ALBERT

All Library Books, journals and Electronic Records Telegrafenberg

feed icon rss

Your email was sent successfully. Check your inbox.

An error occurred while sending the email. Please try again.

Proceed reservation?

Export
  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Environmental geology 21 (1993), S. 62-69 
    ISSN: 1432-0495
    Keywords: Metal speciation ; Surficial sediments ; Scotland
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract The geochemical partitioning of ten elements in stratified Holocene sediments from Loch Dee, southwest Scotland, has been established by use of a five-stage sequential extraction procedure. Samples from below 15 cm sediment depth show minimal evidence of modification by anthropogenic contamination or active diagenesis and hold Fe, Mg, Cu, Cd, Co, Pb, and Ni primarily in detrital silicates or organic complexes, while Mn, Ca, and Zn reside largely in adsorbed and reducible oxide phases. In the uppermost ca 15 cm of sediment, enhanced total concentrations of Zn, Cu, and Pb reflect increased atmospheric deposition during the postindustrial period. Of these metals, only Pb displays any notable adjustment of partitioning in the enriched zone, showing disproportionate accumulation in labile oxides and organic-Pb phases. The lack of Pb and Zn carbonates in the “contaminated” horizon may reflect inherent thermodynamic instability under the acid surface and pore-water conditions of Loch Dee. Increments to total Mn and Co in the surficial ca 5 cm of sediment are attributable to the accumulation of secondary oxides and adsorbed species, consistent with precipitation from the interstitial pore-waters across a sedimentary redox front. The presence of metals such as Zn and Cd in soluble or acid-volatile phases in the interfacial sediment has implications for the future management of the Loch Dee basin, with leaching into the overlying waters likely, given the continuation of current trends of lake acidification.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Environmental geology 39 (2000), S. 272-278 
    ISSN: 1432-0495
    Keywords: Key words Acid mine drainage ; Hydrochemistry ; Modelling ; Zimbabwe
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract  Acid mine drainage (AMD) with a minimum pH of 0.52 was recorded at Iron Duke mine near Mazowe, Zimbabwe during an investigation of the environmental geochemistry of mine waters in the Greenstone Belts of Zimbabwe. Hydrochemical data for waters emanating from the Iron Duke waste-rock pile indicate their super-saturation with respect to Fe and SO4 2–. Extremely high dissolved concentrations of Al, Zn, Cu, Co, Ni, V, Cr, Cd and As also prevail. Substantial losses of metals from solution occur within 400 m of the AMD source through the precipitation of crystalline sulphates, principally melanterite. Further downstream, hydrous oxide precipitation forms the dominant mechanism of metal attenuation in waters characteristically under-saturated with respect to Fe sulphates. Speciation and saturation index data generated using the equilibrium model WATEQ4F, suggest that such codes have broad utility for generic prediction of the mineralogical contraints on metal mobility in acute AMD systems. Major discrepancies between modelled and empirical hydrochemistries are, however, evident for super-saturated waters in which the kinetics of Fe precipitation are slow, and in which total ionic strengths markedly exceed their theoretical maximum.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Environmental geology 20 (1992), S. 117-123 
    ISSN: 1432-0495
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract Integrated total elemental, phase-specific, and pore-water analyses of sediment cores from Loch Ba, Scotland, show that early diagenetic processes have promoted extensive metal enrichment immediately beneath the sediment-water interface. The accumulation of Mn, Pb, Zn, Cu, and Co in sedimentary solids upward of 3 cm depth is accompanied by an increasing residence of these elements in adsorbed and hydrous oxide phases. Such phases are formed through oxidative precipitation from the interstitial pore fluids, following the upward migration of metals from more deeply buried, anaerobic sectors of the sediment pile. There is good evidence that Fe and Ni are subject to similar influences, although their total abundances near the sediment surface are less conspicuously modified. In the Loch Ba sediments, the oxic conditions promoting metal precipitation are entirely confined to strata of postindustrial age. In the absence of fully diagnostic pore-water and sequential chemical data, similar diagenetic profiles could plausibly be misinterpreted as the product of anthropogenic contamination.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 4
    ISSN: 1432-0495
    Keywords: Key words Mercury ; Mining ; Contamination ; Philippines
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract  An integrated geochemical and toxicological assessment of environmental mercury contamination and attendant human exposure in Honda Bay, Palawan was undertaken in 1995 following a nationally reported pollution scare centered on a coastal jetty, Sitio Honda Bay, constructed using approximately 1 million tons of tailings and beneficiation waste from a cinnabar mine. Mercury (Hg) data for marine and fluvial sediments, fish tissues and human hair indicate that the toxicological hazard is considerably lower than initially reported by state environment and health officials. Typical Hg concentrations in surficial Honda Bay sediments were found to lie within the global background range (〈60 μg/kg). Downcore profiles provide no evidence of enhanced Hg fluxes coincident with the onset of mining and/or coastal tailings disposal. The mean and median Hg concentrations recorded in tissues of six species of Honda Bay fish are compliant with thresholds established by the US Environmental Protection Agency (US-EPA) for marketable stocks. Earlier reports of 'Minamata range' Hg concentrations in fish and shellfish from Honda Bay remain unsubstantiated. Geochemical analyses of samples of the Sitio Honda Bay substrate have confirmed the prevalence of solid-phase Hg concentrations to ca. 340 mg/kg. The speciation of Hg is, however, dominated by secondary oxides of low bioavailability. The mean Hg concentration in hair from Sitio Honda Bay residents (4.41 mg/kg) was found to be statistically analogous to that for a neighbouring coastal community unimpacted by the coastal disposal of mine waste. A negligible residential exposure factor is thus inferred for the former. Relatively high hair Hg burdens prevail throughout the coastal Honda Bay population, consistent with significant methyl Hg ingestion through daily fish consumption. The data presented provide no environmental or toxicological justification for immediate remedial action.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 5
