ISSN:
1600-5759
Source:
Crystallography Journals Online : IUCR Backfile Archive 1948-2001
Topics:
Chemistry and Pharmacology
,
Geosciences
,
Physics
Notes:
In the title compound, K[Ni(C3S5)2]·C20H24O6·C3H6O, K+ is incorporated in the cavity of the 1,4,7,10,13,16-hexaoxa-2,3:11,12-dibenzocyclooctadeca-2,11-diene (DB18c6) molecule and is coordinated by the six DB18c6 O atoms and the propanone O atom. Two {K+(DB18c6)[(CH3)2CO]} units form a dimer which is aligned in a one-dimensional manner along the a axis through a face-to-face interaction between the benzene rings of neighboring DB18c6 molecules. [Ni(dmit)2]− anions are also aligned along the a axis through side-by-side S...S interactions.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1107/S0108270101013713
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