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  • 1
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Macromolecules 13 (1980), S. 1487-1494 
    ISSN: 1520-5835
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Journal of food science 20 (1955), S. 0 
    ISSN: 1750-3841
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 1435-1536
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 17 (1979), S. 627-638 
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Sample charging phenomena arising in the ESCA experiment have been investigated for gold and polymer films of known thickness ranging from 5 Å to 20 μ deposited on gold either insulated from or in electrical contact with the spectrometer. Charging induced by a monochromatic x-ray source is typically an order of magnitude greater than that induced by a nonmonochromatized source and exhibits a marked time dependence. A novel source of secondary electrons which employs a low-power, low-pressure mercury lamp external to the spectrometer source chamber as an alternative to an electron flood gun is described, and the charging and biasing characteristics of polymer films as a function of film thickness are discussed and demonstrated to provide an extra informational dimension for the study of polymeric materials.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 15 (1977), S. 2843-2867 
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Electron mean free paths as a function of kinetic energy have been measured by the substrate overlayer technique for in situ-polymerized films of poly(p-xylylene) and the monochloro- and monobromo-substituted derivatives. The results are compared with previous estimates of mean free paths available in the literature for organic materials. Comparison is also drawn with corresponding experimental data for typical metals and semiconductors, and it is shown that organic polymers fit into a consistent picture which may be rationalized on the basis of existing theory. For electrons of kinetic energy ∼969 eV, ∼1170 eV, 1202 eV, and 1403 eV, mean free paths of ∼14 Å, ∼22 Å, ∼23 Å, and ∼29 Å, respectively, are obtained for the poly(p-xylylene) polymer films studied in this work.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 16 (1978), S. 1461-1474 
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Sample-charging phenomena arising in the ESCA experiment have been investigated for a series of polymers. For samples studied as films or powders mounted insulated from the spectrometer probe and for gold under similar conditions it is shown that over a wide range of operating conditions, equilibrium charging shifts are characteristic of the sample and show a strong dependence on the theoretically calculated total photoionization cross sections. The surface sensitivity of the phenomenon has been demonstrated by monitoring changes in charging shifts as a function of hydrocarbon contamination. For polymer films mounted directly in contact with the spectrometer, the charging shifts exhibit time-dependent behavior. The utility of studying sample-charging shifts as an interesting phenomenon in its own right is demonstrated by reference to changes which occur consequent upon surface modification of an ethylene-tetrafluoroethylene copolymer system in RF plasmas excited in inert gases.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 18 (1980), S. 1651-1664 
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The absolute and relative binding energies for the C1s, O1s, and F1s core levels have been determined using x-ray photoelectron spectroscopy (ESCA) for a series of aliphatic, aromatic, and fluorine-containing polycarbonates. Comparisons of these experimentally determined, core-level binding energies with theoretical calculations using the ground-state potential model in the CNDO/2 SCF MO formalism as well as model compounds have been made on the C1s and O1s core levels. The degree of polymerization for low-molecular-weight fluorine-containing polycarbonates, as determined from ESCA measurements, is compared to measurements by vapor-phase osmometry and 19F-NMR.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    International Journal for Numerical and Analytical Methods in Geomechanics 15 (1991), S. 417-431 
    ISSN: 0363-9061
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Geosciences
    Notes: This paper presents the results of the application of a numerical model of flow of water in unsaturated soil to simulate real field behaviour. Numerical predictions are compared with field-monitored results as part of an assessment of the approach adopted.The numerical approach is based on a finite element solution of Richards' theoretical formulation, adopting a finite difference recurrence relationship to model the transient nature of the problem. The field results have been collected by British Gas in Kimmeridge clay at a site in Swindon.The simulation addressed the autumn wetting of the soil during 1983. Comparisons of volumetric moisture content readings from the field and numerical predictions give good correlation. It is concluded that the numerical model has adequately represented field behaviour over the depth of interest. Taken in conjunction with previous results, it is claimed that the model should now be capable of use in a predictive mode.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 14 (1976), S. 1671-1700 
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The core and valence levels of a series of poly(alkyl acrylates) have been studied by ESCA. From an analysis of the individual component peaks for the C1s and O1s core levels and from comparison of relative area ratios it is shown that ESCA may be applied to the study of surface compositions. The evidence presented strongly suggests that on the ESCA depth-profiling scale the technique statistically sample the repeat units with no evidence for preferential orientation of side chains at the surface. For some samples, ESCA provides evidence for a degree of surface oxidation and hydrocarbon contamination. The valence energy levels are shown to be characteristic of the polymer system. The measured absolute and relative binding energies of the core levels have been compared with model calculations using the charge-potential model in the CNDO/2 SCF MO formalism.
    Additional Material: 16 Ill.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 14 (1976), S. 1701-1713 
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The core and valence energy levels of a series of poly(alkyl methacrylates) have been studied by ESCA. Surface compositions have been determined both from a comparison of area ratios for the O1s and C1s core levels and from the relative areas for the individual component peaks for these levels. The evidence presented suggests that on the ESCA depth-profiling scale the technique statistically samples the repeat unit with little or no evidence for preferential orientation of the alkyl side chain at the surface. Little evidence was found for either surface oxidation or hydrocarbon contamination at the surface of the samples studied. The valence energy levels are shown to be characteristic of the polymer system.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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