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Chain stiffness of poly-methoxypropyl[1.1.1]propellane (1994)

Lassale, I. ; Schmidt, M. ; Schlüter, A. D.

Weinheim : Wiley-Blackwell

Acta Polymerica 45 (1994), S. 389-391

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ISSN: 0323-7648

Keywords: Chemistry ; Polymer and Materials Science

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology , Physics

Notes: The chain stiffness of a methoxypropyl-substituted poly[1.1.1]propellane in solution is investigated by static and dynamic light scattering. The Kuhn statistical segment length is determined as lk=150Å utilizing the Kratky-Porod wormlike chain model. It is, however, not yet clear whether the derived Kuhn length characterizes the chain stiffness of a perfect polypropellane chain or rather originates from “kinks” in the polymer backbone due to the presence of possible side reactions during polymerization.

Additional Material: 2 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/actp.1994.010450510

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