ISSN:
1600-5759
Source:
Crystallography Journals Online : IUCR Backfile Archive 1948-2001
Topics:
Chemistry and Pharmacology
,
Geosciences
,
Physics
Notes:
The title complex, [La2(C6H7)4(C6H5S)2(C4H8O)2]·2C4H8O, is a centrosymmetric dimer bridged through the S atoms of the benzenethiolate ligands. The bridging La2S2 unit is completely planar, while the geometry around the nine-coordinate La atom is that of a distorted trigonal bipyramid. The La—S—La and S—La—S angles are 117.51 (4) and 62.5 (1)°, respectively, and the average La—S bond length is 2.9759 Å. The crystals contain two tetrahydrofuran solvate molecules for every complex molecule.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1107/S0108270100017996
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