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  • 1
    Publication Date: 2022-05-27
    Description: Author Posting. © American Geophysical Union, 2021. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Paleoceanography and Paleoclimatology, 36(4), (2021): e2020PA004153, https://doi.org/10.1029/2020PA004153.
    Description: Variations in Mediterranean thermohaline circulation of the Quaternary are still not well constrained whereas they have been considered to have an influence on the Atlantic Meridional Overturning Circulation and on the oxygenation of waters in the deep basins of the Mediterranean Sea. εNd analyses have been carried out on planktonic foraminifera of cores collected in the central Mediterranean Sea to constrain water mass exchange between the Eastern and Western Mediterranean Sea (EMS and WMS) during the last climatic cycle. εNd records from the WMS and EMS display similar higher values during warm substages of interglacial Marine Isotopic Stage (MIS) 1 and 5. This suggests an efficient connection between the two Mediterranean sub-basins and the transfer of radiogenic waters to the Tyrrhenian Sea via the Levantine Intermediate Water (LIW). Conversely, during glacial MIS, εNd of the intermediate depth of the Tyrrhenian Sea are less radiogenic than the EMS, implying limited hydrological connection between sub-basins during low sea-level stands. Superimposed on these glacial-interglacial variations, increased εNd occurred during Heinrich Stadial events. This suggests a reduction in the formation of unradiogenic WIW in the Gulf of Lions due to the input of relatively fresh surface Atlantic water to the WMS and/or the inflow of radiogenic glacial LIW and upper EMDW to the Tyrrhenian Sea as a result of an active EMS convection related to saltier and colder conditions. Such potential millennial-scale pulses of LIW intrusion into the Tyrrhenian Sea may have led to an enhanced Mediterranean Outflow Water intensity in the Gibraltar Strait.
    Description: The research leading to this paper was funded by the French National Research Agency under the “Investissements d'avenir” program (Grant ANR-11-IDEX-0004-17-EURE-0006), the MEDSENS Project (Grant ANR-19-CE01-0019) and the INSU LEFE-IMAGO PALMEDS Project. The authors gratefully acknowledge the support provided by Louise Bordier during Nd isotopic composition analyses.
    Description: 2021-08-15
    Keywords: Central Mediterranean Sea ; foraminifera ; last climatic cycle ; Neodymium isotopic composition ; paleo-hydrology ; sapropels
    Repository Name: Woods Hole Open Access Server
    Type: Article
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  • 2
    Publication Date: 2022-05-26
    Description: © The Author(s), 2017. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Climate of the Past 13 (2017): 17-37, doi:10.5194/cp-13-17-2017.
    Description: We present the neodymium isotopic composition (εNd) of mixed planktonic foraminifera species from a sediment core collected at 622 m water depth in the Balearic Sea, as well as εNd of scleractinian cold-water corals (CWC; Madrepora oculata, Lophelia pertusa) retrieved between 280 and 442 m water depth in the Alboran Sea and at 414 m depth in the southern Sardinian continental margin. The aim is to constrain hydrological variations at intermediate depths in the western Mediterranean Sea during the last 20 kyr. Planktonic (Globigerina bulloides) and benthic (Cibicidoides pachyderma) foraminifera from the Balearic Sea were also analyzed for stable oxygen (δ18O) and carbon (δ13C) isotopes. The foraminiferal and coral εNd values from the Balearic and Alboran seas are comparable over the last  ∼  13 kyr, with mean values of −8.94 ± 0.26 (1σ; n =  24) and −8.91 ± 0.18 (1σ; n =  25), respectively. Before 13 ka BP, the foraminiferal εNd values are slightly lower (−9.28 ± 0.15) and tend to reflect higher mixing between intermediate and deep waters, which are characterized by more unradiogenic εNd values. The slight εNd increase after 13 ka BP is associated with a decoupling in the benthic foraminiferal δ13C composition between intermediate and deeper depths, which started at  ∼  16 ka BP. This suggests an earlier stratification of the water masses and a subsequent reduced contribution of unradiogenic εNd from deep waters. The CWC from the Sardinia Channel show a much larger scatter of εNd values, from −8.66 ± 0.30 to −5.99 ± 0.50, and a lower average (−7.31 ± 0.73; n =  19) compared to the CWC and foraminifera from the Alboran and Balearic seas, indicative of intermediate waters sourced from the Levantine basin. At the time of sapropel S1 deposition (10.2 to 6.4 ka), the εNd values of the Sardinian CWC become more unradiogenic (−8.38 ± 0.47; n =  3 at  ∼  8.7 ka BP), suggesting a significant contribution of intermediate waters originated from the western basin. We propose that western Mediterranean intermediate waters replaced the Levantine Intermediate Water (LIW), and thus there was a strong reduction of the LIW during the mid-sapropel ( ∼  8.7 ka BP). This observation supports a notable change of Mediterranean circulation pattern centered on sapropel S1 that needs further investigation to be confirmed.
