Electronic Resource
Springer
The European physical journal
86 (1992), S. 375-382
ISSN:
1434-6036
Source:
Springer Online Journal Archives 1860-2000
Topics:
Physics
Notes:
Abstract The crystallization behaviour of about 60 samples of electrodeposited Fe1−x P x , 0.09〈x〈0.26, was investigated with DSC and X-ray diffraction. Several subsequenting transformations during heating at 10 K/min were identified. The corresponding transformation temperatures, reaction heats and reaction rates were measured. If the as-deposited samples contain metal-rich crystallites (microcrystalline and partly amorphous material) crystallization starts with primary precipitation of α-iron followed by polymorphous crystallization of Fe3P. In amorphous samples these two processes become less important compared with the eutectoid reaction the higher the phosphorus content. In a small concentration range around 19 at% P this transformation is the only one. Above this range the primary crystallization of Fe3P becomes more and more dominant.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF01323730
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