ISSN:
1089-7690
Source:
AIP Digital Archive
Topics:
Physics
,
Chemistry and Pharmacology
Notes:
The vibronic spectra of vinyl chloride at 7.3–10 eV have been studied using 2+1 resonance-enhanced multiphoton ionization (REMPI) spectroscopy. The geometries and vibrational frequencies of vinyl chloride and its cation calculated with ab initio methods are utilized to compute the Franck–Condon factors. The transitions to the Rydberg states of π→ns, npσ, npπ, nd, nf, and nCl→3s are responsible for the observed REMPI spectra of vinyl chloride. The complex vibrational structures for the observed transitions are successfully identified with the aid of calculated Franck–Condon factors. © 2001 American Institute of Physics.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1063/1.1400786
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