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  • 1
    ISSN: 1520-4995
    Source: ACS Legacy Archives
    Topics: Biology , Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    [s.l.] : Nature Publishing Group
    Nature 199 (1963), S. 73-74 
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] These processes were followed by allowing the segments to take up phenoxy-[l-14C]-acetic acid, followed by extraction of the tissue and a separation of the radioactive compounds by paper chromatography. A typical record of such a chromatogram is shown in Fig. 1, where it will be noted that the ...
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  • 3
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Physics of Plasmas 4 (1997), S. 678-689 
    ISSN: 1089-7674
    Source: AIP Digital Archive
    Topics: Physics
    Notes: How predictions of deuterium atomic reaction rates in tokamak divertors are altered by changes in cross section data which are comparable with the uncertainty in published data is investigated. An extended neutral diffusion theory calculation, which includes D atoms and ground and excited state D2 molecules, is performed on a fixed background plasma. For the atoms, the principal relevant mechanisms are elastic scattering, charge exchange, ionization, and recombination. It is evaluated that the charge exchange and electron processes are known to an accuracy better than +/−25%, and it is concluded that this level of accuracy is sufficient for the present state of divertor calculations. Of significant concern is the fact that classical elastic cross sections which are widely used in divertor calculations differ substantially from a more accurate set of cross sections based on quantum mechanics, and that the latter produce predictions of neutral density and ionization rate which differ by orders of magnitude from predictions based on the classical cross sections. Opacity of the plasma to Lyman alpha radiation influences transport for high density plasma situations. The explicit representation of incident particles recycling as molecules is shown to significantly affect the neutral atom density and reaction rates near the divertor plate. In particular, the dissociation of even a small fraction of excited molecules significantly reduces the plasma ion population and increases the neutral atom population just in front of the plate in nearly detached plasmas. © 1997 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Physics of Plasmas 2 (1995), S. 3740-3756 
    ISSN: 1089-7674
    Source: AIP Digital Archive
    Topics: Physics
    Notes: A formalism is developed that incorporates the anisotropic effects on the neutral atom and molecule transport of collisions with plasma ions flowing toward the divertor into Legendre representations of the scattering, charge-exchange, and recombination processes. These anisotropic directed flow effects and the anisotropic effects of neutral particles recycling from the divertor plate or streaming across low-density regions are incorporated into a differential transport formalism, which retains the computational advantages of an extended diffusion theory. The available collision and wall reflection data that are needed for implementation of the model for deuterium are reviewed, and recommended reaction rates and reflection coefficients are presented. Model problem calculations illustrate the importance of these anisotropic effects. © 1995 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Review of Scientific Instruments 67 (1996), S. 1216-1216 
    ISSN: 1089-7623
    Source: AIP Digital Archive
    Topics: Physics , Electrical Engineering, Measurement and Control Technology
    Notes: A simple, all permanent magnet, 2.45 GHz electron cyclotron resonance ion source has been developed for the production of stable beams of low charge state ions from gaseous feed materials. The source can produce ∼1 mA of low energy (3 kV) singly charged ion current in the 10−4 Torr pressure range. The source can also be operated in a more efficient low-pressure mode at an order of magnitude lower pressure. In this latter range, for example, the ionization efficiency of Ar is estimated to be 1% with charge states up to Ar8+ present. Operation in the low-pressure mode requires low power input (∼20 W). These features make the source especially suited for use with small accelerator systems for a number of applications including ion implantation, mass spectrometry, and atomic collision experiments where multiply charged ions are desirable. Design details and performance characteristics of the source are presented. © 1996 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Review of Scientific Instruments 67 (1996), S. 1634-1637 
    ISSN: 1089-7623
    Source: AIP Digital Archive
    Topics: Physics , Electrical Engineering, Measurement and Control Technology
    Notes: A simple, all permanent magnet, 2.45 GHz electron cyclotron resonance ion source has been developed for the production of stable beams of low charge state ions from gaseous feed materials. The source can produce ∼1 mA of low energy (3 kV) singly charged ion current in the 10−4 Torr pressure range. The source can also be operated in a more efficient low-pressure mode at an order of magnitude lower pressure. In this latter range, for example, the ionization efficiency of Ar is estimated to be 1% with charge states up to Ar8+ present. Operation in the low-pressure mode requires low power input (∼20 W). These features make the source especially suited for use with small accelerator systems for a number of applications including ion implantation, mass spectrometry, and atomic collision experiments where multiply charged ions are desirable. Design details and performance characteristics of the source are presented. © 1996 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    [s.l.] : Nature Publishing Group
    Nature 204 (1964), S. 884-885 
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] The following procedures were used for the isolation of the aglycones. The whole of the aerial portions of seedlings of P. vulgaris var. 'Canadian Wonder1, grown in a greenhouse for 12 days, were gathered and the cut ends immersed in a solution of 2,4-D-14C (30 mg/1.) at pIL 5 for 12 h in the ...
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  • 8
    Electronic Resource
    Electronic Resource
    [s.l.] : Nature Publishing Group
    Nature 204 (1964), S. 286-286 
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] The techniques used are the same as those already reported. All metabolites were isolated in mg quantities by solvent extraction followed by chromatography. Characterization of the metabolites or their derivatives was by comparison with authentic compounds. Phenoxyacetic acids with an ...
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  • 9
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    Journal of Raman Spectroscopy 8 (1979), S. 81-87 
    ISSN: 0377-0486
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Resonance Raman spectra of twenty parasubstituted azobenzene derivatives are compared, enabling a more complete assignment of bands to be made. Since all the spectra are rather similar, the various ring substituents are not resonance Raman active, and all the observed bands can be assigned to vibrational modes of the aromatic rings and to the azo group itself. Frequency shifts in the Ph—N stretching region are opposite to those expected based on delocalization along the Ph—N=N—Ph moiety. From the complexity of band pattern around the N=N stretching region and from the above described frequency shifts, several types of vibrational coupling are evident. On the basis of the band assignments, some useful conclusions can be reached for interpreting the observed spectral changes when azobenzene derivatives are used as chromophore probes in biochemical system studies.
    Additional Material: 5 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    Journal of Raman Spectroscopy 11 (1981), S. 209-214 
    ISSN: 0377-0486
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Resonance Raman spectra of azobenzene and some hydroxyazobenzene derivatives, in strong acid solution (HCI 6 M), are analysed. All the observed bands between 900 and 1700 cm-1 can be assigned to vibrational modes of the aromatic rings and the azo group, and give evidence for a trans azo type structure both for azobenzene and the para substituted hydroxyazobenzene derivatives studied. Resonance Raman spectra of six substituted 2-(4′- hydroxyphenylazo)-benzoic acid derivatives in strong acid solutions are investigated. The spectral features are rather different from the above studied hydroxyazobenzene derivatives, but can be explained on the basis of an azo type structure. A strong perturbation effect on the N=N stretching mode is demonstrated using deuterium substitution. From the complexity of frequency shifts obtained on deuterium substitution, vibrational coupling between NH bending and many other vibrational modes is evident. A tentative assignment of the observed resonance Raman bands is proposed.
    Additional Material: 6 Ill.
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