    Description: The research leading to this study has received funding from the MISTRALS/PALEOMEX/COFIMED, the French National Research Agency “Investissement d’Avenir” (n°ANR-10-LABX-0018), the HAMOC project ANR-13-BS06- 0003 and ENVIMED/Boron Isotope and Trace Elements project.
    Repository Name: Woods Hole Open Access Server
    Type: Article
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  • 3
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Electrophoresis 4 (1983), S. 399-404 
    ISSN: 0173-0835
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Chemistry and Pharmacology
    Notes: Soluble guanylate cyclase purified from rat brain exhibits about 30 different components between pH 5.3 and 6.5 on polyacrylamide gel isoelectric focusing (IEF) Specific immunodetection after IEF of guanylate cyclase from fresh rat brain supernatant allows the detection of a complex profile, indicating that the complex pattern observed with purified enzyme is not related to sample aging. In contrast, purified enzyme gives only one major band on electrophoresis in presence or absence of sodium dodecyl sulfate and a single line of immunoprecipitation was obtained on crossed immunoelectrofocusing. The IEF pattern exhibited by guanylate cyclase is dependent on the sample concentration, the pH range of sample application, the carrier ampholytes used and on the presence of urea in the gel. Fractionation tests, performed with partially purified enzyme or with purified enzyme, indicate that this complex pattern is produced during IEF and does not correspond to an inherent heterogeneity of soluble rat brain guanylate cyclase. The distribution of carrier ampholytes used to form the pH gradient and that of guanylate cyclase bands was found to be very similar at the steady-state of IEF, suggesting that interaction between carrier ampholytes and rat brain soluble guanylate cyclase can be involved in the generation of the complex IEF pattern.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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  • 4
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    PANGAEA
    In:  Supplement to: Dubois-Dauphin, Quentin; Montagna, Paolo; Siani, Giuseppe; Douville, Eric; Wienberg, Claudia; Hebbeln, Dierk; Liu, Zhifei; Kallel, Nejib; Dapoigny, Arnaud; Revel, Marie; Pons-Branchu, Edwige; Taviani, Marco; Colin, Christophe (2017): Hydrological variations of the intermediate water masses of the western Mediterranean Sea during the past 20 ka inferred from neodymium isotopic composition in foraminifera and cold-water corals. Climate of the Past, 13(1), 17-37, https://doi.org/10.5194/cp-13-17-2017
    Publication Date: 2023-01-13
    Description: We present the neodymium isotopic composition (epsilon-Nd) of mixed planktonic foraminifera species from a sediment core collected at 622 m water depth in the Balearic Sea, as well as epsilon-Nd of scleractinian cold-water corals (CWC; Madrepora oculata, Lophelia pertusa) retrieved between 280 and 442 m water depth in the Alboran Sea and at 414 m depth in the southern Sardinian continental margin. The aim is to constrain hydrological variations at intermediate depths in the western Mediterranean Sea during the last 20 kyr. Planktonic (Globigerina bulloides) and benthic (Cibicidoides pachyderma) foraminifera from the Balearic Sea were also analyzed for stable oxygen (d18O) and carbon (d13C) isotopes. The foraminiferal and coral epsilon-Nd values from the Balearic and Alboran seas are comparable over the last ~13 kyr, with mean values of -8.94 ± 0.26 (1 Sigma; n = 24) and -8.91 ± 0.18 (1 Sigma; n = 25), respectively. Before 13 ka BP, the