Publication Date:
2017-06-02
Description:
S-heterocyclic dicarboxylic acid, thiophene-2,5-dicarboxylic acid (H 2 TDC), was employed to construct a series of lanthanide-organic frameworks ( Ln OFs) with coligand acetate, formulated as [ Ln (TDC)(OAc)(H 2 O)] n [ Ln = Eu ( 1 ), Tb ( 2 ), Gd ( 3 ), Dy ( 4 ), Sm ( 5 )] under hydrothermal conditions. Structure analysis reveals that 1 – 5 have dinuclear 3D metal organic frameworks (MOFs), in which TDC 2– and OAc – display (κ 1 -κ 1 )-(κ 1 –κ 1 )-μ 4 and (κ 2 -κ 1 )-μ 2 coordination fashions, respectively. The dehydrated products of all compounds show high thermal stability above 410 °C. As for 1 , 2 , 4 , and 5 , the photoluminescence analyses exhibit characteristic luminescence emission bands of the corresponding lanthanide ions in the visible region. In particular, compound 2 displays bright green luminescence in the solid state with 5 D 4 lifetime of 0.510 ms and relative high overall quantum yield of 16 %, based on an ideal energy gap between the lowest triplet state energy level of H 2 TDC ligand and the 5 D 4 state energy level of Tb 3+ . The energy transfer mechanisms in compounds 1 and 2 were also discussed.
Print ISSN:
0044-2313
Electronic ISSN:
1521-3749
Topics:
Chemistry and Pharmacology
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