ISSN:
0044-2313
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Contributions to the Chemistry of Transition Metal Alkyl Compounds. XLIII. Tetrakis(alkoxycarbonylmethyl)titanium CompoundsOrganotitanium(IV) compounds of the type (ROCOCH2)4Ti (R = C2H5, i-C3H7, t-C4H9, C6H5, C6H5CH2) were obtained by reactions of ROCOCH2Li derivatives with TiCl4 at low temperature. The compounds which decompose only above 90°C were characterized by the hydrolysis products, anaerobic reactions with iodine, and the i.r. spectra. The bond conditions are discussed.
Notes:
Organotitan(IV)-Verbindungen des Typs (ROCOCH2)4Ti wurden durch Umsetzung von ROCOCH2Li-Derivaten (R = C2H5, i-C3H7, t-C4H9, C6H5, C6H5CH2) mit TiCl4 bei tiefer Temperatur gewonnen. Die erst oberhalb 90°C zerfallenden Verbindungen wurden durch ihre Hydrolyseprodukte, anaerobe Iodierung und die IR-Spektren charakterisiert. Die Bindungsverhältnisse werden diskutiert.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/zaac.19865320108
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