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  • Chemical Engineering  (108)
  • 1985-1989  (108)
  • 1980-1984
  • 1960-1964
  • 1987  (108)
  • 1
    Electronic Resource
    Electronic Resource
    Facilitated transport of CO2 in ion exchange membranes (1987)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 480-487 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The facilitated transport of CO2 through ion exchange membranes containing organic amine counterions was studied. Steady state CO2 fluxes were measured from pure gas streams and mixtures with CH4. Facilitation factors for CO2 up to 26.7 were calculated from transport data. Transport measurements were binary mixtures of CO2 and CH4 yielded ratios of CO2 flux to CH4 flux ranging from 29.0 to 264. Conversion of flux ratios to permeabilities yielded separation factors up to 551 for CO2 over CH4, which are compared to literature data for polymeric membranes. The transport data support a mobile, reactive-carrier facilitated transport mechanism with a carbamate zwitterion complex. Effective diffusivities for CO2 and the carrier-gas complex were determined from transport data. A reaction equilibrium model predicted facilitation factors that were in very good agreement with experimental values. Potential applications are also discussed.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690330313
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  • 2
    Electronic Resource
    Electronic Resource
    Novel reinforced reaction injection molding (RRIM) processing: Computer-controlled multiple-stream RRIM production of interpenetrating polymer networks and polyurethanes (1987)
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 27 (1987), S. 1209-1215 
    Details
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A four-stream computer-controlled reinforced reaction injection molding (RRIM) machine has been developed that attains high accuracy in dispense ratios throughout the injection period. This machine has been used for novel processing of polyurethanes, offering a route to varying product properties either throughout a shot or on a shotto-shot basis. It also has been used for what appears to be the first production on commercial scale RRIM equipment of a polyurethane-acrylic interpenetrating polymer network (IPN) in commercial cycle times of around 2 min.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pen.760271602
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  • 3
    Electronic Resource
    Electronic Resource
    Unsteady heat convection over circular cylinders (1987)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 19-25 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Numerical calculations of the velocity and temperature fields were conducted for unsteady flows over a single circular cylinder and a bundle of cylinders. Periodic disturbances, natural or externally imposed, were considered. Periodic and averaged heat transfer rates were examined. Results compare favorably with experimental data. Calculations were carried out to predict heat transfer rates in regimes of unsteady flows that have not been tested experimentally.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690330104
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  • 4
    Electronic Resource
    Electronic Resource
    Estimating the relative acid site density of silica-alumina by infrared spectroscopy using a selective reactant poison (1987)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 336-340 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690330226
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  • 5
    Electronic Resource
    Electronic Resource
    Effect of solids on oxygen transfer in agitated three-phase systems (1987)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 1542-1549 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A dynamic response method was used to measure the volumetric mass transfer coefficient for oxygen in a mechanically agitated vessel containing an aqueous suspension of 66 μm glass beads. At constant stirring speed and superficial gas velocity the volumetric gas transfer coefficient kLa was found to decrease with solids loading. A generalized equation correlated the results in terms of the volume concentration of the solids, the total power input per slurry volume, and the superficial gas velocity.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690330914
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  • 6
    Electronic Resource
    Electronic Resource
    A new simplified model for adsorption in a single particle (1987)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 1397-1400 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690330819
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  • 7
    Electronic Resource
    Electronic Resource
    Application of LQ and IMC controllers to a packed-bed reactor (1987)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 1496-1506 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A practical application of advanced, model-based, multivariable control to a pilot plant packed-bed reactor carrying out highly exothermic butane hydrogenolysis reactions is presented. The system is first stabilized by using butane flow rate to control the reactor hot-spot temperature. Propane production and butane conversion are then controlled using multivariable controllers that manipulate the hot-spot temperature set point and hydrogen flow rate. The controller designs are based on multivariable transfer function models developed using multivariable time series and process identification methods.Two types of multivariable controllers are applied. The first is an internal model controller (IMC) utilizing a stabilized approximation of the model inverse and a tunable exponential filter. The second is a linear-quadratic (LQ) controller design using pulse transfer function models to characterize the process dynamics and autoregressive-moving average models to characterize the disturbances. The optimal control solution was arrived at via a spectral factorization solution to the Wiener-Hopf equations. The results indicate that both designs, if well tuned, provide good performance and robustness over a wide range of operation.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690330909
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  • 8
    Electronic Resource
    Electronic Resource
    An image-carrying fiber optic probe to investigate solids distribution around an immersed surface in a gas-fluidized bed (1987)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 672-676 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690330416
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  • 9
    Electronic Resource
    Electronic Resource
    Drag reduction in two-phase gas-liquid flows (1987)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 351-352 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690330229
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  • 10
    Electronic Resource
    Electronic Resource
    Effect of pore-distributed coke on catalyst regeneration kinetics (1987)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 940-951 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Prior experimental study by Haldeman and Botty has demonstrated that catalyst regeneration rates vary with conversion, showing a nearly constant rate of reaction in the early stages of regeneration and falling off rapidly at higher conversion levels. This peculiar reaction behavior calls for explanation in terms of pore structural changes. In this work a mathematical model is developed based on the interaction between catalyst pore structure and coke distribution in the pores. The model is able to associate overall regeneration kinetics with alternative pore-distributed coke deposition patterns. Results exhibit a slight shallow rate maximum at an intermediate conversion level, in agreement with the prior experimental report. The model makes coke distribution in the pores accessible to experimental determination. The numerical results indicate that among pore structures with the same mean and overall pore volume, a larger variance offers a higher threshold for coke loading; for a given degree of dispersion, a smaller mean allows a higher coke loading.
    Additional Material: 14 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690330607
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