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Polymerization-degradation of styrene in solution (1948)

Spodheim, Hilda W. ; Badgley, Wilfrid J. ; Mesrobian, Robert B.

Hoboken, NJ : Wiley-Blackwell

Journal of Polymer Science 3 (1948), S. 410-420

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ISSN: 0022-3832

Keywords: Chemistry ; Polymer and Materials Science

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology , Physics

Notes: The changes in the viscosity-average size distribution of polystyrene under conditions of simultaneous degradation and polymerization in toluene solutions have been observed. The appearance of the differential distribution curves for the degraded polymers and the polymerized monomer in the steady-state viscosity region are nearly identical. Osmotic pressure data on fractions of the degraded polymers do not show evidence for the occurrence of chain branching.

Additional Material: 6 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/pol.1948.120030315

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