ISSN:
0044-2313
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Formation and Structure of tert-Butyl(tert-butylamino) [tris(tert-butyloxy)silylthio]-boraneThe smooth addition of the SH bond of (tBuO)3SiSH to the BN bond of tBuB≡NtBu gives the title compound, which crystallizes in the triclinic system, space group P1, with an unexpectedly short BN bond, d(BN) = 137 pm, in a Z configuration.
Notes:
Die SH-Bindung von (tBuO)3SiSH addiert sich glatt an die BN-Bindung von tBuB≡NtBu unter Bildung der Titelverbindung. Diese kristallisiert triklin, Raumgruppe P1, mit einer unerwartet kurzen, Z-konfigurierten BN-Bindung, d(BN) = 137 pm.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/zaac.19885560109
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