ISSN:
0009-2940
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Preparation and X-Ray Structural Analysis of an Adamantyl-spirophosphorane, C10HI5P(O2C6H4)Reaction of (1-adamantyl)tetrafluorophosphorane with catechol bis(trimethylsilyl ether) yielded the spirophosphorane C10H15P(O2C6H4)2 (4). Crystals of 4 are orthorhombic. P212121, with a = 668.5 (1), b = 1575.8 (2), c = 1755.1 (2) pm, Z = 4, R = 0.058. C2v,-distorted rectangular pyramidal coordination is observed at phosphorus.
Notes:
Durch Umsetzung von (1-Adamantyl)tetrafluorphosphoran mit Brenzcatechin-bis(trimethylsilylether) wurde das Spirophosphoran C10H15P(O2C6H4)2 (4) erhalten. 4 kristallisiert orthorhombisch, P212121, mit a = 668.5 (1), b = 1575.8 (2), c = 1755.1 (2) pm, Z = 4,. R, = 0.058. Es wird C2v-verzerrte rechteckig-pyramidale Koordination am Phosphor gefunden.
Additional Material:
3 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19791120440
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