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  • 1
    Publication Date: 2011-08-19
    Description: Theoretical models suggest that the initial form of nitrogen in Titan's atmosphere may have been NH3. The possible importance of strong shocks produced during high-velocity impacts accompanying the late stages of accretion are investigated as a method for converting NH3 to N2, of which Titan's atmosphere is now primarily composed. The focused beam of a high-power laser is used to simulate the effects of an impact in Titan's atmosphere. For mixtures of 10, 50, and 90 percent NH3, yields of 0.25, 1, and 6 x 20 to the 17th molecules of N2 per joule, respectively, were obtained. It is also found that the yield of HCN is comparable to that for N2. Several other hydrocarbons are produced, many with yields in excess of theoretical high-temperature-equilibrium models. The above yields, when combined with models of the satellite's accretion, result in a total N2 production comparable to that present in TItan's atmosphere and putative ocean.
    Keywords: LUNAR AND PLANETARY EXPLORATION
    Type: Nature (ISSN 0028-0836); 332; 520-522
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  • 2
    Publication Date: 2011-08-19
    Description: In order to ascertain the features of organic compound-production in planetary atmospheres under the effects of plasmas and shocks, various mixtures of N2, CH4, and H2 modeling the atmosphere of Titan were subjected to discrete sparks, laser-induced plasmas, and UV radiation. The experimental results obtained suggest that UV photolysis from the plasma is an important organic compound synthesis process, as confirmed by the photolysis of gas samples that were exposed to the light but not to the shock waves emitted by the sparks. The thermodynamic equilibrium theory is therefore incomplete in the absence of photolysis.
    Keywords: LUNAR AND PLANETARY EXPLORATION
    Type: Icarus (ISSN 0019-1035); 81; 413-428
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