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  • 1
    Electronic Resource
    Electronic Resource
    Westerville, Ohio : American Ceramics Society
    Journal of the American Ceramic Society 87 (2004), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Weakly bonded particle mixtures of mullite and alumina are assessed as candidate matrixes for use in porous matrix ceramic composites. Conditions for the deflection of a matrix crack at a fiber-matrix interface are used to identify the combinations of modulus and toughness of the fibers and the matrix for which damage-tolerant behavior is expected to occur in the composite. Accordingly, the present study focuses on the modulus and toughness of the particle mixtures, as well as the changes in these properties following aging at elevated temperature comparable to the targeted upper-use temperature for oxide composites. Models based on bonded particle aggregates are presented, assessed, and calibrated. The experimental and modeling results are combined to predict the critical aging times at which damage tolerance is lost because of sintering at the particle junctions and the associated changes in mechanical properties. For an aging temperature of 1200°C, the critical time exceeds 10 000 h for the mullite-rich mixtures.
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  • 2
    Electronic Resource
    Electronic Resource
    Westerville, Ohio : American Ceramics Society
    Journal of the American Ceramic Society 84 (2001), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Effects of matrix cracks and the attendant interface debonding and sliding on both the longitudinal and the transverse thermal diffusivities of a unidirectional Nicalon/MAS composite are investigated. The diffusivity measurements are made in situ during tensile testing using a phase-sensitive photothermal technique. The contribution to the longitudinal thermal resistance from each of the cracks is determined from the longitudinal diffusivity along with measurements of crack density. By combining the transverse measurements with the predictions of an effective medium model, the thermal conductance of the interface (characterized by a Biot number) is determined and found to decrease with increasing crack opening displacement, from an initial value of ∼1 to ∼0.3. This degradation is attributed to the deleterious effects of interface sliding on the thermal conductance. Corroborating evidence of degradation in the interface conductance is obtained from the inferred crack conductances coupled with a unit cell model for a fiber composite containing a periodic array of matrix cracks. Additional notable features of the material behavior include: (i) reductions of ∼20% in both the longitudinal and the transverse diffusivities at stresses near the ultimate strength, (ii) almost complete recovery of the longitudinal diffusivity following unloading, and (iii) essentially no change in the transverse diffusivity following unloading. The recovery of the longitudinal diffusivity is attributed to closure of the matrix cracks. By contrast, the degradation in the interface conductance is permanent, as manifest in the lack of recovery of the transverse diffusivity.
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  • 3
    Electronic Resource
    Electronic Resource
    Westerville, Ohio : American Ceramics Society
    Journal of the American Ceramic Society 85 (2002), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The present article focuses on changes in the mechanical properties of an all-oxide fiber-reinforced composite following long-term exposure (1000 h) at temperatures of 1000–1200°C in air. The composite of interest derives its damage tolerance from a highly porous matrix, precluding the need for an interphase at the fiber–matrix boundary. The key issue involves the stability of the porosity against densification and the associated implications for long-term durability of the composite at elevated temperatures. For this purpose, comparisons are made in the tensile properties and fracture characteristics of a 2D woven fiber composite both along the fiber direction and at 45° to the fiber axes before and after the aging treatments. Additionally, changes in the state of the matrix are probed through measurements of matrix hardness by Vickers indentation and through the determination of the matrix Young's modulus, using the measured composite moduli coupled with classical laminate theory. The study reveals that, despite evidence of some strengthening of the matrix and the fiber–matrix interfaces during aging, the key tensile properties in the 0°/90° orientation, including strength and failure strain, are unchanged. This strengthening is manifested to a more significant extent in the composite properties in the ±45° orientation, wherein the modulus and the tensile strength each exhibit a twofold increase after the 1200°C aging treatment. It also results in a change in the failure mechanism, from one involving predominantly matrix damage and interply delamination to one which is dominated by fiber fracture. Additionally, salient changes in the mechanical response beyond the maximum load suggest the existence of an optimum matrix strength at which the fracture energy in the ±45° orientation attains a maximum. The implications for long-term durability of this class of composite are discussed.
