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  • 1990-1994  (28)
  • 1960-1964  (13)
  • 1994  (28)
  • 1964  (13)
  • 1
    Electronic Resource
    Electronic Resource
    Evidence of a 50-year increase in tropospheric ozone in Upper Bavaria (1994)
    Springer
    Annales geophysicae 12 (1994), S. 1197-1206 
    Details
    ISSN: 0992-7689
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract In a series of ozone-sonde soundings at the Hohenpeißenberg observatory, starting in 1967, the most striking features are increases of \sim2.2% per year in all tropospheric heights up to 8 km during the past 24 years. These facts have recently been published and discussed by several authors. In this paper, we present some evidence for the increase of tropospheric ozone concentrations during the past 50 years 1940–1990 in the territory of the northern edge of the Bavarian Alps, including the Hohenpeißenberg data. In December 1940 and August 1942, probably the first exact wet-chemical vertical soundings of ozone up to 9 km height were made by an aircraft in the region mentioned. These results were published in the earlier literature. We have converted the results of the flights on 4 days in December 1940 and on 6 days in August 1942 to modern units and have compared them with the Hohenpeißenberg ozone-sonde data of the December and August months. We also compared the data at the ground with the August results of Paris-Montsouris 1886-1898. Our results show an increase of ozone concentration at all tropospheric heights in Upper Bavaria during the past 50 years, compared with the Montsouris data in August during the past 105 years. In the recently published papers, the increases since 1967 were approximated linearly.Our results, extended to the past, show non-linear trends, with steeper increases since 1975-1979. Possible reasons for these findings are discussed. Quite recently (in case of the December months since 1986/87, the August months since 1990), the ozone mixing ratios at and above Hohenpeißenberg seem to have decreased.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/s00585-994-1197-7
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  • 2
    Electronic Resource
    Electronic Resource
    Optical and Photoelectrical Properties of Microcrystalline Silicon Layers in Relation to Structural Ordering (1994)
    s.l. ; Stafa-Zurich, Switzerland
    Solid state phenomena Vol. 37-38 (Mar. 1994), p. 387-392 
    Details
    ISSN: 1662-9779
    Source: Scientific.Net: Materials Science & Technology / Trans Tech Publications Archiv 1984-2008
    Topics: Physics
    Type of Medium: Electronic Resource
    URL: http://www.tib-hannover.de/fulltexts/2011/0528/02/25/transtech_doi~10.4028%252Fwww.scientific.net%252FSSP.37-38.387.pdf
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  • 3
    Electronic Resource
    Electronic Resource
    Buchbesprechungen (1964)
    Springer
    Colloid & polymer science 198 (1964), S. 101-111 
    Details
    ISSN: 1435-1536
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF01499465
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  • 4
    Electronic Resource
    Electronic Resource
    Baryon asymmetry from a two stage electroweak phase transition? (1994)
    Springer
    The European physical journal 64 (1994), S. 105-109 
    Details
    ISSN: 1434-6052
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract We investigate an extension of the Standard Model with a second Higgs doublet, showing a two stage phase transition. Wash-out of a baryon asymmetry after the phase transition can be easily avoided in this class of models.B+L transitions are more strongly suppressed in the intermediate phase than in the high temperature symmetric phase, however. Therefore, it becomes more difficult if not impossible to generate a sufficient baryon asymmetry during the phase transition.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF01557241
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  • 5
    Electronic Resource
    Electronic Resource
    Chain stiffness of poly-methoxypropyl[1.1.1]propellane (1994)
    Weinheim : Wiley-Blackwell
    Acta Polymerica 45 (1994), S. 389-391 
    Details
    ISSN: 0323-7648
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The chain stiffness of a methoxypropyl-substituted poly[1.1.1]propellane in solution is investigated by static and dynamic light scattering. The Kuhn statistical segment length is determined as lk=150Å utilizing the Kratky-Porod wormlike chain model. It is, however, not yet clear whether the derived Kuhn length characterizes the chain stiffness of a perfect polypropellane chain or rather originates from “kinks” in the polymer backbone due to the presence of possible side reactions during polymerization.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/actp.1994.010450510
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  • 6
    Electronic Resource
    Electronic Resource
    141. Entwicklung einer in verschiedenen organischen Modellösungen resistenten strahlenchemisch modifizierten Nanofiltrationsmembran (1994)
    Weinheim : Wiley-Blackwell
    Chemie Ingenieur Technik - CIT 66 (1994), S. 1244-1244 
    Details
    ISSN: 0009-286X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cite.3306609142
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  • 7
    Electronic Resource
    Electronic Resource
    Heterogeneous suspension polymerization of vinyl chloride: Phase distribution and evolution (1994)
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 34 (1994), S. 532-540 
    Details
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A model for the phase distribution and evolution of the heterogeneous (suspension) polymerization of vinyl chloride is presented. Experimental information on pressure, temperature, and conversion has been obtained from a 34 liter bench reactor reproducing reaction conditions and product properties typical of industrial operation. A calculation procedure based on simple plant data is proposed for the description of the phase compositions and their evolution over the entire process. Results based on classical Flory-Huggins theory of solutions are presented and compared with existing data.
