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  • 1
    ISSN: 1520-5827
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Journal of the American Chemical Society 115 (1993), S. 77-81 
    ISSN: 1520-5126
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    s.l. ; Stafa-Zurich, Switzerland
    Key engineering materials Vol. 329 (Jan. 2007), p. 755-760 
    ISSN: 1013-9826
    Source: Scientific.Net: Materials Science & Technology / Trans Tech Publications Archiv 1984-2008
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Deposition processes of conventional diamond films and smooth fine-grained diamondfilms on cemented tungsten carbide inserts (SCMT120408-HR, 6wt. %Co) in the hot filamentchemical vapor deposition (HFCVD) apparatus were investigated. A novel combined pretreatmentof Murakami’s reagent, acid etching and microwave plasma decarburization in Ar-H2 gas wascarried out. The adhesive strength of the films to the substrates, diamond-coated tool wear andsurface roughness of the workpiece were further studied by turning glass fiber reinforced plastics(GFRP) cylindrical bars. Scanning electron microscopy (SEM), X-ray diffraction (XRD), energydispersive X-ray spectroscopy (EDX), and Raman spectroscopy were employed to characterize thesubstrates and diamond films subjected to different pretreatments and deposition processes. Opticalmicroscope and surface scanning profilometer were utilized to monitor the evolution of tool wearand surface roughness of the workpiece respectively during the cutting test. The experimentalresults showed that the novel combined pretreatment was more effective in enhancing the adhesivestrength of diamond films to the substrate. Fine WC interlayer generated during the initial stage ofthe diamond film deposition played an important role in improving the adhesion. Diamond coatedtools subjected to such pretreatment demonstrated up to 6 times longer tool life than uncoated ones.Varied parameter deposition process produced smooth fine-grained diamond films, which led toremarkably lower surface roughness of the workpiece in turning GFRP
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    s.l. ; Stafa-Zurich, Switzerland
    Key engineering materials Vol. 329 (Jan. 2007), p. 545-550 
    ISSN: 1013-9826
    Source: Scientific.Net: Materials Science & Technology / Trans Tech Publications Archiv 1984-2008
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Despite great advancements in diamond thin film growth and deposition techniques,determination of the residual stress and Young’s modulus for diamond films has continued to be achallenge. The bulge test is a potentially powerful tool for characterizing the mechanical properties ofdiamond film. In a bulge tester, pressure is applied on a thin membrane and the out-of-planedeflection of the membrane center is measured. The Young’s Modulus and the residual stress aresimultaneously determined by using the load-deflection behavior of a membrane. By means ofelectron-enhanced hot filament chemical vapor deposition (HFCVD), a diamond film was depositedon silicon slice (100), and the free-standing window sample of diamond thin films was fabricated bymeans of photolithography and anisotropic wet etching. The deflection of the membranes is measuredusing a laser interferometry system. The elastic modulus and residual stress were measured using aself-designed bulge equipment. In addition, the distortion of diamond thin films under differentpressure was simulated using finite element analysis and the contrast was made with experimentaldata. The research indicated that the Young’s Modulus of diamond thin films is 937.8GPa and theresidual stress is -10.53MPa. The elastic modulus and the residual stress coincide with the report inthe literature and the value tested by X-ray diffraction, respectively. This method uses a simpleapparatus, and the fabrication of samples is very easy, and it has provided an effective means forprecise measure the mechanical properties of other thin films
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  • 5
    Electronic Resource
    Electronic Resource
    s.l. ; Stafa-Zurich, Switzerland
    Key engineering materials Vol. 329 (Jan. 2007), p. 551-556 
    ISSN: 1013-9826
    Source: Scientific.Net: Materials Science & Technology / Trans Tech Publications Archiv 1984-2008
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Adhesion properties of diamond thin films are essential to their performance in technicalapplications. To obtain the adhesive strength precisely and quantitatively has been the frontier issueto the related scientists and engineers. In this paper, a new experimental equipment for blister testswas designed purposely and fabricated considering related influencing facts. A free-standingwindow of diamond thin film with the support of silicon wafer was obtained by the aid ofphotolithography and anisotropic wet etching technology so as to improve the precision ofquantitative adhesion measures of diamond films. The mechanics for calculating the quantitativedriving force of blister-induced delamination of diamond thin film is presented, which is on base ofintensive modeling and simulation. The laser interferometer measurement with fine solution wasused to pick up dynamic signals of diamond thin film bulge deformation in micrometer scale andthe relationship demonstration of stress to strain of the diamond thin film was available, as aconsequence, the adhesive strength could be obtained precisely and quantitatively by the validmodel. The paper confirms the accessibility to precise quantitative adhesion measures of diamondfilms and the results will be beneficial to wide application of diamond thin films in the relatedfields
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    s.l. ; Stafa-Zurich, Switzerland
    Applied mechanics and materials Vol. 10-12 (Dec. 2007), p. 864-868 
    ISSN: 1662-7482
    Source: Scientific.Net: Materials Science & Technology / Trans Tech Publications Archiv 1984-2008
