ISSN:
1436-2449
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
,
Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
,
Physics
Notes:
Summary The polymerizations of styrene and alpha-methylstyrene in liquid sulfur dioxide have been investigated by the use of the slow, continuous monomer addition technique in the presence of m-chloroperbenzoic acid or CF3SO3H as initiator. Quasiliving polymerization has been obtained in Sty/MCPBA/−40°C/liquid SO2 system. The formed polymer is insoluble in the medium indicating that in liquid SO2 the propagating species remain active even in a heterogeneous system.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00271964
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