ISSN:
1572-8773
Keywords:
Co(II)
;
complexes
;
Cu(II)
;
glucose
;
Mn(II)
;
Ni(II)
;
saccharide
;
transition metal
;
Zn(II)
Source:
Springer Online Journal Archives 1860-2000
Topics:
Biology
,
Chemistry and Pharmacology
Notes:
Abstract Metal complexes of d-glucose (d-Glc) from large cation containing dibromo-dichloro salts of dipositive metals [NEt4]2[MBr2Cl2] (M = Mn, Co, Ni, Cu and Zn) and the disodium salt of glucose were synthesized from a MeOH:MeCN mixture. The complexes were characterized by UV-vis absorption, circular dichroism, IR and proton magnetic resonance spectroscopies, and by elemental analysis, and were found to be Na[M(d-Glc)(OMe)Cl]. Cyclic voltammetric studies of these complexes, in the acidic to neutral pH range, indicated no dissociation, even in highly acidic conditions.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00156153
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