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  • 1
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Journal of the American Chemical Society 77 (1955), S. 2161-2164 
    ISSN: 1520-5126
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 64 (1994), S. 3104-3106 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Gadolinium-doped barium cerate thin films have been grown on r-plane (11¯02) sapphire and on silver foil substrates by single solid-source metalorganic chemical vapor deposition using tetramethylheptanedionate mixed powder sources. The films have been deposited at 800 °C at a reduced pressure of 6 Torr. The bulk conductivity of the thin films, as measured by an alternating current impedance method, is close to that of sintered ceramic samples, and shows a similar hydrogen/deuterium isotope effect, providing evidence of protonic conduction.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    The @journal of physical chemistry 〈Washington, DC〉 67 (1963), S. 2424-2429 
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 68 (1990), S. 4008-4013 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The diffusion of Si in GaAs was investigated using diffusion sources from different tie triangle regions on the Si-Ga-As ternary phase diagram which provide constant chemical potentials for the three components under isothermal conditions. The Si profiles are measured with secondary ion mass spectrometry and differ significantly for the different sources. The Ga-Si-GaAs tie triangle source produces p-type Si doping with concentration independent diffusion coefficients, and a neutral As or Ga vacancy is proposed as the dominant mobile defect for these conditions. Arsenic-rich sources from two tie triangle regions and also a Si-GaAs tie line source produce Si donor diffusion with concentration-dependent diffusion behavior. The concentration-dependent diffusion coefficients of donor Si for As-rich source diffusion are related to the net ionized donor concentration showing three different regimes: intrinsic regime, intermediate regime, and saturation regime. Ga vacancies are proposed to be responsible for donor Si diffusion in GaAs: a V0Ga and/or V−Ga mechanism for the intrinsic regime; and a V−Ga related mechanism for the extrinsic and saturation regimes. The Si-GaAs tie line source resulted in two branch type profiles, intermediate between the As-rich and the Ga-rich source diffusion cases.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 65 (1989), S. 1048-1052 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The influence of concurrent diffusion of Zn and Si on the interdiffusion on the cation and anion sublattices was studied in InxGa1−xPyAs1−y-GaAs heterostructures (with x and y≈0.05). The heterostructures are grown by liquid phase epitaxy and the diffusion sources are equilibrium ternary tie triangle sources. The extent of interdiffusion on both group III and V atoms is observed by depth profiling In and P, respectively, with secondary ion-mass spectrometry. The Zn diffusion selectively enhances the cation (In-Ga) interdiffusion, whereas Si diffusion enhances both cation and anion interdiffusion to the same extent. A kick-out mechanism is proposed to explain the selective enhancement of the cation interdiffusion induced by Zn, and a single vacancy mechanism is proposed for the interdiffusion due to Si. Based on those observations, we propose that the impurity diffusion mechanism is a major factor in determining the degree of enhancement.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 68 (1990), S. 6224-6228 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The objective of this research is to establish a shape-memory effect in sputter-deposited films of nickel titanium. The alloy, generically called nitinol, was prepared from sputtering targets in two different compositions. Films were deposited up to 10 μm in thickness on glass substrates using a dc magnetron sputtering source. The as-deposited films were amorphous in structure and did not exhibit a shape memory. The amorphous films were crystallized with a suitable annealing process, and the transformation properties were measured using differential scanning calorimetry. The crystallized films showed transition temperatures that were much lower than those of the parent material. X-ray diffraction patterns indicated that the films were not a single phase but showed evidence of a second phase. However, the annealed films demonstrated a strong shape-memory effect. Stress/strain measurements and physical manipulation were used to evaluate the shape recovery. These tests demonstrated sustained tensile stresses of up to 480 MPa in the high-temperature phase, and a characteristic plastic deformation in the low-temperature phase.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 70 (1991), S. 6790-6795 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Ion-implantation-induced extended defect formation and annealing processes have been studied in GaAs. Mg, Be, Si, Ge, and Sn ions were implanted between 40 and 185 keV over the dose range of 1×1013–1×1015/cm2. Furnace annealing after capping with Si3N4 was performed between 700 and 900 °C for times between 5 min and 10 h. Plan-view and cross-sectional transmission electron microscopy results were correlated with secondary-ion-mass spectroscopy profiles. The results indicate subthreshold (type-I) defect formation occurs at a dose of 1×1014/cm2 for high-energy, light (Mg, Be) ions but not for heavier ions (Si, Ge, Sn) at shallower projected ranges (〈500 A(ring)). Si and Ge implants at a dose of 1×1015/cm2 both show extended defect formation upon annealing that is believed to be precipitation related (type-V defects). For Si implants, these dislocation loops are eliminated after 10 h at 900 °C. Upon annealing 1×1015/cm2 Sn implants, unusual precipitate motion both toward the surface and into the crystal was observed. Type-II defects are observed but only in the as-implanted cross section. In addition, a layer of dislocation loops formed at a depth much greater than the type-II defect layer. These defects appear to be a new type of defect possibly related to either the different binary recoil distributions of Ga and As or differences in vacancy and interstitial diffusivities. It is shown that, with modifications to account for the binary nature of the target, the classification scheme developed for extended defects in silicon can be applied to implantation of gallium arsenide.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 65 (1989), S. 2090-2094 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The results of an investigation of the relationship between potentiodynamic anodic polarization behavior, composition, and microstructure for both sputtered and electroplated Ni-Fe thin-film alloys is described. The presence of high-temperature phases established by sputter deposition correlate directly with the compositional dependence of the passive current density. These results correlate exceptionally well with previous studies on the corrosion of Ni-Fe films under simulated atmospheric conditions. Electroplated films of the permalloy composition show significantly different passive behavior, as compared to sputter deposited films. Possible explanations for this anomaly are discussed.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 59 (1986), S. 2398-2407 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The diffusion of Cr in GaAs was investigated under both in-diffusion and out-diffusion conditions. In-diffusion sources were CrAs(s)-GaAs(s)-Ga(l), three phase mixtures which, at a given temperature, provide an invariant chemical potential of the components. Unexpectedly deep penetration was observed and complex (two-branch) concentration profiles were often observed. The profiles were successfully modeled using an interstitial/substitutional/dissociative model. Different regimes of diffusion conditions gave rise to fast and slow effective diffusion coefficients. Subtle effects of doping and preannealing under arsenic overpressures confirmed the proposed model and served as a probe to study these subtle differences. Out-diffusion experiments led to slow effective diffusion coefficients, consistent with the diffusion model.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 61 (1987), S. 3155-3157 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: In the present study, Co-V films (17 at. % V) were deposited by rf sputtering onto several substrates that are candidates for magnetic recording substrates: glass; SiO2/Si; Ni-P/Al; and Corning Fotoceram. Films were deposited through a range of deposition variables, and their magnetic properties were measured in the film plane and perpendicular to the film plane. Magnetic orientation ratios on the various substrates range from 〈0.10 to 〉0.50. The substrate bias was one of the most important deposition parameters, and the response of coercivity to the bias voltage was much greater on glass than on any other substrate. On glass the perpendicular coercivity increased from 238 to 1360 Oe as the bias increased from 0 to 100 V. X-ray diffraction showed the films to be either amorphous or crystalline with preferred orientation. In general, amorphous films were deposited with zero substrate bias, while crystalline films were more easily obtained under conditions of substrate bias. The degree of crystallinity is a major determining factor for the magnetic properties of these films.
    Type of Medium: Electronic Resource
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