ISSN:
1600-5368
Source:
Crystallography Journals Online : IUCR Backfile Archive 1948-2001
Topics:
Chemistry and Pharmacology
,
Geosciences
,
Physics
Notes:
The structure of the title compound, [Co2(C8H18Sn2)(CO)6], a distannyl-substituted dicobaltatetrahedrane, shows geometrical parameters noticeably different from those observed in the only monostannyl-substituted dicobaltatetrahedrane structurally studied so far. Thus, the complexed acetylenic bond in the title compound is shorter, and the cobalt–cobalt and cobalt–carbon bonds are longer, while the Sn—C—C angles are much smaller than in the complex with monostannyl-substituted ligand.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1107/S1600536801016154
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