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Three-dimensional finite element simulations were used to investigate the influences ofvarious hot filaments and other deposition parameters on the temperature field of substrates whichaffect significantly the growth and quality of diamond films by hot filament chemical vapordeposition (HFCVD) and based on the simulation results, the optimum position for diamonddeposition was found. In the experiment, six cemented tungsten carbide inserts were used assubstrates and placed on the workbench in the CVD reactor to deposit diamond films. According tothe temperature distribution on substrates measured by thermocouple fixed in CVD reactor, thesimulations were validated and the optimum arrangement of substrates was established from thesimulation results. In addition, the simulation model was altered to optimize the process parametersof HFCVD deposition, and an improved process of depositing diamond films with high quality wasobtained in order to achieve the great surface morphology, which laid the foundation of developinga new method to arrange the substrates in the CVD reactor for depositing diamond films
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    s.l. ; Stafa-Zurich, Switzerland
    Advanced materials research Vol. 53-54 (July 2008), p. 397-402 
    ISSN: 1662-8985
    Source: Scientific.Net: Materials Science & Technology / Trans Tech Publications Archiv 1984-2008
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Heat-resistant steel F91, which has high heat-resistance, is widely used in valve and pipemanufacturing industry, but it is difficult to process due to its high strength and toughness. Toinvestigate the influence of cutting parameters on the machinability of F91, a series of millingexperiments based on uniform design were carried out. From the experimental data, an exponentialmodel of milling force was set up. The result of regress analyse showed that the model had a highconfidence degree. A group of optimized cutting parameters were obtained from the model for drycutting with TiAlX coated carbide milling cutter. Cutting with the optimized milling parameters,lower milling force, higher material removal rate and less tool wear could be obtained. Theprediction model showed a satisfactory agreement with those obtained from the experiments, so itcan be referenced in actual processes for F91
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    s.l. ; Stafa-Zurich, Switzerland
    Advanced materials research Vol. 53-54 (July 2008), p. 331-336 
    ISSN: 1662-8985
    Source: Scientific.Net: Materials Science & Technology / Trans Tech Publications Archiv 1984-2008
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The influence of surface morphology of diamond films on their friction behaviors wasinvestigated under both ambient air and water environments. The diamond films with three differentsurface morphologies were deposited on the Co-cemented tungsten carbide (WC-6wt%Co) substrateusing hot filament chemical vapor deposition (HFCVD) method and their frictional behavior werestudied on a ball-on-plate type reciprocating friction tester, where the ball-bearing steel was used asthe counterface materials. The coefficient of friction (COF) of diamond films showed strong surfacemorphology dependence, those samples with smaller diamond grain size and smoother surface finishrepresented lower COF in both dry and water lubricating conditions. Water lubricating wassignificantly favor to decrease the COF of diamond films, which might mainly due to the lubricatingeffect of physisorbed water layer formed on the sliding interface. In addition, the transferred materialslayer adhered on the worn surface of diamond films were supposed to be another factor that wasbeneficial for reducing the COF
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  • 9
    Electronic Resource
    Electronic Resource
    s.l. ; Stafa-Zurich, Switzerland
    Materials science forum Vol. 532-533 (Dec. 2006), p. 249-252 
    ISSN: 1662-9752
    Source: Scientific.Net: Materials Science & Technology / Trans Tech Publications Archiv 1984-2008
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Nanocrystalline diamond films (NDFs) were deposited on mirror-polished silicon (100)substrates using a graphite-grid assisted hot filament chemical vapor deposition (HFCVD)technique. The evidence of nanocrystallinity, smoothness and purity was obtained by characterizingthe sample with various advanced analyses. A graphite-grid was used as the DC electrode, whichwas pre-coated by diamond films and could emit electron when a negative bias was applied to theunder electrode. The results show that the film consists of nanocrystalline diamond grains with sizesof about 7-15nm. The Raman spectroscopy, XRD pattern, HR-TEM image and SAED pattern of thefilms indicate the presence of nanocrystalline diamond. Surface roughness is measured as Ra〈20nmby the profilometry scans. A large quantity of electrons emission from the graphite-grid and positiveions bombardment to the graphite-grid results in an enormous enhancement of the generation ofdiamond nuclei. Density of a diamond nuclei as high as 1010~1011/cm2 can be attained with thismethod. NDFs can be deposited on mirror-polished Si substrate surfaces without damaging surfacepretreatment for nucleation enhancement. These ultra-smooth films will display excellentperformances, which make them the best candidates for semiconductor and MEMS applications
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  • 10
    Electronic Resource
    Electronic Resource
    s.l. ; Stafa-Zurich, Switzerland
    Materials science forum Vol. 532-533 (Dec. 2006), p. 21-24 
    ISSN: 1662-9752
    Source: Scientific.Net: Materials Science & Technology / Trans Tech Publications Archiv 1984-2008
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: It is necessary to drill micro holes in some hard brittle materials. Comparing with electrodischarge machining, electrochemical machining and laser machining, the ultrasonic machining(USM) has unique advantages in hard brittle materials machining. The aim of this paper is topresent experimental work that has been done in micro holes machining by micro USM. The mainmachining mechanisms of USM are discussed. It is pointed out that the contributions of eachmechanism to material removal rate are different in different cases. By using micro USM withworkpiece vibration and tool feeding in constant rate, the experiments of micro holes machining arecarried out and the process laws of tool wear are studied. Some phenomena are found and thecausation of causing these phenomena is analyzed. A Ø13μm micro hole is obtained
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