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  • 4
    Electronic Resource
    Electronic Resource
    Westerville, Ohio : American Ceramics Society
    Journal of the American Ceramic Society 81 (1998), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Continuous fiber ceramic composites (CFCCs) based on oxides are of interest for high-temperature applications owing to their inherent oxidative stability. An enabling element is a matrix with an optimum combination of toughness and strength, which may be achieved by incorporating a controlled amount of fine, well-distributed porosity. Implementation of this concept by vacuum infiltration of aqueous mullite-alumina slurries into two-dimensional woven preforms of alumina fibers has been investigated. Evaluation of these materials shows stress-strain characteristics similar to other CFCCs, especially carbon-matrix composites. Moreover, promising notch and creep properties have been found. Microstructural and processing issues relevant to the attainment of these behaviors are discussed.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Westerville, Ohio : American Ceramics Society
    Journal of the American Ceramic Society 80 (1997), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Hybrid laminar composites that are comprised of alternating layers of ceramic sheets and fiber-reinforced ceramic-matrix composite (CMC) layers exhibit attractive mechanical properties, including a high first cracking stress and a high strain to failure. To achieve these properties, a strong bond must exist between the ceramic and CMC layers; otherwise, delamination will occur readily between the layers. The present study focuses on the delamination resistance of such laminates at ambient and elevated temperatures. The delamination resistance of interfaces that have been subjected to mixed-mode loading has been measured for two different hybrid composites by using edge-notched flexure specimens. At low temperatures, delamination occurs by a process that involves multiple matrix cracking within the CMC layers normal to the fibers, followed by cracking of the matrix parallel to the fibers at or near the ceramic/CMC interface. The corresponding fracture energies are typically in the range of ∼100-300 J/m2—comparable to the delamination resistance of the CMC itself. At elevated temperatures, delamination occurs via cavitation and rupture of the matrix within the CMC layers at or near the ceramic/CMC interface, with an attendant loss in toughness (to ∼10-30 J/m2). The loss in toughness occurs most rapidly at temperatures that are close to the strain point of the matrix phase; this represents the life-limiting temperature for this class of composites.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Westerville, Ohio : American Ceramics Society
    Journal of the American Ceramic Society 83 (2000), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The thermal conductance of delamination cracks in a unidirectionally reinforced ceramic composite is investigated. A phase-sensitive photothermal technique is used to measure the crack conductance in situ under load. Special emphasis is given to the effects of the local crack opening displacement (δ). A crack conductance model that considers the contributions from both the air and the fibers within the crack is developed and compared with the measurements. Despite considerable scatter in the experimental data, the model adequately predicts the increased conductance that is associated with fiber bridging, as well as the overall trend that is observed with δ.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Westerville, Ohio : American Ceramics Society
    Journal of the American Ceramic Society 81 (1998), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The stress rupture characteristics of an enhanced Nicalon/SiC composite at 900°C have been examined. This temperature has been identified as being in the regime wherein oxidation embrittlement is operative. The enhancement of the composite involves the use of a coating around the fiber tows, comprising a C-rich matrix and B-containing particulates. The efficacy of this oxidation protection scheme has been evaluated by comparing the stress rupture characteristics with those of both Nicalon/SiC composites without the enhancement and the fibers alone. Such comparisons indicate that a substantial portion of the strength loss is attributable to a degradation of the fibers, and that the performance of the enhanced material is marginally better than that of the reference (nonenhanced) composite. Moreover, at stress levels greater than the matrix cracking limit, oxidation embrittlement occurs rapidly and the rupture times (several hours) are short in relation to the targeted service lives of most ceramic composite components. The mechanisms associated with the embrittlement have been identified using scanning electron microscopy and Auger spectroscopy.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Westerville, Ohio : American Ceramics Society
    Journal of the American Ceramic Society 84 (2001), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The in-plane fracture resistance of a crossply Si3N4/BN fibrous monolith in the 0°/90° and ±45° orientations is examined through tests on notched flexure specimens. The measurements and observations demonstrate the importance of fiber pullout following fiber fracture. The mechanical response is modeled using a crack-bridging approach. Two complementary approaches to evaluating the bridging law are developed: one based on a micromechanical model of fiber pullout and the other based on the load versus crack mouth opening displacement response of the flexure specimens following fracture of all fibers. Both approaches indicate that the bridging law follows an exponential form, characterized by a bridging strength and an effective pullout length. An assessment of the bridging model is made through comparisons of simulations of the load–displacement response with those measured experimentally.
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  • 9
    Electronic Resource
    Electronic Resource
    Westerville, Ohio : American Ceramics Society
    Journal of the American Ceramic Society 84 (2001), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The effects of matrix porosity on the mechanical properties of an all-oxide ceramic composite are investigated. The porosity is varied through impregnation and pyrolysis of a ceramic precursor solution. Mechanical tests are performed to assess the role of the matrix in both matrix-dominated and fiber-dominated loading configurations. The results demonstrate a loss in damage tolerance and tensile strength along the fiber direction as the porosity is reduced. Concomitantly, some improvements in interlaminar strength are obtained. The latter improvements are found to be difficult to quantify over the entire porosity range using the standard short beam shear method, a consequence of the increased propensity for tensile fracture as the porosity is reduced. Measurements of interlaminar shear strength based on the double-notched shear specimen are broadly consistent with the limited values obtained by the short beam shear method, although the former exhibit large variability. In addition, effects of precursor segregation during drying on through-thickness gradients in matrix properties and their role in composite performance are identified and discussed. An analysis based on the mechanics of crack deflection and penetration at an interphase boundary is presented and used to draw insights regarding the role of matrix properties in enabling damage tolerance in porous-matrix composites. Deficiencies in the understanding of the mechanisms that enable damage tolerance in this class of composites are discussed.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Westerville, Ohio : American Ceramics Society
    Journal of the American Ceramic Society 82 (1999), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The effects of circular holes and sharp notches on the tensile strength of two Nicalon-reinforced ceramic composites have been investigated. The influence of inelastic straining on the redistribution of stress has been elucidated through measurements of the local strains in the regions of high stress concentration, coupled with finite element simulations of the test geometries, using a nonlinear constitutive law appropriate to ceramic composites. The scale dependence of strength has been inferred from tests performed on specimens of varying size. The utility of two failure models that incorporate both the inelastic straining and the scale dependence has been assessed: one based on the point stress failure criterion and the other on weakest-link fracture statistics. Both approaches provide a reasonably consistent description of the experimental measurements. Some of the implications and limitations associated with the failure models are discussed.
    Type of Medium: Electronic Resource
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