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  • Chemistry  (213)
  • Physics
  • STRUCTURAL MECHANICS
  • ASTROPHYSICS
  • Wiley-Blackwell  (213)
  • 1970-1974
  • 1960-1964  (213)
  • 1962  (213)
Collection
Publisher
  • Wiley-Blackwell  (213)
Years
  • 1970-1974
  • 1960-1964  (213)
Year
  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 8 (1962), S. 659-662 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Mass transfer rates and flooding limits are basic to the use of packed columns for liquid-liquid extraction. The input of pulsing energy increases transfer rates and promotes counterflow of the two phases. The wetting characteristics of the packing influence performance.The toluene-benzoic acid-water system was used to observe the performance of a 2-in. diam. column containing ceramic (hydrophilic) rings, polyethylene (hydrophobic) rings, or a sieve-plate cartridge. The packed columns showed lower flooding limits than the plate column, but polyethylene packing gave highest transfer rates and capacities. The pulsing energy input was much lower for the plastic packing to effect a higher transfer rate.Flooding limits for the pulsed, packed columns were lower than for packed columns which were not pulsed. Columns packed with rings so that the ratio of diameter to packing size was 4:1 gave higher flooding limits and better performance than a ratio of 8:1. The use of the two types of packing in alternating bands resulted in a performance intermediate between that of each packing employed separately, and no advantage was indicated in reference to flooding limits or transfer rates.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 8 (1962), S. 708-710 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 1 Tab.
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  • 3
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 8 (1962), S. 123-126 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Experimental data were determined for drag coefficients on fluid bubbles rising in a saturated packed bed and in clear liquids. Air and benzene were used to form bubbles in glycerine solution, water, and normal heptane. One-inch diameter glass spheres in hexagonal, random, and cubic packings constituted the bed. The range in Reynolds number was from 0.1 to 1,000. It was found that the drag coefficients in the hexagonal and random arrays were from two to three times those in clear liquids, while the drag on bubbles rising in cubic packings was the same as that for clear liquids. The method of correlation involved the use of the minor diameter in the drag coefficient and the major diameter in the Reynolds number. This innovation improved the correlation for bubble rise in clear liquids.
    Additional Material: 7 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 8 (1962), S. 418-420 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Tab.
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  • 5
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für die chemische Industrie 74 (1962), S. 39-39 
    ISSN: 0044-8249
    Keywords: Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    Journal of Polymer Science 62 (1962), S. S123 
    ISSN: 0022-3832
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Additional Material: 1 Tab.
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  • 7
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    Journal of Polymer Science 61 (1962), S. 353-359 
    ISSN: 0022-3832
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Regularly alternating polyesteramides with glycol components ranging from C2 to C14 and interamide linkages ranging from 2 to 6 have been prepared by high-temperature polycondensation of performed bisesteramides with sodium hydrogen tetrabutyltitanate as catalyst.
    Additional Material: 5 Ill.
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  • 8
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 13 (1962), S. 204-209 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Using auto-radiograms for the investigation of phenomena on metal surfacesFor the examination of boundary layer phenomena on solid surfaces, radio-active isotopes can be used with advantage. In this connection, the local distribution of radiating matter can be ascertained with the aid of auto-radiograms.The present article deals with the use of auto-radiograms for studying the separation and adsorption phenomena on metal surfaces. Special attention is paid to the influence of grain boundaries, displacements and orientations of the crystallites as well as the influence of macroscopic roughness on the adsorption of aqueous electrolyte solutions. The tests were carried out with β radiating isotopes 147 Pm and 204 T1.The auto-radiograms show that any zones of disturbance and any inhomogeneities on a solid metal surface are the first to be covered with radio-active substance. It is, for instance, found that increased adsorption takes place at grain boundaries and points of displacement. It is also shown that the separation is influenced by the orientation of the crystallites. The test results give rise to the conclusion that auto-radiograms can also be used for the clarification of other boundary layer phenomena.
    Notes: Zur Untersuchung von Grenzflächenvorgängen an festen Oberflächen werden mit Vorteil radioaktive Isotope eingesetzt. Die örtliche Verteilung des strahlenden Materials kann man dabei mit Hilfe der Autoradiographie feststellen.Die vorliegende Arbeit beschreibt die Verwendung der Autoradiographie beim Studium von Abscheide- und Adsorptionsvorgängen an Metalloberflächen. Insbesondere wird hier der Einfluß von Korngrenzen, Versetzungen und Orientierungen der Kristallite sowie makroskopischen Rauhigkeiten auf die Adsorption aus wäßrigen Elektrolytlösungen behandelt. Die Versuche wurden mit den β-strahlenden Isotopen 147Pm und 204T1 durchgeführt.Aufschlußreiche Autoradiographien zeigen, daß jede Störstelle und jede Inhomogenität an einer festen Metalloberfläche bevorzugt mit radioaktiver Substanz belegt wird. So beobachtet man z. B., daß an Korngrenzen und Versetzungen eine verstärkte Adsorption auftritt. Ferner wird gezeigt, daß die Orientierung der Kristallite die Abscheidung beeinflußt. Die Versuchsergebnisse weisen darauf hin, daß auch andere Grenzflächenvorgänge mit der Autoradiographie geklärt werden können.
    Additional Material: 7 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 13 (1962), S. 143-150 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Causes of scale formationContinuous operation of many appliances is impeded by scale formation which is most frequently encountered on heat transmitting surfaces. The present article deals with crystalline scale formed by dissolved substances on metallic materials.A theoretical section, dealing with the influence on scale formation of such factors as pressure, temperature, extraneous matter, flow velocity and condition of the solid surface, is followed by the description of experimental investigations.The phenomenon investigated as a model is the crystallisation in radioactively marked CaSo4 solution (Ca45 and S35, respectively). The experiments show, in keeping with the theory, that macroscope scale can only appear when the solution is over-saturated. There are no essential differences as between corrosive and non-corrosive materials, the formation of blisters on the solid surface tends to promote scale formation. In this connection, the roughness of the solid surface is likewise of importance. The experimental results give rise to certain practical conclusions.
    Notes: Durch die Verkrustung, die insbesondere and wärmeübertragenden Oberflächen auftritt, ist ein Dauerbetrieb mancher Apparate nur begrenzt möglich. Die vorliegende Arbeit behandelt kristalline Krusten, wie sie sich aus gelösten Stoffen an metallischen Werkstoffen bilden.Nach einem theoretischen Abschnitt, in dem der Einfluß des Druckes, der Temperature, fremder Stoffe, der Strömungsgeschwindigkeit der Lösung sowie der Zustand der festen Oberfläche auf die Krustenbildung diskutiert wird, werden experimentelle Untersuchungen beschrieben.Als Modellvorgang ist die Kristallisation aus radioaktiv markierten CaSo4- Lösungen (45Ca bzw. 35S) untersucht, Die Versuche zeigen in Übereinstimmung mit der Theorie, daß makroskopische Krusten erst bei einer übersättigten Lösung entstehen können. Wesentliche Unterschiede liegen zwischen korrodierenden und nicht korrodierenden Werkstoffen vor. Blasenbildung an der festen Oberfläche erhöht die Krustenbildung. Hierbei ist auch die Rauhigkeit der festen Oberfläche von Bedeutung. Aus den Versuchsergebnissen werden schließlich Folgerungen fü die Praxis gezogen.
    Additional Material: 15 Ill.
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