ISSN:
0030-4921
Keywords:
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Assignment of RR and RS configurations to 2,2,6,6-tetramethyl-5-phenyl-3-heptanol diastereomers has been carried out through an analysis of the observed values for vicinal coupling constants of both isomers and their conformational distribution. The latter was previously estimated from steric interaction energies between groups. Since the RR isomer is monoconformational its magnetic parameters can be used to carry out conformational analysis of related acyclic compounds.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/mrc.1270100158
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