ISSN:
0538-8066
Keywords:
Chemistry
;
Physical Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The kinetic deuterium isotope effect in the thermal dehydration stages of powdered SrCl2 · 2H2O was examined by means of both isothermal and dynamic gravimetries. These dehydration processes proved to be controlled by a random nucleation and its subsequent growth mechanism. No significant kinetic isotope effect was seen in these dehydration stages. It seems that there exists a kinetic compensation effect between the hydrate and its deuterium analog, if any isotopic differences in activation energy and frequency factor could exist.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/kin.550170203
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