    ISSN: 1432-1211
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Medicine
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 6
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Ground water 30 (1992), S. 0 
    ISSN: 1745-6584
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Geosciences
    Notes: A two-well tracer experiment was conducted in a coastal, sandy aquifer in South Carolina to investigate tracer migration in ground-water systems. Chloride tracer was injected into the aquifer under a steady flow condition created by continuous injection and withdrawal of ground water at an injection and a withdrawal well dipole separated by a distance of 5 meters. Breakthrough data were collected at several depths from two multilevel sampling wells, 1.5 meters apart, between the injection well and the withdrawal well.A one-dimensional advection-dispersion model that considers the nonuniform velocity field of the two-well experiment was employed to estimate the hydrologic properties of the aquifer. The values of the porosity and dispersivity were estimated by fitting the model to the observed breakthrough data collected at three depths at one sampling well (Well A). These values were then used to predict the breakthroughs at the same depths in the other sampling well (Well B). A two-dimensional flow and transport model was also employed to simulate the tracer migration. Results of both one- and two-dimensional simulations show that these models fail to predict the tracer breakthrough at Well B using parameter values obtained from Well A.The failure of the model to predict breakthroughs at Well B suggests that a three-dimensional characterization of aquifer heterogeneities and a three-dimensional modeling effort may be needed in order to capture the complex flow pattern in the aquifer.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 7
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    The @journal of organic chemistry 51 (1986), S. 2702-2706 
    ISSN: 1520-6904
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 8
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Marine mammal science 9 (1993), S. 0 
    ISSN: 1748-7692
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Biology
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 9
    Electronic Resource
    Electronic Resource
    Springer
    Stochastic environmental research and risk assessment 14 (2000), S. 8-32 
    ISSN: 1436-3259
    Keywords: Key words: wetland, elevation, scaling, stochastic, multifractal, intermittency.
    Source: Springer Online Journal Archives 1860-2000
    Topics: Architecture, Civil Engineering, Surveying , Energy, Environment Protection, Nuclear Power Engineering , Geography , Geosciences
    Notes: Abstract. The land surface elevation distribution will serve as fundamental input data to any wetland flow model. As an alternative to the traditional smooth function approach to represent or interpolate elevation data, we explore the use of Levy monofractals and universal multifractals as a means for defining a statistically equivalent topography. The motivation behind this effort is that fractals, like natural topography, are irregular, they offer a way to relate elevation variations measured at different scales, and the relationships are of a statistical nature. The study site was a riparian wetland near Savannah, GA, that contained beavers, and a total of four elevation transects were examined. The elevation increments showed definite non-Gaussian behavior, with parameter values, such as the Hurst coefficient and Lévy index (α), depending on the question of presence of beaver activity. It was obvious that the data were highly irregular, especially the transects influenced by beavers. Significantly different α values were obtained depending on whether the entire data set or just the tails were examined, which demonstrated inability of the monofractal model to reflect fully the irregularity of wetland data. Further analysis confirmed definite multifractal scaling, and it is concluded that the multifractal model is superior for this data set. Universal multifractal parameters are calculated and compared to those obtained previously for more typical terrain. Although it is difficult to consider a unique universal multifractal parameter α for the entire wetland, multifractal-like scaling was evident in each transect as reflected by the nonlinear behaviors of the scaling functions. We demonstrate a good agreement between theory and measurements up to a critical order of statistical moments, q D , close to 3.5 and obtain realistic unconditioned simulations of multifractal wetland topography based on our parameter estimates. Future work should be devoted to conditioning multifractal realizations to data and to obtaining larger data sets so that the question of anisotropy may be studied.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 10
    Electronic Resource
    Electronic Resource
    [s.l.] : Nature Publishing Group
    Nature 329 (1987), S. 42-45 
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] The samples were analysed by established methods22"24 and the results, presented in Table 1, show obvious discontinuities, both in the concentrations of the individual radionuclides and in the activity ratios, which suggest that the samples can (with the few exceptions discussed below) be grouped ...
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
Close ⊗
This website uses cookies and the analysis tool Matomo. More information can be found here...