ISSN:
0899-0042
Keywords:
planar chirality
;
diastereoselectivity
;
Lewis acid catalyst
;
catalyzed Diels-Alder reaction
;
α-ferrocenyl carbenium ions
;
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The synthesis of chiral ferrocenyl carbocations is described starting from enantiopure orthosubstituted ferrocenylcarboxaldehydes. Secondary or tertiary carbocations have been prepared by ionization of an alcohol precursor. The stereochemistry of secondary α-ferrocenylcarbenium ions has been defined. Preliminary tests as Lewis acid catalysts have been performed. Chirality 9:478-486, 1997. © 1997 Wiley-Liss, Inc.
Additional Material:
2 Tab.
Type of Medium:
Electronic Resource
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