ISSN:
0170-2041
Keywords:
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Mesoionic Six-membered Heterocycles, III. - Reactions of o-Quinonoid Compounds with 6-Oxo-6H-1,3-diazin-1-ium-4-olatesMesoionic 6-oxo-6H-1,3-diazin-1-ium-4-olates 9 react with tetrachloro-o-benzoquinone (2, R = Cl) to give 1:1 adducts 12 which can formally be derived from ketene tautomers 13 of 9. The structure of 12f has been clarified by X-ray crystallography.
Notes:
Mesoionische 6-Oxo-6H-1,3-diazin-1-ium-4-olate 9 reagieren mit Tetrachlor-o-benzochinon (2, R = Cl) unter Bildung von 1:1-Addukten 12, die sich formal von den Ketentautomeren 13 von 9 ableiten. Die Struktur von 12f wurde durch eine Röntgenstrukturanalyse geklärt.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/jlac.198119810317
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