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  • 1
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 79 (1996), S. 1435-1440 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Ferromagnetic MnAs thin films grown on GaAs (001) substrates by molecular-beam epitaxy have been studied by the methods of grazing incidence x-ray scattering, x-ray diffraction, and extended x-ray-absorption fine structure. Microstructures in two films prepared with different first-layer growth conditions (template effects) are compared in terms of the interfacial roughness in the layer structure, lattice constants, epilayer thickness, local environment surrounding the Mn atoms, coordination number, and local disorder. Our results indicate that the template effects can cause significant differences in the local structures and crystallinity of the MnAs epitaxial layers. © 1996 American Institute of Physics.
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  • 2
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 86 (1999), S. 6052-6058 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Angular dependence of x-ray fluorescence (ADXRF), x-ray absorption fine structure (XAFS), and grazing incidence x-ray scattering measurements were carried out using synchrotron radiation for a study of the interface morphology and migration of constituent atoms in a heterojunction formed between CdS and CuInSe2 single crystals. The advantage of using a single crystal for this study is to avoid the usually complicated problems arising from multiple phases of the Cu–In–Se compounds. By a comparison of the results obtained with a bare CuInSe2 single crystal, the changes of interface microstructures in the CdS/CuInSe2 heterojunction system with well-defined stoichiometry can therefore be investigated. Prominent features in the ADXRF data clearly demonstrate that both Cu and Se atoms have migrated into the CdS layer in the heterojunction while In atoms remain intact in the CuInSe2 single crystal. The local structures around Cu in the system also show a significant change after the deposition of CdS, as manifested by the appearance of new Cd near neighbors in the XAFS spectra. © 1999 American Institute of Physics.
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  • 3
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 85 (1999), S. 237-243 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Grazing incidence x-ray scattering and x-ray diffraction techniques have been employed to investigate the microstructures in various ZnSe-based semiconductor thin films grown on GaAs substrates by molecular beam epitaxy and metalorganic chemical vapor deposition methods. The results are also used for a comparison of the interfacial roughness and overall quality of the II–VI thin films prepared by these two different growth methods. Structural parameters such as the interfacial roughness and layer thickness obtained from the scattering measurements and lattice constants obtained from the x-ray diffraction pattern around the GaAs(004) peak can be correlated with the film deposition rate, compound composition, and lattice strain in the epilayers. We thus demonstrate that x-ray scattering techniques in conjunction with diffraction measurements are useful tools for nondestructive characterization of buried interfaces in semiconductor layer materials. © 1999 American Institute of Physics.
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  • 4
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 80 (2002), S. 2654-2656 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Local structure and effective chemical valency of Mn atoms in Mn/GaAs digital alloys have been investigated using the x-ray absorption fine structure techniques. The samples were prepared by molecular-beam epitaxy with different thickness of GaAs layers separating the nominal Mn monolayers. Lattice constants of the digital alloys are found by x-ray diffraction to increase linearly in a very narrow range (about 0.3%) with the Mn/GaAs ratio in the samples. Our data show that Mn atoms in the nominal Mn monolayers actually combine with GaAs to form (Ga, Mn)As alloys with Mn atoms substituting for the Ga sites in GaAs. This result clearly rules out the possibility of dominant MnAs formation. © 2002 American Institute of Physics.
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  • 5
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 79 (2001), S. 3926-3928 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Local structure and effective chemical valency of Mn impurity atoms incorporated in wide-band-gap (Ga,Mn)N epilayers have been investigated by using x-ray absorption fine structure techniques. The x-ray results provide direct evidence for the substitution of majority Mn atoms for the Ga sites in GaN, with an effective valency close to Mn(II), up to a rather high Mn concentration about 2 at. %. A small fraction of the impurity atoms could also form Mn clusters. © 2001 American Institute of Physics.
