ISSN:
1573-8353
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract The oxidation of secondary and tertiaryα-hydroxylamino oximes with sodium hypobromite gives, respectively, furoxans and 3-bromo-1,2-diazetine 1,2-dioxides. The intermediate oxidation products, which confirm the proposed reaction mechanism, were isolated. When 3-bromo-1,2-diazetine 1,2-dioxides are heated in benzene, the ring opens with the evolution of nitrogen oxides and the formation of halo olefins.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00959952
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