Publication Date:
2012-02-23
Description:
The title compound, {[Cd4(C5H2N2O4)(C5HN2O4)2(C10H8N2)2(H2O)]·2H2O}n, crystallized in the monoclinic space groupP21/nand displays a three-dimensional architecture. The asymmetric unit is composed of four crystallographically independent CdIIcentres, two triply deprotonated pyrazole-3,5-dicarboxylic acid molecules, one doubly deprotonated pyrazole-3,5-dicarboxylic acid molecule, two 2,2′-bipyridine ligands, one coordinated water molecule and two interstitial water molecules. Interestingly, the CdIIcenters exhibit two different coordination numbers. Two CdIIcentres adopt a distorted octahedral arrangement and a third a trigonal–prismatic geometry, though they are all hexacoordinated. However, the fourth CdIIcenter is heptacoordinated and displays a pentagonal–bipyramidal geometry. The three anionic ligands adopt μ3-, μ4- and μ5-bridging modes, first linking CdIIcenters into a one-dimensional wave-like band, then into a wave-like layer and finally into a three-dimensional coordination framework, which is stabilized by hydrogen bonds.
Print ISSN:
0108-2701
Electronic ISSN:
1600-5759
Topics:
Chemistry and Pharmacology
,
Geosciences
,
Physics
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