ISSN:
0018-019X
Keywords:
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
A study of photo-induced electron-transfer reactions in MeCN with 9,10-dicyanoanthracene as acceptor and 21 electron donors with transient photoconductivity measurements is reported. The free-ion yield and the rate constant of back electron transfer are determined. For exergonic reactions, the ‘Marcus-inverted’ region is observed. The fit with the theory is best, when a nearly solvent-independent Coulomb term is used in the calculation of the energy balance.
Additional Material:
4 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/hlca.19880710111
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