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  • 6
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 78 (2001), S. 3684-3686 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Local structure around Ge in Si/Ge superlattices containing the "inverted hut" nanocrystals has been investigated by using the extended x-ray absorption fine structure (EXAFS) technique. In contrast to the usual nanometer-sized Ge "hut clusters" commonly grown on top of Si layers using the conventional Stranski–Krastanow self-organized growth mode, SiGe-alloy nanocrystals can be formed beneath the Ge wetting layer and grown into the Si layer in Si/Ge superlattices prepared in a low-temperature molecular beam epitaxy growth mode, and exhibit inverted hut nanocrystal structures regularly spaced along the Si/Ge interface. The EXAFS results obtained with varying Ge wetting layer thickness provide a direct evidence that intermixing of Ge and Si atoms takes place in a zone of about 1–3 monolayers on each side of the Si/Ge interface. The intermixing of constituent atoms allows a mechanism other than the usual formation of misfit dislocations to release the strain energy resulted from lattice mismatch between Si and Ge at the interface. © 2001 American Institute of Physics.
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  • 7
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 81 (2002), S. 655-657 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The local environment surrounding magnetic impurity atoms and the host crystal structure of codoped TiO2 (TiO2:Co) nanocrystal ferromagnetic semiconductors have been investigated using the x-ray absorption fine structure and powder diffraction techniques. It has been found that the magnetic Co impurity atoms substitute for the Ti sites in an anataselike local environment through a structural phase transition when the material changes from an amorphous phase to a mixture of anatase and rutile crystal structures and then to a rutile structure as a result of increasing the anneal temperature. This result reveals an interesting feature that the local structure around magnetic impurity atoms can remain practically unchanged while the material undergoes drastic structural variations and a loss of room-temperature ferromagnetism. © 2002 American Institute of Physics.
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  • 8
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 76 (2000), S. 3729-3731 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Angular dependence of x-ray fluorescence and x-ray absorption fine structure techniques have been used to study the diffusion of Cu atoms into the photovoltaic material CdTe. Depth profile, effective valency, and local structure of Cu atoms in a Cu-doped single crystal of CdTe were investigated before and after a second heat treatment. Enhanced Cu diffusion into the CdTe single crystal was observed as a result of heating at a moderate temperature around 200 °C, resulting in a redistribution of the Cu impurities through a broader depth profile. Some of the Cu atoms are believed either to form small complexes with Te or occupy interstitial sites in the host but accompanied by a large local lattice distortion while others substitute for Cd on the cation sites. The results thus demonstrate that these nondestructive x-ray characterization methods are useful for probing microstructural changes in CdTe photovoltaic materials/devices in which some Cu-containing compounds are used as back contacts. © 2000 American Institute of Physics.
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  • 9
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 75 (1999), S. 2464-2466 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Local environment surrounding Y atoms in Y2O3:Tb nanocrystals under various heat treatment conditions has been investigated by using the extended x-ray absorption fine structure (EXAFS) technique. X-ray excited luminescence (XEL) with the incident x-ray energy near Y K edge and Tb L edges has also been measured to investigate the mechanisms of x-ray-to-visible down conversion in these doped nanoparticles. The observed changes in EXAFS, XEL, and photoluminescent data can be explained on the basis of increased average size of the nanoparticles as confirmed by transmission electron microscopy studies. Our results thus demonstrate that the doped nanoparticles can agglomerate to a controllable degree by varying the heat treatment temperature. At higher temperatures, the local environment surrounding Y atoms in the nanoparticles is found to become similar to that in bulk Y2O3 while the XEL output still shows the characteristics of nanocrystals. These results indicate that appropriate heat treatment can afford an effective means to control the intensity and signal-to-background ratio of green luminescence output of these doped nanocrystal phosphors, potentially useful for some device applications. © 1999 American Institute of Physics.
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  • 10
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 80 (2002), S. 1150-1152 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Grazing incidence x-ray scattering (GIXS) and x-ray diffraction (XRD) techniques have been employed to study the microscopic structure of magnetic digital layers of Mn/GaAs and MnGa/GaAs. Samples with various GaAs layer thickness (8 to 16 monolayers) and a half monolayer of either Mn or MnGa were prepared by low-temperature molecular-beam epitaxy. All digital alloys consist of 50 periods of magnetic layers separated by GaAs. High crystalline quality was verified and the periodicity and layer thickness were determined from the GIXS and XRD data. In order to investigate the magnetic properties, we performed magnetization measurements on all samples using superconducting quantum interference device magnetometry (SQUID). © 2002 American Institute of Physics.
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