ISSN:
0044-2313
Keywords:
Potassium
;
magnesium
;
copper
;
vanadium
;
oxide
;
crystal structure
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Preparation and Crystal Structure of Potassium Magnesium Oxocuprate/-vanadate: KMg2Cu2V3O12.Single crystals of KMg2Cu2V3O12 were prepared by solid state reactions below the melting point of the reaction mixture (K2CO3, MgCO3, CuO, V2O5). It crystallizes with monoclinic symmetry space group C2h6—C2/c, a = 12.1592 Å, b = 12.7204 Å, c = 6.8557 Å, β = 111.73°, Z = 4. The structure type is characterized by VO4 tetrahedra, twisted CuO4 square units, MgO6 octahedra and a special 2 + 4 + 2 coordination around the potassium ion.
Notes:
Einkristalle von KMg2Cu2V3O12 wurden durch Feststoffreaktionen, dicht unterhalb des Schmelzpunktes des Reaktionsgemenges (K2CO3, MgCO3, CuO, V2O5), erhalten. Die Verbindung kristallisiert mit monokliner Symmetrie, Raumgruppe C2h6—C2/c, a = 12,1592 Å, b = 12,7204 Å, c = 6,8557 Å, β = 111,73°, Z = 4. Die Kristallstruktur ist durch VO4-Tetraeder, tordierte CuO4-Baugruppen, MgO6-Oktaeder und Kalium, in einer besonderen 2 + 4 + 2 Koordination charakterisiert.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/zaac.19936190402
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