foraminiferal epsilon-Nd values are slightly lower (-9.28 ± 0.15) and tend to reflect higher mixing between intermediate and deep waters, which are characterized by more unradiogenic epsilon-Nd values. The slight epsilon-Nd increase after 13 ka BP is associated with a decoupling in the benthic foraminiferal d13C composition between intermediate and deeper depths, which started at ~16 ka BP. This suggests an earlier stratification of the water masses and a subsequent reduced contribution of unradiogenic epsilon-Nd from deep waters. The CWC from the Sardinia Channel show a much larger scatter of epsilon-Nd values, from -8.66 ± 0.30 to 5.99 ± 0.50, and a lower average (-7.31 ± 0.73; n = 19) compared to the CWC and foraminifera from the Alboran and Balearic seas, indicative of intermediate waters sourced from the Levantine basin. At the time of sapropel S1 deposition (10.2 to 6.4 ka), the epsilon-Nd values of the Sardinian CWC become more unradiogenic (-8.38 ± 0.47; n = 3 at ~8.7 ka BP), suggesting a significant contribution of intermediate waters originated from the western basin. We propose that western Mediterranean intermediate waters replaced the Levantine Intermediate Water (LIW), and thus there was a strong reduction of the LIW during the mid-sapropel (~8.7 ka BP). This observation supports a notable change of Mediterranean circulation pattern centered on sapropel S1 that needs further investigation to be confirmed.
    Type: Dataset
    Format: application/zip, 4 datasets
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  • 5
    Publication Date: 2023-02-07
    Keywords: Age, dated; Age, dated standard deviation; Coral; Core; CORE; Depth, bottom/max; DEPTH, sediment/rock; Depth, top/min; Neodymium-143/Neodymium-144 ratio; Neodymium-143/Neodymium-144 ratio, standard deviation; RECORD; RECORD_23; Sample code/label; Sardinia Channel; Thorium-230/Thorium-232, standard deviation; Thorium-230/Thorium-232 ratio; Thorium-230/Uranium-238, standard deviation; Thorium-230/Uranium-238 ratio; Thorium-232; Thorium-232, standard deviation; Urania; Uranium-238; Uranium-238, standard deviation; δ234 Uranium; δ234 Uranium, standard deviation; ε-Neodymium; ε-Neodymium, standard deviation
    Type: Dataset
    Format: text/tab-separated-values, 418 data points
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  • 6
    Publication Date: 2023-02-13
    Keywords: AGE; Balear Sea; Cibicidoides pachyderma, δ13C; Cibicidoides pachyderma, δ18O; DEPTH, sediment/rock; Globigerina bulloides, δ13C; Globigerina bulloides, δ18O; Le Suroît; Mass spectrometer, Finnigan, MAT 253; Neodymium-143/Neodymium-144 ratio; Neodymium-143/Neodymium-144 ratio, standard deviation; PALEOCINAT II; PC; Piston corer; SU92; SU92-33; ε-Neodymium; ε-Neodymium, standard deviation
    Type: Dataset
    Format: text/tab-separated-values, 200 data points
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  • 7
    Publication Date: 2023-05-12
    Keywords: AGE; Comment; DEPTH, sediment/rock; France_Mix; KS79-25; Mass spectrometer Finnigan MAT 261; Neodymium-143/Neodymium-144 ratio; PC; Piston corer; Strontium; Strontium-87/Strontium-86 ratio; ε-Neodymium (0)
    Type: Dataset
    Format: text/tab-separated-values, 49 data points
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  • 8
    Publication Date: 2023-05-12
    Keywords: AGE; Comment; DEPTH, sediment/rock; France_Mix; KS79-29; Mass spectrometer Finnigan MAT 261; Neodymium; Neodymium-143/Neodymium-144 ratio; PC; Piston corer; Strontium; Strontium-87/Strontium-86 ratio; ε-Neodymium (0)
    Type: Dataset
    Format: text/tab-separated-values, 144 data points
