this mud depocenter. A general paleoclimatic pattern in terms of fluvial input appears to be recorded in this depositional archive. Intervals characterized by high terrigenous input, high sedimentation rates and fine grain sizes occur roughly contemporaneously in all cores and are interpreted as corresponding to intensified river discharge related to more humid conditions in the hinterland. From 2750 to 1900 and from 1000 to 700 cal a BP, wetter conditions are recorded off Senegal, an observation which is in accordance with other records from NW-Africa. Nevertheless, the three employed proxies (sedimentation rate, grain size and elemental distribution) do not always display consistent inter-core patterns. Major differences between the individual core records are attributed to sediment remobilization which was linked to local hydrographic variations as well as reorganizations of the coastal system. The Senegal mud belt is a layered inhomogeneous sedimentary body deposited on an irregular erosive surface. Early Holocene deceleration in the rate of the sea-level rise could have enabled initial mud deposition on the shelf. These favorable conditions for mud deposition occur coevally with a humid period over NW-Africa, thus, high river discharge. Sedimentation started preferentially in the northern areas of the mud belt. During mid-Holocene, a marine incursion led to the formation of an embayment. Afterwards, sedimentation in the north was interrupted in association with a remarkable southward shift in the location of the active depocenter as it is reflected by the sedimentary architecture and confirmed by radiocarbon dates. These sub-recent shifts in depocenters location are caused by migrations of the Senegal River mouth. During late Holocene times, the weakening of river discharge allowed the longshore currents to build up a chain of beach barriers which have forced the river mouth to shift southwards.

Description: The high-energy, low-accumulation NW Iberian shelf features three confined Holocene mud depocentres. Here, we show that the evolution of such depocentres follows successive steps. The flooding of inner shelf zones and river catchment areas by the late deglacial sea-level rise provided the precondition for shelf mud deposition. Following this, the Holocene deceleration of the sea-level rise caused a rapid refill of the accommodation space within river valleys. Subsequently, the export of major amounts of fines was initiated. The initial onset and loci of shelf mud deposition were related to deposition-favouring conditions in mid-shelf position or to the presence of morphological highs, which act as sediment traps by providing protection against stronger hydrodynamic energy. The detailed reconstruction of the Holocene depocentre evolution shows for the first time that the expansion of such shelf mud deposits cannot only occur by linear growth off the associated sediment source. Rather, they might develop around centres that are fully disconnected from the source of original sediment supply, and expand later into specific directions. Based on these differences and on the connection of the individual mud depocentres to the material source we propose a conceptual subdivision of the group "mid-shelf mud depocentres".

Description: Continental shelves represent areas of highest economical and ecological importance. Nevertheless, these sedimentary systems remain poorly understood due to a complex interplay of various factors and processes which results in highly individual construction schemes. Previous studies of sedimentary shelf systems have mainly focused on a limited number of cores, retrieved from Holocene fine-grained depocentres. As such, the relation between shelf architecture and sedimentary history remains largely obscure. Here, we present new data from the NW Iberian shelf comprising shallow-seismic profiles, a large number of sediment cores, and an extended set of radiocarbon dates to reveal the Late Quaternary evolution of a low-accumulation shelf system in detail. On the NW Iberian shelf, three main seismic units are identified. These overly a prominent erosional unconformity on top of the basement. The lowermost Unit 1 is composed of maximal 75-m thick, Late Tertiary to Pleistocene deposits. The youngest sediments of this unit are related to the last glacial sea-level fall. Unit 2 was controlled by the deglacial sea-level rise and shows a maximum thickness of 15 m. Finally, Unit 3 comprises deposits related to the late stage of sea-level rise and the modern sea-level highstand with a thickness of 4 m in mid-shelf position. Two pronounced seismic reflectors separate these main units from each other. Their origin is related to (1) exposure and ravinement processes during lower sea level, and (2) to reworking and re-deposition of coarse sediments during subsequent sea-level rise. According to the sediment core ground-truthing, sediments of the Late Tertiary to Pleistocene unit predominantly display homogenous fine sands with exceptional occurrences of palaeosols that indicate an ancient exposure surface. Fine sands which were deposited in the run of the last sea-level rise show a time-transgressive retrogradational development. The seismic reflectors, bounding the individual units, appear in the cores as 0.1 to 1-m thick deposits consisting either of shell gravels or siliceous coarse sands with gravels. The modern sea-level highstand stage is characterised by zonal deposition of mud forming a mud belt in mid-shelf position, and sediment starvation on outer shelf zones. Radiocarbon ages indicate that this mud belt was the main depocentre for river-supplied fine material on the NW Iberian shelf at least over the past 5.32 ka BP. The initial onset of this depocentre is proposed to be related to a shift in the balance between rate of sea-level rise and amount of terrigenous sediment supply. Various other stratigraphical shelf reconstructions reveal analogies in architecture which indicate that timing and shaping of the individual units on low-accumulation shelves is fundamentally controlled by eustatic sea-level changes. Other factors of local importance such as differential elevation of the basement and the presence of morphological barriers formed by rocky outcrops on the seafloor have additionally modifying influence on the sedimentary processes.