ISSN:
0749-1581
Keywords:
Nitrosonaphthols
;
Dioxouranium(VI)
;
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The 1H and 13C NMR spectra of 1-nitroso-2-naphthol and its disodium 3,6-disulphonate, 2-nitroso-1-naphthol and its sodium 4-sulphonate and the complexes of the sulphonated ligands with dioxouranium(VI) were recorded and analysed. The results show the nitrosonaphthols exist predominantly in the oxime form, and that the 1-nitroso compounds have a preferred structure. The quinonoid oxygen does not take part in the complexation with dioxouranium(VI), which is effected by chelation through the oxime oxygen and nitrogen.
Additional Material:
5 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/mrc.1260240905
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