    Additional Material: 14 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pen.760340612
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  • 8
    Electronic Resource
    Electronic Resource
    Zur Identität der aus Thioschwefelsäure mit Dichlordisulfan und aus Thioschwefelsäure mit salpetriger Säure hergestellten Tetrasulfandisulfonate und zur Existenz eines „Saueren“ Tetrasulfan-disulfonats (1964)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 330 (1964), S. 179-187 
    Details
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: The product prepared following the method of GOEHRING and FELDMANN from H2S2O3 and S2Cl2 is not a „spectrum“ of different salts as stated by WEITZ and BECKER, but really K2S6O6, which is also prepared from H2S2O3 and HNO2. Tetrasulfane-disulfonate does not only exist in the neutral form K2S6O6, but also in a „acid“ form with a part of the potassium - nonstoichiometrically - replaced by H+. The two forms have different shape and X-ray spectra.
    Notes: Bei dem nach GOEHRING und FELDMANN aus H2S2O3 und S2Cl2 dargestellten Produkt handelt es sich nicht, wie von WEITZ und BECKER angegeben, um ein „Spektrum“ verschiedener Salze, sondern um einheitliches K2S6O6, wie es auch aus H2S2O3 und HNO2 erhalten wird. Tetrasulfan-disulfonat existiert neben der neutralen Form K2S6O6 noch in einer „saueren“ Form, bei der ein Teil des Kaliums - nichtstöchiometrisch - durch H+ ersetzt ist. Die beiden Formen unterscheiden sich in Aussehen und Röntgenspektrum voneinander.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19643300310
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  • 9
    Electronic Resource
    Electronic Resource
    Versuche zur Trennung von Sulfan-disulfonaten mit Hilfe von Anionenaustauschern (1964)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 330 (1964), S. 188-194 
    Details
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: The separation of sulfane-disulfonates, sulfite and thiosulfate by anion-exchangers has been studied. Whereas K2S6O6 is decomposed on the column, the salts K2S3O6, K2S4O6 and K2S5O6 may be separated quantitatively.
    Notes: Die Trennung von Sulfan-disulfonaten, Sulfit und Thiosulfat mit Anionenaustauschern wird untersucht. Während K2S6O6 auf der Säule zu rasch zerfällt, lassen sich die Salze K2S3O6, K2S4O6 und K2S5O6 quantitativ voneinander trennen.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19643300311
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  • 10
    Electronic Resource
    Electronic Resource
    Thiolyse von Sulfurylchlorid (1964)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 330 (1964), S. 130-140 
    Details
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: The reaction of hydrogen sulfide with sulfuryl chloride in the ratio 2:1 leads in benzene solution to hydrogen chloride, water, sulfur, and disulfur monoxide, S2O, which is surprisingly stable under the prevailing conditions. The reaction of sulfuryl chloride with liquid hydrogen sulfide leads to the formation of sulfanes and chlorosulfanes, respectively, besides other products, depending on the molar ratio H2S:SO2Cl2.
    Notes: Schwefelwasserstoff reagiert mit Sulfurylchlorid beim molaren Einsatz 2:1 in benzolischer Lösung unter Bildung von Chlorwasserstoff, Wasser, Schwefel und Dischwefelmonoxid S2O, das unter den herrschenden Reaktionsbedingungen überraschend stabil ist. Mit flüssigem Schwefelwasserstoff bildet SO2Cl2 im Unterschuß u. a. Sulfane, im Überschuß Chlorsulfane.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19643300304
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