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  • 1
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Chemical reviews 94 (1994), S. 3-29 
    ISSN: 1520-6890
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 114 (2001), S. 9938-9946 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: First hyperpolarizabilities β were obtained for CX4 molecules in gas and liquid phases from hyper-Rayleigh scattering measurements at λ=1064 nm. The gas-phase results for βxyz (atomic units) are 7.1±0.9 (CH4), 7.0±0.9 (CD4), 5.4±0.6 (CF4), and 11.0±0.9 (CCl4). Ab initio calculations of β are consistent with the experimental results for CF4 and CCl4, but not for CH4 and CD4. The effective liquid-phase β for CCl4 is 3× the gas phase value, but the liquid environment has little effect on β for the other molecules. Thermal-lens and absorption coefficients were also measured for ten liquids. © 2001 American Institute of Physics.
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  • 3
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    The @journal of physical chemistry 〈Washington, DC〉 99 (1995), S. 6973-6979 
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 108 (1998), S. 849-856 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The first and second hyperpolarizabilities (β and γ) of eight molecules at a fundamental wavelength of 1064 were measured by gas-phase electric-field-induced second-harmonic generation (EFISH), gas-phase hyper-Rayleigh scattering (HRS), and liquid-phase HRS experiments. The EFISH measurements give accurate values of β and γ for these molecules in the gas phase, and the HRS measurements show that the effective β of these molecules in the liquid is enhanced over the gas-phase value by a factor which varies from (approximate)0.4 to 2.0, over and above the Lorentz local field factors. Combining all of the measurements provides an accurate, absolute determination of the effective β for HRS in the liquid phase. The results for CCl4, suitable as reference standards, are 〈βVV2〉1/2=18.6±0.7 au in the liquid phase and βxyz=20.7±1.6 au in the gas phase. Comparison of measurements between hydrogenated and deuterated molecules indicates that vibrational contributions to β are small. © 1998 American Institute of Physics.
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  • 5
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 105 (1996), S. 3918-3929 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Hyper-Rayleigh light scattering measurements at incident wavelengths of 1064 and 1319 nm are reported for several organic nonlinear optical chromophores in solution with approximately 5%–10% uncertainty in the relative first hyperpolarizabilities. The measured chromophores include representatives from C1, Cs, C2V, and D3 molecular point groups and include both neutral and ionic compounds. The measurements were made with 2–5 cm−1 spectral resolution and include polarization analysis of the incident and scattered light. Polarization ratios were measured with 2%–3% uncertainty for each molecule, and relative magnitudes of the hyperpolarizability components were deduced. Two-photon induced fluorescence from several chromophores was observed to overlap with the scattered second harmonic light spectrum. The use of a scanning monochromator, however, generally allows the separation of these two sources of photons. The measured first hyperpolarizabilities are consistent with previous electric field induced second harmonic generation measurements of the same compounds, provided that the standard reference value for the nonlinear susceptibility of quartz is taken to be d11=0.30±0.02 pm/V at 1064 nm. © 1996 American Institute of Physics.
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  • 6
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 97 (1992), S. 7590-7599 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Frequently it is useful to compare experimental values of the hyperpolarizabilities β and γ with calculated values. It is also often helpful to compare experimental values of β obtained from dc-electric field induced second harmonic generation (dc-SHG) experiments, e.g., with values obtained using the solvatochromism method. In order to do this the hyperpolarizabilities must be defined using consistent conventions. In this paper, four commonly used conventions are discussed and simple factors for converting between them presented. In addition, the sum-over-states expression for the calculation of β and γ is described and its correct use in comparing with hyperpolarizabilities obtained using other experimental and theoretical techniques discussed. As an illustration of the consistent use of conventions, ab initio and semiempirical calculations on para-nitroaniline are compared with experimental dc-SHG values. This comparison highlights the difference between theoretical values of the hyperpolarizability with the molecule in a gas phase environment and experimental values obtained in polar solvents−a difference that has in the past been obscured by inconsistent choice of conventions.
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  • 7
    ISSN: 1546-170X
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Medicine
    Notes: [Auszug] Evidence suggests that nerve growth factor (NGF) may function as a mediator of some persistent pain states. We have used a synthetic protein, trkA-IgG, to sequester endogenous NGF and block the survival effects of NGF on cultured sensory neurons. We show that administration of trkA-IgG produces a ...
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  • 8
    Electronic Resource
    Electronic Resource
    Bingley : Emerald
    International journal of bank marketing 13 (1995), S. 41-44 
    ISSN: 0265-2323
    Source: Emerald Fulltext Archive Database 1994-2005
    Topics: Economics
    Notes: Examines changes in the life and pensions industry in the UK withparticular regard to distribution. Reviews changes at the industry andproduct level and the major impacts these have had on customer attitudesand service and the way in which distribution strategies have failed toput the customer first over the past 20 years. Argues that new entrantshave changed the benchmarks for distribution in terms of productivityand customer orientation and that existing companies and distributionchannels will face an increasingly difficult challenge to remaincompetitive. Concludes that there will be rationalization of the lifeand pensions industry and, along with it, a shift towards moreacceptable and innovative forms of distribution with traditional directsales being the major loser and bancassurance and direct writing beingthe main winners.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Springer
    Crop science 39 (1999), S. 448-452 
    ISSN: 1435-0653
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Triticum aestivum L.) quality and marketing in the USA. The objective of this study was to characterize the effects of fallow management—moldboard plow (plow), subtillage (subtill), and no-tillage (no-till)— and N fertilizer (0 and 45 kg N ha-1) on winter wheat kernel hardness, as measured by the Single Kernel Characterization System (SKCS). Rainfed field studies were conducted with 'Siouxland' hard red winter wheat from 1995 to 1997 on an Alliance silt loam (fine-silty, mixed, mesic Aridic Argiustoll) near Sidney, NE. In 1995 and 1996, the kernel harness index was increased from a 2-yr average of 46.0 to 55.2 by the addition of 45 kg N ha-1 , but N fertilizer treatment had no effect on kernel harness in 1997 when the average kernel harness index was 72.9. The effect of fallow management on kernel hardness varied from year to year. Kernel harness was positively correlated with grain protein in 1995 (r = 0.93) and 1996 (r = 0.94), but no meaningful relationship was observed in 1997. Half of the grain samples analyzed by the SKCS in 1995 and 1996 were classified as either soft or mixed wheat. This study suggests that kernel hardness is affected by a number of factors beyond genetics including N management, tillage system, pest infestations, environment, and their interaction. Growers may find that meeting proposed new grain standards is more complex than merely selecting the right cultivar.
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  • 10
    ISSN: 1572-9540
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract We show that Raman spectral lines from H2, D2, T2, HD, HT and DT are readily resolved, permitting an effective means to analyze isotopic hydrogen mixtures used in muon-catalyzed fusion experiments. We propose a Raman spectrographic system to allow for real-time analysis of targets involving all three isotopes of hydrogen.
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