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  • 1
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 5 (1965), S. 280-284 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Strain gage techniques have been developed to monitor the internal stresses in epoxy resin castings. The data obtained are a measure of the stresses developed on a transducer held in the center of a mass of polymerizing epoxy resin or those caused by thermal cycling of the potted unit at intervals of storage time. Results show that the stresses developed on the transducer during the first 70 hours of room temperature polymerization reached 900 psi in axial compression. Further polymerization during storage increased the stress to 2300 psi after 12 months. During thermal cycling approximately 10,000 psi compressive stress was developed at -54°C. These stresses were relieved at 71°C but reappeared at the lower temperatures upon subsequent cooling.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 3 (1963), S. 61-66 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The effect of resin mass on the degree of crosslinking during the initial polymerization of three typical polymer compounds was determined by electrical resistivity techniques. Activation energies for the electrical conduction process (Ec) were calculated and used as an index of the extent of additional crosslinking occurring during sixteen months of storage. Test data show continued polymerization at slow rates for periods of time ranging from three days to over sixteen months before the polymerization process is completed. The final degree of crosslinking is shown to be dependent on the extent of initial crosslinking.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
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