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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 394 (1972), S. 233-242 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: The sorption of Cd2+-ions on freshly precipitated Al(OH)3 cannot be explained as a counterion exchange, as would be generally expected for cations. It is shown by kinetic measurements, that the process of sorption is composed of two consecutive reactions, at least one of which must be a chemisorption process. Moreover, the sorption process is controlled by a pH-dependent reaction, which previously has reached its equilibrium state.
    Notes: Die Sorption von Cd2+-Ionen an gelartigem Aluminiumhydroxid ist nicht, wie allgemein für Kationen erwartet, als counterion-exchange aufzufassen. Kinetische Messungen zeigen, daß der Sorptionsvorgang aus zwei nacheinander ablaufenden Reaktionen erster Ordnung besteht, von denen zumindest die zweite eine Chemisorption darstellt. Ein pH-abhängiges Gleichgewicht ist der Sorption vorgelagert.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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