ISSN:
1436-2449
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
,
Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
,
Physics
Notes:
Summary The homopolymerization of 3-chlorothietane was accomplished using a variety of cationic initiators. Most successful was bulk polymerization at 0°C with ethyl trifiuoromethanesulfonate as initiator and with rapid stirring of the polymerizing mixture. Poly(3-chlorothietane) undergoes a facile structural rearrangement at 35°C in CD2Cl2, giving at equilibrium a copolymer containing 3-chlorothietane and (chloromethyl)thiirane repeating units in a ratio of approximately 6 to 4.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00254368
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