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  • 9
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    Unknown
    PANGAEA
    In:  Supplement to: Biscaye, Pierre Eginton; Grousset, Francis E; Revel, Marie; van der Gaast, Sjierk; Zielinski, G A; Vaars, A; Kukla, George J (1997): Asian provenance of glacial dust (stage 2) in the Greenland Ice Sheet Project 2 ice core, Summit, Greenland. Journal of Geophysical Research: Oceans, 102(C12), 26765-26782, https://doi.org/10.1029/97JC01249
    Publication Date: 2023-06-27
    Description: Samples of dust from the Greenland Ice Sheet Project 2 (GISP2) ice core, Summit, Greenland, dated within marine isotope stage 2 (between 23,340 and 26,180 calendar years B.P.) around the time of the coldest, local, last glacial temperatures, have been analyzed to determine their provenance. To accomplish this, we have compared them with approximately Coeval aeolian sediments (mostly loesses) sampled in possible source areas (PSAs) from around the northern hemisphere. The 〈5-µm grain-size fraction of these samples was analyzed on the basis that it corresponds to the atmospheric dust component of that time and locale, which was sufficiently fine grained to be transported over long distances. On the basis of comparison of the clay mineralogy and Sr, Nd and Pb isotope composition with ice dust and PSAs and assuming that we have sampled the most important PSAs, we have determined that the probable source area of these GISP2 dusts was in eastern Asia. The dust was not derived from either the midcontinental United States or the Sahara, two more proximal areas that have been suggested as potential sources based on atmospheric circulation modeling. Except for a brief period during an interstadial, when dust transport was exceptionally low (for glacial times) and had a mineralogical composition indicative of a slightly more southern provenance, the source area of the dust did not change significantly during times of variably higher fluxes of dust with larger mean grain size or lower fluxes of dust with smaller mean grain size. This includes the high-dust period that correlates with the Heinrich 2 period of major iceberg discharge into the North Atlantic. Variable wind strengths must therefore be invoked to account for these abrupt and significant changes in dust flux and grain size.
    Keywords: DRILL; Drilling/drill rig; Fairbanks; GISP; GISP2; GISPRefSamp245-5; GISPRefSamp245-6; GISPRefSamp248-1; GISPRefSamp248-2; GISPRefSamp248-3; GISPRefSamp248-4; GISPRefSamp248-5; GISPRefSamp248-6; GISPRefSamp248-7; GISPRefSamp248-8; GISPRefSamp251-3; GISPRefSamp251-4; GISPRefSamp251-5; GISPRefSamp251-6; Gobi Desert; Greenland Ice Core Projects; GRIP/GISP/NGRIP; HAND; Illinois, United States of America; Sampling/drilling ice; Sampling by hand; Shaanxi; Toronto; Ukraine; Washington
    Type: Dataset
    Format: application/zip, 2 datasets
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  • 10
    Publication Date: 2023-06-27
    Keywords: AGE; Aluminosilicate insoluble particles; Aluminosilicate insoluble particles, flux; Calcium; Chlorite; Crystal size; Depth, bottom/max; DEPTH, ice/snow; Depth, top/min; DRILL; Drilling/drill rig; GISP; GISP2; Greenland Ice Core Projects; GRIP/GISP/NGRIP; Illite; Kaolinite; Lead-206/Lead-204 ratio; Lead-206/Lead-207 ratio; Lead-207/Lead-204 ratio; Lead-208/Lead-204 ratio; Lead-208/Lead-206 ratio; Neodymium-143/Neodymium-144 ratio; Sampling/drilling ice; Smectite; Strontium-87/Strontium-86 ratio; X-ray diffraction TEXTUR, clay fraction
    Type: Dataset
    Format: text/tab-separated-values, 149 data points
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