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  • 1
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Energy & fuels 2 (1988), S. 9-13 
    ISSN: 1520-5029
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Energy, Environment Protection, Nuclear Power Engineering , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Journal of food science 37 (1972), S. 0 
    ISSN: 1750-3841
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The caustic peeling rates of potatoes is considered from an analytical and experimental point of view. The analysis considers the process to be governed by the competing rates of mass transport within the potato (diffusion) and chemical reaction. The chemical reaction between caustic and chlorogenic acid is singled out for analysis since the product of this reaction is a yellow salt which is easily measured by calorimetry. Simplified equations for the concentration of the yellow salt as a function of time is obtained for the two limiting extremes of diffusion controlled rates and reaction controlled rates. Experiments on Idaho Russetts indicate that, over the first 2–3 min of immersion in caustic, the process is diffusion controlled. It is also shown that it is the outer skin which presents the large diffusion resistance. For reasonable times after this initial period the process is reaction controlled and very sensitive to temperature. The implications of these results with respect to processing techniques (e.g., the dry peel process) and sequences is considered and discussed.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Industrial & engineering chemistry research 26 (1987), S. 1628-1632 
    ISSN: 1520-5045
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Copenhagen : International Union of Crystallography (IUCr)
    Applied crystallography online 22 (1989), S. 150-154 
    ISSN: 1600-5767
    Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001
    Topics: Geosciences , Physics
    Notes: A new equation involving an absorption coefficient is presented for calculating the thickness of a layer of a crystalline specimen deposited on a crystalline substrate. This new equation is particularly applicable to in situ X-ray diffraction studies of diffusion-limited kinetics; it is demonstrated that the practical difficulty of optimally partitioning count time between the peak of the substrate and peak of the layered specimen is overcome by making use of all available data in this single equation. This can result in more precise thickness determinations for intermediate specimen thicknesses than would be possible with either of the existing methods.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Springer
    Journal of materials science 31 (1996), S. 1319-1325 
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Reaction kinetic studies of Ca3SiO5 formation from sol-gel-derived precursors were carried out in situ using dynamic X-ray diffraction. Infrared spectra data, TEM experimental results, and X-ray diffraction patterns, all confirmed that CaO and Ca2SiO4 are the only compounds formed from a stoichiometric gel prior to Ca3SiO5 formation (〈 1250 °C). The kinetic data for Ca3SiO5 formation are consistent with an Avrami nucleation and growth mechanism but with a sudden drop in the time exponent at higher conversion. The sharp drop of the exponent is attributed to the impingement of grain growth in the longitudinal direction and this is confirmed by SEM observations of the fully converted gels. The presence of 10% steam did not change the mechanism nor the activation energy of the reaction but significantly enhanced the nucleation and grain growth rate at both stages of the reaction.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 18 (1972), S. 792-797 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Sublimation drying is analyzed by considering coupled heat and mass transport at the ice-vapor interface. Since, the typical model of sublimation drying assumes a pseudo steady state heat transport limited process, these assumptions are critically analyzed to determine whether they are the cause of some of the limitations of the simplified model. It is shown that although total drying times can be substantially increased if there is heat leakage into the ice core and coupled heat and mass transport, this is not a problem in the conventional sublimation drying of foods. However, the results indicate that consideration of both coupled transport and heat leakage into the core result in time-varying ice temperatures which could exceed the triple point. In addition, the application of this analysis to the analogous heterogeneous chemical reaction problem is pointed out and appropriate conclusions can be drawn by inference.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Springer
    Journal of materials science 34 (1999), S. 3577-3580 
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Dynamic X-ray diffraction (DXRD) has been used in an effort to identify the specific phase changes which are responsible for observed thermal events at ∼980 °C in mullite gel precursors. Specifically, changes in the evolution of the common and strongest diffraction peak (d = 0.139 nm) corresponding to both transient alumina phases and the Al-Si spinel were followed in order to descriminate between these two phases. Results which compare the DXRD results for a diphasic mullite gel and a boehmite gel are presented and suggest that the Al-Si spinel phase forms at ∼980 °C in diphasic gels along with δ- and/or γ-Al2O3. These results are corroborated by separate TEM measurements which indicate the presence of both phases in samples quenched from 1000 °C.
    Type of Medium: Electronic Resource
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  • 8
    Publication Date: 1996-03-01
    Print ISSN: 0022-2461
    Electronic ISSN: 1573-4803
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Published by Springer
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  • 9
    Publication Date: 1994-08-01
    Description: SummaryExperiments were conducted in glasshouses at IRRI, Philippines, during 1987 and 1988 to identify varietal differences in apical development using six rice cultivars having extreme characters; Jirasar 280 (early senescence), Neo-Dunghan 1 (late senescence), Macunting (small seeds), ABB (large seeds), C12474–1 (long culm), and B581–A6–458 (short culm); and five cultivars, IR20, IR22, IR34, IR54, IR64, of the same growth duration.The length of time from physiological panicle initiation (PI) to flowering varied from 25 to 50 days. The onset of physiological PI occurred when the fourth penultimate leaf was fully exserted. The visual panicle initiation stage (VPI) coincided with spikelet differentiation in all cultivars. Nitrogen top-dressing at 55–57 days before the anticipated maturity date (the present N management recommendation) did not coincide with the actual panicle initiation stage in any of the cultivars and the major yield determinants (i.e. the primary and secondary branches) therefore differentiated in conditions of internal nitrogen shortage. Spikelet abortion took place both before and after flowering. Reduction of pre-flowering abortion is important in increasing rice grain yields and could be achieved by improved N management. It is important to recognise cultivar differences and periods of loss of potential yield in developing efficient N management protocols.
    Print ISSN: 0021-8596
    Electronic ISSN: 1469-5146
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
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  • 10
    Publication Date: 1989-04-01
    Description: A new equation involving an absorption coefficient is presented for calculating the thickness of a layer of a crystalline specimen deposited on a crystalline substrate. This new equation is particularly applicable to in situ X-ray diffraction studies of diffusion-limited kinetics; it is demonstrated that the practical difficulty of optimally partitioning count time between the peak of the substrate and peak of the layered specimen is overcome by making use of all available data in this single equation. This can result in more precise thickness determinations for intermediate specimen thicknesses than would be possible with either of the existing methods.
    Print ISSN: 0021-8898
    Electronic ISSN: 1600-5767
    Topics: Geosciences , Physics
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