ISSN:
0009-2940
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Contributions to the Chemistry of Boron, 173. Salts of the Bis(diisopropylamino)boron(1+) CationBromobis(diisopropylamino)borane (1) reacts with aluminium and gallium tribromide to produce stable salts of type [(iPr2N)2B]EBr4 (2, 3). Silver triflate converts 1 into bis(diisopropylamino)[(trifluoromethyl)sulfonyloxy]borane (4), while silver tetratriflatoborate produces a mixture of 4 with the salt [(iPr2N)2B]B(OSO2CF3)4 (6). Furthermore (diisopropylamino)bis[(trifluoromethyl)sulfonyloxy]borane (7) is formed.
Notes:
Bis(diisopropylamino)borbromid (1) reagiert mit Aluminium-oder Galliumtribromid zu den stabilen Salzen [(iPr2N)2B]EBr4 (2, 3), während 1 mit Silber-triflat Bis(diisopropylamino)-[(trifluormethyl)sulfonyloxy]boran (4) liefert. Silber-tetratriflatoborat setzt sich mit 1 zu einem Gemisch von 4 mit dem Salz [(iPr2N)2B]B(OSO2CF3)4 (6) um. Ferner entsteht (Diisopropylamino)bis[(trifluormethyl)sulfonyloxy]boran (7).
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19861190702
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