ISSN:
1572-8854
Keywords:
Ag(mela)2ClO4
;
hydrogen bond
;
weak bond
Source:
Springer Online Journal Archives 1860-2000
Topics:
Geosciences
,
Physics
Notes:
Abstract The crystal structure of the title compound, Ag(mela)2ClO4 (mela = melamine), has been investigated by X-ray diffraction techniques, the crystals are triclinic, space group P1¯, with a = 5.236(2), b = 7.5385(9) c = 19.063(3) Å, α = 99.91(1), β = 90.53(2), γ = 108.32(2)° and Z = 2. The Ag atom has a coordination geometry with two strong bonds (2.162(2) and 2.179(4) Å) to the nitrogen of the melamines and two weak bonds (2.776(4) and 2.785(4) Å) to oxygen atoms of the ClO− 4anions. The N—Ag—N vector is markedly nonlinear (angle at Ag 167.7(2)°).
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1023/A:1009590631734
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