Electronic Resource
College Park, Md.
:
American Institute of Physics (AIP)
The Journal of Chemical Physics
114 (2001), S. 6499-6501
ISSN:
1089-7690
Source:
AIP Digital Archive
Topics:
Physics
,
Chemistry and Pharmacology
Notes:
Ligand field spectra have been recorded in the gas phase for the two complexes [Ag.(pyridine)4]2+ and [Cu.(pyridine)4]2+. Both spectra compare favorably with analogous condensed phase measurements; however, for [Ag.(pyridine)4]2+ the results differ in interpretation. The Ag(II) data are attributed to a ligand-to-metal charge transfer process, and the Cu(II) data (spectral region and extinction coefficient) match the characteristics of a d–d transition. © 2001 American Institute of Physics.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1063/1.1365098
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